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Journal of the American Chemical Society

Volumn 133, Issue 13, 2011, Pages 5124-5128

Effect of buffer general acid-base catalysis on the stereoselectivity of ester and thioester H/D exchange in D2O

(5) Mohrig, Jerry R a Reiter, Nicholas J a Kirk, Randy a Zawadski, Michelle R a Lamarre Vincent, Nathan a

a CARLETON COLLEGE (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID-BASE CATALYSIS; ACYCLIC ESTERS; AMMONIUM IONS; BUFFER EFFECT; DIASTEREOMERS; ENCOUNTER COMPLEX; ENOLATE ANIONS; ENOLATES; H/D EXCHANGE; H/D EXCHANGE REACTIONS; HYDRATASE; HYDROGEN BONDINGS; NMR ANALYSIS; PHOSPHATE BUFFERS; THIOESTERS;

AMMONIUM COMPOUNDS; CARBONYL COMPOUNDS; CARBONYLATION; CATALYSIS; ESTERIFICATION; ESTERS; HYDROGEN BONDS; IONS;

STEREOSELECTIVITY;

ACETIC ACID ETHYL ESTER; DEUTERIUM OXIDE; ENOYL COENZYME A HYDRATASE; ESTER; HYDROGEN; PHOSPHATE BUFFERED SALINE; THIOESTER;

ARTICLE; CATALYSIS; DEUTERIUM HYDROGEN EXCHANGE; DIASTEREOISOMER; HYDROGEN BOND; PROTON TRANSPORT; STEREOCHEMISTRY;

ACIDS; CATALYSIS; DEUTERIUM EXCHANGE MEASUREMENT; DEUTERIUM OXIDE; ESTERS; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 79953836819 PISSN: 00027863 EISSN: 15205126 Source Type: Journal
DOI: 10.1021/ja200014c Document Type: Article

Times cited : (11)

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