A review of the effects of iron redox cycles on smectite properties;Revue sur les effets des cycles redox du fer sur les propriétés des smectites

Comptes Rendus - Geoscience

Volumn 343, Issue 2-3, 2011, Pages 199-209

  Stucki, Joseph W ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

Cation exchange; Cation fixation; Color; Ferric; Ferrous; Infrared spectroscopy; Intervalence charge transfer; Magnetic order; M ssbauer spectroscopy

Indexed keywords

INFRARED SPECTROSCOPY; ION EXCHANGE; IRON; MOSSBAUER SPECTROSCOPY; REDOX CONDITIONS; SMECTITE;

EID: 79953807920     PISSN: 16310713     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.crte.2010.10.008     Document Type: Article

References (48)

1. Banin A., Lahav N. Particle size and optical properties of montmorillonite in suspension. Israel J. Chemistry 1968, 6:235-250.
2. Coyne L.M., Costanzo P.M., Theng B.K.G. Luminescence and ESR studies of relationships between O-centres and structural iron in natural and synthetically hydrated kaolinites. Clay Minerals 1989, 24:571-693.
3. Drits V.A., Manceau A. A model for the mechanism of Fe3+ to Fe2+ reduction in dioctahedral smectites. Clays Clay Minerals 2000, 48:185-195.
4. Fialips C.I., Huo D., Yan L., Wu J., Stucki J.W. Infared study of reduced and reduced-reoxidized ferruginous smectite. Clays Clay Minerals 2002, 50:455-469.
5. Fialips C.I., Huo D., Yan L., Wu J., Stucki J.W. Effect of iron oxidation state on the IR spectra of Garfield nontronite. Am. Mineral. 2002, 87:630-641.
6. Freund, F., Batllo, F., Freund, M.M., 1989. In: Coyne, L.M., McKeever, S.W.S., Blake, D.F. (Eds.), Dissociation and Recombination of Positive Holes in Minerals. American Chemical Society, Washington, DC, pp. 310-329.
7. Gates W.P., Wilkinson H.T., Stucki J.W. Swelling properties of microbially reduced ferruginous smectite. Clays Clay Minerals 1993, 41:360-364.
8. Hofstetter T.B., Schwarzenbach R.P., Haderlein S.B. Reactivity of Fe(II) species associated with clay minerals. Environmental Science & Technology 2003, 37:519-528.
9. Hofstetter T.B., Neumann A., Schwarzenbach R.P. Reduction of nitroaromatic compounds by Fe(II) species associated with iron-rich smectites. Environmental Science & Technology 2006, 40:235-242.
10. Jaisi D.P., Dong H.L., Liu C.X. Kinetic analysis of microbial reduction of Fe(III) in nontronite. Environmental Science & Technology 2007, 41:2437-2444.
11. Jaisi D.P., Dong H.L., Liu C.X. Influence of biogenic Fe(II) on the extent of microbial reduction of Fe(III) in clay minerals nontronite, illite, and chlorite. Geochim. Cosmochim. Acta 2007, 71:1145-1158.
12. Jaisi D.P., Dong H.L., Kim J., He Z.Q., Morton J.P. Nontronite particle aggregation induced by microbial Fe(III) reduction and exopolysaccharide production. Clays Clay Minerals 2007, 55:96-107.
13. Jaisi D.P., Kukkadapu R.K., Eberl D.D., Dong H.L. Control of Fe(III) site occupancy on the rate and extent of microbial reduction of Fe(III) in nontronite. Geochim. Cosmochim. Acta 2005, 69:5429-5440.
14. Jaisi D.P., Ji S.S., Dong H.L., Blake R.E., Eberl D.D., Kim J. Role of microbial Fe(III) reduction and solution chemistry in aggregation and settling of suspended particles in the Mississippi River & Delta; Plain, Louisiana, USA. Clays Clay Minerals 2008, 56:416-428.
15. Khaled E.M., Stucki J.W. Fe oxidation state effects on cation fixation in smectites. Soil Sci. Soc. Am. J. 1991, 55:550-554.
16. Kim J., Dong H., Seabaugh J., Newell S.W., Eberl D.D. Role of microbes in the smectite to illite reaction. Science 2004, 303:830-832.
17. Komadel P., Lear P.R., Stucki J.W. Reduction and reoxidation of nontronite: extent of reduction and reaction rates. Clays Clay Minerals 1990, 38:203-208.
18. Komadel P., Madejova J., Stucki J.W. Reduction and reoxidation of nontronite - Questions of reversibility. Clays Clay Minerals 1995, 43:105-110.
19. Kostka J.E., Haefele E., Viehweger R., Stucki J.W. Respiration and dissolution of Fe(III)-containing clay minerals by bacteria. Environmental Science & Technology 1999, 33:3127-3133.
20. Lahav N., Banin A. Effect of various treatments on particle size and optical properties of montmorillonite suspensions. Israel J. Chemistry 1968, 6:285-294.
21. Lear P.R., Stucki J.W. Role of structural hydrogen in the reduction and reoxidation of Fe in nontronite. Clays Clay Minerals 1985, 33:539-545.
22. Lear P.R., Stucki J.W. Intervalence electron transfer and magnetic exchange in reduced nontronite. Clays Clay Minerals 1987, 35:373-378.
23. Lear P.R., Stucki J.W. Effects of Fe oxidation state on the specific surface area of nontronite. Clays Clay Minerals 1989, 37:547-552.
24. Lee K., Kostka J.E., Stucki J.W. Comparisons of structural Fe reduction in smectites by bacteria and dithionite: an infrared spectroscopic study. Clays Clay Minerals 2006, 54:195-208.
25. Manceau A., Lanson B., Drits V.A., Chateigner D., Gates W.P., Wu J., Huo D., Stucki J.W. Oxidation-reduction mechanism of iron in dioctahedral smectites. 1. Crystal chemistry of oxidized reference nontronites. Am. Mineral. 2000, 85:133-152.
26. Manceau A., Lanson B., Drits V.A., Chateigner D., Wu J., Huo D., Gates W.P., Stucki J.W. Oxidation-reduction mechanism of iron in dioctahedral smectites. 2. Crystal chemistry of reduced Garfield nontronite. Am. Mineral. 2000, 85:153-172.
27. Murad E. Mössbauer spectra of nontronites: structural implications and characterization of associated iron oxides. Zeitschrift für Pflanzenernaehrurng und Bodenkunde 1987, 150:279-285.
28. Neumann A., Hofstetter T.B., Lussi M., Cirpka O.A., Petit S., Schwarzenbach R.P. Assessing the redox reactivity of structural iron in smectites using nitroaromatic compounds as kinetic probes. Environmental Science & Technology 2008, 42:8381-8387.
29. Neumann A., Hofstetter T.B., Skarpeli-Liati M., Schwarzenbach R.P. Reduction of polychlorinated ethanes and carbon tetrachloride by structural Fe(II) in smectites. Environmental Science & Technology 2009, 43:4082-4089.
30. Ribeiro F.R., Fabris J.D., Kostka J.E., Komadel P., Stucki J.W. Comparisons of structural iron reduction in smectites by bacteria and dithionite: II. A variable-temperature Mössbauer spectroscopic study of Garfield nontronite. Pure and Applied Chemistry 2009, 81:1499-1509.
31. Roth, C.B., Tullock, R.J., 1973. Deprotonation of nontronite resulting from chemical reduction of structural ferric iron. In: Serratosa, J.M. (Ed.), Proceedings, International Clay Conference, 1972. CSIC, Madrid, pp. 107-114.
32. Roth C.B., Jackson M.L., Syers J.K. Deferration effect on structural ferrous-ferric iron ratio and CEC of vemiculites and soils. Clays Clay Minerals 1969, 17:253-264.
33. Shen, S., Stucki, J.W., 1994. Effects of iron oxidation state on the fate and behavior of potassium in soils. In: Havlin, J.L., Jacobsen, J. (Eds.), Soil Testing: Prospects for Improving Nutrient Recommendations, Special Publication Number 40. Soil Science Society of America, Madison, Wisconsin, pp. 173-185.
34. Shen S., Stucki J.W., Boast C.W. Effects of structural iron reduction on the hydraulic conductivity of Na-smectite. Clays Clay Minerals 1992, 40:381-386.
35. Sherman D.M., Vergo N. Optical (Diffuse reflectance) and Mössbauer spectroscopic study of nontronite and related Fe-bearing smectites. Am. Mineral. 1988, 73:1346-1354.
36. Stucki J.W. Properties and behaviour of iron in clay minerals. Handbook of Clay Science 2006, 429-482. Elsevier, Amsterdam. F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.).
37. Stucki J.W., Roth C.B. Interpretation of infrared spectra of oxidized and reduced nontronite. Clays Clay Minerals 1976, 24:293-296.
38. Stucki J.W., Roth C.B. Oxidation-reduction mechanism for structural iron in nontronite. Soil Sci. Soc. Am. J. 1977, 41:808-814.
39. Stucki, J.W., Lear, P.R., 1989. Variable oxidation states of Fe in the crystal structure of smectite clay minerals. In: Coyne, L.M., McKeever, S.W.S., Blake, D.F. (Eds.), Spectroscopic Characterization of Minerals and Their Surfaces. ACS Symposium Series 415 American Chemical Society, Washington, DC, pp. 330-358.
40. Stucki J.W., Kostka J.E. Microbial reduction of iron in smectite. C. R. Geoscience 2006, 338:468-475.
41. Stucki J.W., Golden D.C., Roth C.B. The effect of reduction and reoxidation on the surface charge and dissolution of dioctahedral smectites. Clays Clay Minerals 1984, 32:350-356.
42. Stucki J.W., Low P.F., Roth C.B., Golden D.C. Effects of oxidation state of octahedral iron on clay swelling. Clays Clay Minerals 1984, 32:357-362.
43. Stucki J.W., Goodman B.A., Schwertmann U. Iron in soils and clay minerals 1988, D. Reidel, Dordrecht, The Netherlands, (893 p).
44. Tor J.M., Xu C., Stucki J.W., Wander M.M., Sims G.K. Trifluralin degradation under microbiologically induced nitrate and Fe(III) reduced conditions. Environmental Science & Technology 2000, 34:3148-3152.
45. Wu J., Low P.F., Roth C.B. Biological reduction of structural Fe in sodium-nontronite. Soil Sci. Soc. Am. J. 1988, 52:295-296.
46. Xu J.C., Sims G.K., Kostka J.E., Wu J., Stucki J.W. Fate of atrazine and alachlor in redox-treated ferruginous smectite. Environmental Toxicology and Chemistry 2001, 20:2717-2724.
47. Yan L., Stucki J.W. Effects of structural Fe oxidation state on the coupling of interlayer water and structural Si-O stretching vibrations in montmorillonite. Langmuir 1999, 15:4648-4657.
48. Yan L., Stucki J.W. Structural perturbations in the solid-water interface of redox transformed nontronite. Journal of Colloid and Interface Science 2000, 225:429-439.