Dirhodium-catalyzed phenol and aniline oxidations with T-HYDRO. Substrate scope and mechanism of oxidation

Journal of Organic Chemistry

Volumn 76, Issue 8, 2011, Pages 2585-2593

  Ratnikov, Maxim O ^a   Farkas, Linda E ^a   McLaughlin, Emily C ^a   Chiou, Grace ^a   Choi, Hojae ^a   El Khalafy, Sahar H ^a,b   Doyle, Michael P ^a  

^a Bldg 142   (United States)

^b Tanta University   (Egypt)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC AMOUNTS; CHEMO-SELECTIVITY; DIASTEREO-SELECTIVITY; DIRHODIUM; EFFICIENT CATALYSTS; ELECTRON-RICH; GOOD YIELD; HYDROGEN ATOM ABSTRACTION; MECHANISM OF OXIDATION; NITROARENES; ORTHO POSITION; P-TERT-BUTYLPHENOL; PARA-SUBSTITUTED PHENOLS; PHENOL OXIDATION; PHENOLIC SUBSTRATES; PHENOXY RADICALS; PRIMARY AMINES; RATE ENHANCEMENT; REACTION CONDITIONS; SELECTIVE OXIDATION; STERIC INFLUENCE; SUBSTITUTED ANILINES; TERT-BUTYLHYDROPEROXIDE; TERT-BUTYLPEROXY RADICALS;

ANILINE; CARBONYL COMPOUNDS; CARBONYLATION; CATALYSIS; CATALYSTS; HALOCARBONS; OXIDATION; POTASSIUM COMPOUNDS; RHODIUM; RHODIUM COMPOUNDS; RUTHENIUM COMPOUNDS; SUBSTRATES; TOLUENE;

PHENOLS;

4 (TERT BUTYLDIOXY)CYCLOHEXADIENONE; 4 TERT BUTYLPHENOL; AMINE; ANILINE; AROMATIC NITRO COMPOUND; CAPROLACTAM DERIVATIVE; CHLOROBENZENE; CYCLOHEXANE DERIVATIVE; DIRHODIUM; DIRHODIUM CAPROLACTAMATE; ESTRONE; HALOCARBON; HYDROGEN; PHENOL; QUINONE DERIVATIVE; RADICAL; RHODIUM DERIVATIVE; SOLVENT; TERT BUTYL HYDROPEROXIDE; TERT BUTYLPEROXY RADICAL; TOLUENE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; ATOM; CATALYSIS; CATALYST; CHEMICAL REACTION; CONTROLLED STUDY; DIASTEREOISOMER; ELECTRON; OXIDATION; PHASE TRANSITION; STEREOCHEMISTRY; STEREOSPECIFICITY; SUBSTITUTION REACTION;

AMINES; ANILINE COMPOUNDS; CATALYSIS; CYCLOHEXENES; ELECTRONS; ESTRONE; OXIDANTS; OXIDATION-REDUCTION; OXYGEN; PHENOLS; PROTONS; RHODIUM; SOLVENTS; STEREOISOMERISM; SUBSTRATE SPECIFICITY; TERT-BUTYLHYDROPEROXIDE; WATER;

EID: 79953883498     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1024865     Document Type: Article

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