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Volumn 43, Issue 4, 2011, Pages 331-351

Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl) (amido)dimethyltitanium-based catalysts

Author keywords

1 alkene; cycloolefin copolymer; living polymerization; norbornene; propene; single site catalyst; syndiospecific polymerization

Indexed keywords

1-ALKENES; CYCLOOLEFIN COPOLYMERS; NORBORNENES; PROPENE; SINGLE-SITE CATALYST; SYNDIOSPECIFIC POLYMERIZATION;

EID: 79953715379     PISSN: 00323896     EISSN: 13490540     Source Type: Journal    
DOI: 10.1038/pj.2011.13     Document Type: Review
Times cited : (38)

References (77)
  • 1
    • 0001669336 scopus 로고
    • Living coordination polymerization of propene initiated by the soluble tris(acetylacetonato)vanadium-chlorodiethylaluminum system
    • Doi, Y., Ueki, S. & Keii, T. Living coordination polymerization of propene initiated by the soluble tris(acetylacetonato)vanadium- chlorodiethylaluminum system. Macromolecules 12, 814-811 (1979).
    • (1979) Macromolecules , vol.12 , pp. 814-811
    • Doi, Y.1    Ueki, S.2    Keii, T.3
  • 2
    • 0022490556 scopus 로고
    • Synthesis of 'living' polyolefins with soluble ziegler-natta catalysts and application to block copolymerization
    • Doi, Y. & Keii, T. Synthesis of 'living' polyolefins with soluble Ziegler-Natta catalysts and application to block copolymerization. Adv. Polym. Sci. 73-74, 201-248 (1986). (Pubitemid 16520856)
    • (1986) Advances in Polymer Science , pp. 201-248
    • Doi Yoshiharu1    Keii Tominaga2
  • 4
    • 0000662343 scopus 로고    scopus 로고
    • New polymers by metallocene catalysis
    • Kaminsky, W. New polymers by metallocene catalysis. Macromol. Phys. Chem. 197, 3907-3945 (1996). (Pubitemid 126504577)
    • (1996) Macromolecular Chemistry and Physics , vol.197 , Issue.12 , pp. 3907-3945
    • Kaminsky, W.1
  • 5
    • 0033557814 scopus 로고    scopus 로고
    • The search for new-generation olefin polymerization catalysts: Life beyond metallocenes
    • DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0. CO;2-3
    • Britovsek, G. J. P., Gibson, V. C. & Wass, D. F. The search for new-generation olefin polymerization catalysts: life beyond metallocenes. Angew. Chem. Int. Ed. Engl. 38, 428-447 (1999). (Pubitemid 29095490)
    • (1999) Angewandte Chemie - International Edition , vol.38 , Issue.4 , pp. 428-447
    • Britovsek, G.J.P.1    Gibson, V.C.2    Wass, D.F.3
  • 6
    • 0033752160 scopus 로고    scopus 로고
    • Precise control of polyolefin stereochemistry using single-site metal catalysts
    • Coates, G. W. Precise control of polyolefin stereochemistry using single-site metal catalysts. Chem. Rev. 100, 1223-1252 (2000).
    • (2000) Chem. Rev. , vol.100 , pp. 1223-1252
    • Coates, G.W.1
  • 7
    • 0037240069 scopus 로고    scopus 로고
    • Advances in non-metallocene olefin polymerization catalysis
    • Gibson, V. C. & Spitzmesser, S. K. Advances in non-metallocene olefin polymerization catalysis. Chem. Rev. 103, 283-315 (2003).
    • (2003) Chem. Rev. , vol.103 , pp. 283-315
    • Gibson, V.C.1    Spitzmesser, S.K.2
  • 8
    • 0037007888 scopus 로고    scopus 로고
    • Catalysts for the living insertion polymerization of alkenes: Access to new polyolefin architectures using Ziegler-Natta chemistry
    • DOI 10.1002/1521-3773(20020703)41:13<2236::AID-ANIE2236>3.0.CO;2-3
    • Coates, G. W., Hustad, P. D. & Reinartz, S. Catalysts for the living insertion polymerization of alkenes: access to new polyolefin architectures using Ziegler-Natta chemistry. Angew. Chem. Int. Ed. Engl. 41, 2236-2257 (2002). (Pubitemid 34778537)
    • (2002) Angewandte Chemie - International Edition , vol.41 , Issue.13 , pp. 2236-2257
    • Coates, G.W.1    Hustad, P.D.2    Reinartz, S.3
  • 9
    • 84885725198 scopus 로고    scopus 로고
    • Living transition metal-catalyzed alkene polymerization: Polyolefin synthesis and new polymer architectures
    • As the best recent review (eds Müller A. H. E & Matzjasyewski, K.) Ch. 4 (Wiley-VCH: Weinheim
    • As the best recent review. Edson, J. B., Domski, G. J., Rose, J. M., Bolig, A. D., Brookhart, M. & Coates, G. W. Living transition metal-catalyzed alkene polymerization: polyolefin synthesis and new polymer architectures. in Controlled and Living Polymerizations (eds Müller A. H. E & Matzjasyewski, K.) Ch. 4, 167-239 (Wiley-VCH: Weinheim, 2009).
    • (2009) Controlled and Living Polymerizations , pp. 167-239
    • Edson, J.B.1    Domski, G.J.2    Rose, J.M.3    Bolig, A.D.4    Brookhart, M.5    Coates, G.W.6
  • 10
    • 0025400943 scopus 로고
    • Scandium complex [{(Z5- C5Me4)Me2Si(Z1-NCMe3)(PMe3)ScH]2: A unique example of a single-component aolefin polymerization catalyst
    • Shapiro, P. J., Bunel, E., Schaefer, W. P. & Bercaw, J. E. Scandium complex [{(Z5- C5Me4)Me2Si(Z1-NCMe3)(PMe3)ScH]2: a unique example of a single-component aolefin polymerization catalyst. Organometallics 9, 867-869 (1990).
    • (1990) Organometallics , vol.9 , pp. 867-869
    • Shapiro, P.J.1    Bunel, E.2    Schaefer, W.P.3    Bercaw, J.E.4
  • 11
    • 4544234770 scopus 로고
    • Functionalized cyclopentadienyl ligands. IV. Synthesis and complexation of linked cyclopentadienyl-amido ligands
    • Okuda, J. Functionalized cyclopentadienyl ligands. IV. Synthesis and complexation of linked cyclopentadienyl-amido ligands. Chem. Ber. 123, 1649-1651 (1990).
    • (1990) Chem. Ber. , vol.123 , pp. 1649-1651
    • Okuda, J.1
  • 12
    • 0032203250 scopus 로고    scopus 로고
    • Group 4 ansa-cyclopentadienyl-amido catalysts for olefin polymerization
    • McKnight, A. L. & Waymouth, R. M. Group 4 ansa-cyclopentadienyl-amido catalysts for olefin polymerization. Chem. Rev. 98, 2587-2598 (1998). (Pubitemid 128620328)
    • (1998) Chemical Reviews , vol.98 , Issue.7 , pp. 2587-2598
    • McKnight, A.L.1    Waymouth, R.M.2
  • 13
    • 0031210257 scopus 로고    scopus 로고
    • 2-based catalysts by chain-end controlled mechanism
    • Hagihara, H., Shiono, T. & Ikeda, T. Syndiospecific polymerization of propene with [t-BuNSiMe2Flu]TiMe2-based catalysts by chain-end controlled mechanism. Macromolecules 30, 4783-4785 (1997). (Pubitemid 127569614)
    • (1997) Macromolecules , vol.30 , Issue.16 , pp. 4783-4785
    • Hagihara, H.1    Shiono, T.2    Ikeda, T.3
  • 15
    • 28844505759 scopus 로고    scopus 로고
    • Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes
    • DOI 10.1016/j.jorganchem.2005.08.027, PII S0022328X05006881
    • Nishii, K., Hagihara, H., Ikeda, T., Akita, M. & Shiono, T. Stereospecific polymerization of propylene with group 4 ansa- fluorenylamidodimethyl complexes. J. Organometal. Chem. 691, 193-201 (2006). (Pubitemid 41767452)
    • (2006) Journal of Organometallic Chemistry , vol.691 , Issue.1-2 , pp. 193-201
    • Nishii, K.1    Hagihara, H.2    Ikeda, T.3    Akita, M.4    Shiono, T.5
  • 16
    • 26944469589 scopus 로고    scopus 로고
    • Substituent effects of tert-butyl groups on fluorenyl ligand in syndiospecific living polymerization of propylene with ansa- fluorenylamidodimethyltitanium complex
    • DOI 10.1021/ma050898i
    • Cai, Z., Ikeda, T., Akita, M. & Shiono, T. Substituent effects of tert-butyl groups on fluorenyl ligand in syndiospecific living polymerization of propylene with ansa-fluorenylamidodimethyltitanium complex. Macromolecules 38, 8135-8139 (2005). (Pubitemid 41476074)
    • (2005) Macromolecules , vol.38 , Issue.20 , pp. 8135-8139
    • Cai, Z.1    Ikeda, T.2    Akita, M.3    Shiono, T.4
  • 17
    • 77952523918 scopus 로고    scopus 로고
    • A highly activecatalyst composed of ansa-fluorenylamidodimethyltitanium derivative for propene polymerization
    • Shiono, T., Harada, R., Cai, Z. & Nakayama, Y. A highly activecatalyst composed of ansa-fluorenylamidodimethyltitanium derivative for propene polymerization. Top. Catal. 52, 675-680 (2009).
    • (2009) Top. Catal. , vol.52 , pp. 675-680
    • Shiono, T.1    Harada, R.2    Cai, Z.3    Nakayama, Y.4
  • 18
    • 14844335717 scopus 로고    scopus 로고
    • 2-MAO catalyst systems
    • DOI 10.1016/j.molcata.2004.12.035, PII S1381116905000518
    • Nishii, K., Ikeda, T., Akita, M. & Shiono, T. Polymerization of propylene with [t- BuNSiMe2Ind]TiMe2-MAO catalyst systems. J. Mol. Catal. A Chem. 231, 241-246 (2005). (Pubitemid 40348740)
    • (2005) Journal of Molecular Catalysis A: Chemical , vol.231 , Issue.1-2 , pp. 241-246
    • Nishii, K.1    Ikeda, T.2    Akita, M.3    Shiono, T.4
  • 19
    • 0032073280 scopus 로고    scopus 로고
    • Living polymerization of propene and 1-hexene with the [t-BuNSiMe2Flu]TiMe2/B(C6F5)3 catalyst
    • Hagihara, H., Shiono, T. & Ikeda, T. Living polymerization of propene and 1-hexene with the [t-BuNSiMe2Flu]TiMe2/B(C6F5)3 catalyst. Macromolecules 31, 3184-3188 (1998).
    • (1998) Macromolecules , vol.31 , pp. 3184-3188
    • Hagihara, H.1    Shiono, T.2    Ikeda, T.3
  • 20
    • 0033740669 scopus 로고    scopus 로고
    • Cocatalysts for metal-catalyzed olefin polymerization: Activators, activation processes, and structure-activity relationships
    • Chen, E. Y.- X. & Marks, T. J. Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure-activity relationships. Chem. Rev. 100, 1391-1434 (2000).
    • (2000) Chem. Rev. , vol.100 , pp. 1391-1434
    • Chen, E.Y.-X.1    Marks, T.J.2
  • 21
    • 0001249879 scopus 로고    scopus 로고
    • Kinetic features in living polymerization of propene with the [t-BuNSiMe2Flu]TiMe2/B(C6F5)3 catalyst
    • (ed. W Kaminsky) Ch. 3 (Springer-Verlag, Berlin Heidelberg
    • Shiono, T., Yoshida, S., Hagihara, H. & Ikeda, T. Kinetic features in living polymerization of propene with the [t-BuNSiMe2Flu]TiMe2/B(C6F5)3 catalyst. in Metalorganic Catalysts for Synthesis and Polymerization (ed. W Kaminsky) Ch. 3, 264-273 (Springer-Verlag, Berlin Heidelberg, 1999).
    • (1999) Metalorganic Catalysts for Synthesis and Polymerization , pp. 264-273
    • Shiono, T.1    Yoshida, S.2    Hagihara, H.3    Ikeda, T.4
  • 22
    • 0034726229 scopus 로고    scopus 로고
    • Additive effects of trialkylaluminum on propene polymerization with (t-BuNSiMe2Flu)TiMe2-based catalysts
    • Shiono, T., Yoshida, S., Hagihara, H. & Ikeda, T. Additive effects of trialkylaluminum on propene polymerization with (t-BuNSiMe2Flu)TiMe2-based catalysts. Appl. Catal. A Gen. 200, 145-152 (2000).
    • (2000) Appl. Catal. A Gen. , vol.200 , pp. 145-152
    • Shiono, T.1    Yoshida, S.2    Hagihara, H.3    Ikeda, T.4
  • 23
    • 0029999491 scopus 로고    scopus 로고
    • Living polymerization of α-olefins by chelating diamide complexes of titanium
    • DOI 10.1021/ja9618964, PII S0002786396018963
    • Scollard, J. D. & McConville, D. H. Living polymerization of alpha -olefins by chelating diamide complexes of titanium. J. Am. Chem. Soc. 118, 10008-10009 (1996). (Pubitemid 26366093)
    • (1996) Journal of the American Chemical Society , vol.118 , Issue.41 , pp. 10008-10009
    • Scollard, J.D.1    McConville, D.H.2
  • 24
    • 0006366786 scopus 로고    scopus 로고
    • 5 bond
    • Scollard, J. D., McConville, D. H. & Rettig, S. J. Living polymerization of a-olefins: catalyst precursor deactivation via the unexpected cleavage of a B-C6F5 bond. Organometallics 16, 1810-1812 (1997). (Pubitemid 127593365)
    • (1997) Organometallics , vol.16 , Issue.8 , pp. 1810-1812
    • Scollard, J.D.1    McConville, D.H.2    Rettig, S.J.3
  • 25
    • 0030191607 scopus 로고    scopus 로고
    • Polymerization of a-olefins by chelating diamide complexes of titanium
    • Scollard, J. D., McConville, D. H., Payne, N. C. & Vittal, J. J. Polymerization of a-olefins by chelating diamide complexes of titanium. Macromolecules 29, 5241-5243 (1996).
    • (1996) Macromolecules , vol.29 , pp. 5241-5243
    • Scollard, J.D.1    McConville, D.H.2    Payne, N.C.3    Vittal, J.J.4
  • 26
    • 0035827022 scopus 로고    scopus 로고
    • 2 using MAO as cocatalyst
    • DOI 10.1021/ma0017438
    • Hasan, T., Ioku, A., Nishii, K., Shiono, T. & Ikeda, T. Syndiospecific living polymerization of propene with [t-BuNSiMe2Flu]TiMe2 using MAO as cocatalyst. Macromolecules 34, 3142-3145 (2001). (Pubitemid 34216932)
    • (2001) Macromolecules , vol.34 , Issue.10 , pp. 3142-3145
    • Hasan, T.1    Ioku, A.2    Nishii, K.3    Shiono, T.4    Ikeda, T.5
  • 27
    • 0037088495 scopus 로고    scopus 로고
    • Effects of cocatalysts on propene polymerization with [t-BuNSiMe2Flu]TiMe2
    • Ioku, A., Hasan, T., Shiono, T. & Ikeda, T. Effects of cocatalysts on propene polymerization with [t-BuNSiMe2Flu]TiMe2. Macromol. Chem. Phys. 203, 748-755 (2002).
    • (2002) Macromol. Chem. Phys. , vol.203 , pp. 748-755
    • Ioku, A.1    Hasan, T.2    Shiono, T.3    Ikeda, T.4
  • 28
    • 0036002677 scopus 로고    scopus 로고
    • Living polymerization of propene with a chelating diamide complex of titanium using dried methylaluminoxane
    • Hagimoto, H., Shiono, T. & Ikeda, T. Living polymerization of propene with a chelating diamide complex of titanium using dried methylaluminoxane. Macromol. Rapid Commun. 23, 73-76 (2002).
    • (2002) Macromol. Rapid Commun. , vol.23 , pp. 73-76
    • Hagimoto, H.1    Shiono, T.2    Ikeda, T.3
  • 29
    • 1142286741 scopus 로고    scopus 로고
    • Supporting effects of methylaluminoxane on the living polymerization of propylene with a chelating (diamide)dimethyltitanium complex
    • Hagimoto, H., Shiono, T. & Ikeda, T. Supporting effects of methylaluminoxane on the living polymerization of propylene with a chelating (diamide)dimethyltitanium complex. Macromol. Chem. Phys. 205, 19-26 (2004).
    • (2004) Macromol. Chem. Phys. , vol.205 , pp. 19-26
    • Hagimoto, H.1    Shiono, T.2    Ikeda, T.3
  • 30
    • 4544272426 scopus 로고    scopus 로고
    • Effect of solvents on living polymerization of propylene with [t-BuNSiMe2Flu]TiMe2-MMAO catalyst system
    • Nishii, K., Matsumae, T., Dare, E. O., Shiono, T. & Ikeda, T. Effect of solvents on living polymerization of propylene with [t-BuNSiMe2Flu]TiMe2-MMAO catalyst system. Macromol. Chem. Phys. 205, 363-369 (2004).
    • (2004) Macromol. Chem. Phys. , vol.205 , pp. 363-369
    • Nishii, K.1    Matsumae, T.2    Dare, E.O.3    Shiono, T.4    Ikeda, T.5
  • 31
    • 0000076520 scopus 로고
    • Elementary processes in Ziegler catalysis. 5. Solvent effect on a stereospecific zirconocene/methylaluminoxane Ziegler catalyst
    • Herfert, N. & Fink, G. Elementary processes in Ziegler catalysis. 5. Solvent effect on a stereospecific zirconocene/methylaluminoxane Ziegler catalyst. Makromol. Chem. 193, 773-778 (1992).
    • (1992) Makromol. Chem. , vol.193 , pp. 773-778
    • Herfert, N.1    Fink, G.2
  • 32
    • 0031165424 scopus 로고    scopus 로고
    • Selectivity in propylene polymerization with group 4 Cp-amido catalysts
    • McKnight, A. L., Masood, M. A., Waymouth, R. M. & Straus, D. A. Selectivity in propylene polymerization with group 4 Cp-amido catalysts. Organometallics 16, 2879-2885 (1997). (Pubitemid 127645808)
    • (1997) Organometallics , vol.16 , Issue.13 , pp. 2879-2885
    • McKnight, A.L.1    Masood, Md.A.2    Waymouth, R.M.3    Straus, D.A.4
  • 33
    • 0001354488 scopus 로고
    • A perfect initiator for 'living' coordination polymerization of propene: Tris(2-methyl-1,3-butanedionato)vanadium/diethylaluminum chloride system
    • Doi, Y., Suzuki, S. & Soga, K. A perfect initiator for 'living' coordination polymerization of propene: tris(2-methyl-1,3-butanedionato) vanadium/diethylaluminum chloride system. Makromol. Chem. Rapid Commun. 6, 639-642 (1985).
    • (1985) Makromol. Chem. Rapid Commun. , vol.6 , pp. 639-642
    • Doi, Y.1    Suzuki, S.2    Soga, K.3
  • 34
    • 0035965694 scopus 로고    scopus 로고
    • Strong ion pairing effects on single-site olefin polymerization: Mechanistic insights in syndiospecific propylene enchainment [4]
    • DOI 10.1021/ja011558p
    • Chen, M.- C. & Marks, T. J. Strong ion pairing effects on single-site olefin polymerization: mechanistic insights in syndiospecific propylene enchainment. J. Am. Chem. Soc. 123, 11803-11804 (2001). (Pubitemid 33121803)
    • (2001) Journal of the American Chemical Society , vol.123 , Issue.47 , pp. 11803-11804
    • Chen, M.-C.1    Marks, T.J.2
  • 35
    • 0038575130 scopus 로고    scopus 로고
    • Metallocenecatalyzed propene polymerization: From microstructure to kinetics Cs-Symmetric ansa- Zirconocenes
    • Busico, V., Cipullo, R., Cutillo, F., Vacatello, M. & Castelli, V. V. A. Metallocenecatalyzed propene polymerization: from microstructure to kinetics Cs-Symmetric ansa- Zirconocenes. Macromolecules 36, 4258-4261 (2003).
    • (2003) Macromolecules , vol.36 , pp. 4258-4261
    • Busico, V.1    Cipullo, R.2    Cutillo, F.3    Vacatello, M.4    Castelli, V.V.A.5
  • 36
    • 33845279950 scopus 로고
    • Syndiospecific propylene polymerizations with Group IVB metallocenes
    • Ewen, J. A., Jones, R. L., Razavi, A. & Ferrara, J. D. Syndiospecific propylene polymerizations with Group IVB metallocenes. J. Am. Chem. Soc. 110, 6255-6256 (1988).
    • (1988) J. Am. Chem. Soc. , vol.110 , pp. 6255-6256
    • Ewen, J.A.1    Jones, R.L.2    Razavi, A.3    Ferrara, J.D.4
  • 37
    • 2342426952 scopus 로고    scopus 로고
    • Highly stereoregular syndiotactic polypropylene formation with metallocene catalysts via influence of distal ligand substituents
    • Miller, S. A. & Bercaw, J. E. Highly stereoregular syndiotactic polypropylene formation with metallocene catalysts via influence of distal ligand substituents. Organometallics 23, 1777-1789 (2004).
    • (2004) Organometallics , vol.23 , pp. 1777-1789
    • Miller, S.A.1    Bercaw, J.E.2
  • 38
    • 22244480090 scopus 로고    scopus 로고
    • 1-amido zirconium complex
    • DOI 10.1021/ja052256g
    • Irwin, L. J. & Miller, S. A. Unprecedented syndioselectivity and syndiotactic polyolefin melting temperature: polypropylene and poly(4-methyl-1-pentene) from a highly active, sterically expanded Z1-fluorenyl- Z1-amido zirconium complex. J. Am. Chem. Soc. 127, 9972-9973 (2005). (Pubitemid 40995421)
    • (2005) Journal of the American Chemical Society , vol.127 , Issue.28 , pp. 9972-9973
    • Irwin, L.J.1    Miller, S.A.2
  • 39
    • 11244272932 scopus 로고    scopus 로고
    • A sterically expanded "Constrained Geometry Catalyst" for highly active olefin polymerization and copolymerization: An unyielding comonomer effect
    • DOI 10.1021/ja044678g
    • Irwin, L. J., Reibenspies, J. H. & Miller, S. A. A sterically expanded 'constrained geometry catalyst' for highly active olefin polymerization and copolymerization: an unyielding comonomer effect. J. Am. Chem. Soc. 126, 16716-16717 (2004). (Pubitemid 40069478)
    • (2004) Journal of the American Chemical Society , vol.126 , Issue.51 , pp. 16716-16717
    • Irwin, L.J.1    Reibenspies, J.H.2    Miller, S.A.3
  • 40
    • 48249126230 scopus 로고    scopus 로고
    • Highly active copolymerization of ethylene and dicyclopentadiene with [(Z1-t-BuN)SiMe2 (Z1-C29H36)]TiMe2(THF) complex
    • Nishii, K., Hayano, S., Tsunogae, Y., Cai, Z., Nakayama, Y. & Shiono, T. Highly active copolymerization of ethylene and dicyclopentadiene with [(Z1-t-BuN)SiMe2 (Z1-C29H36)]TiMe2(THF) complex. Chem. Lett. 37, 590-591 (2008).
    • (2008) Chem. Lett. , vol.37 , pp. 590-591
    • Nishii, K.1    Hayano, S.2    Tsunogae, Y.3    Cai, Z.4    Nakayama, Y.5    Shiono, T.6
  • 41
    • 0003022727 scopus 로고    scopus 로고
    • Fluorenyl complexes of zirconium and hafnium as catalysts for olefin polymerization
    • Alt, H. G. & Samuel, E. Fluorenyl complexes of zirconium and hafnium as catalysts for olefin polymerization. Chem. Soc. Rev. 27, 323-329 (1998). (Pubitemid 128653114)
    • (1998) Chemical Society Reviews , vol.27 , Issue.5 , pp. 323-329
    • Alt, H.G.1    Samuel, E.2
  • 42
    • 0035533955 scopus 로고    scopus 로고
    • Highly syndiospecific living polymerization of propylene using a titanium complex having two phenoxy-imine chelate ligands
    • Saito, J., Mitani, M., Mohri, J., Ishii, S., Yoshida, Y., Matsugi, T., Kojoh, S., Kashiwa, N. & Fujita, T. Highly syndiospecific living polymerization of propylene using a titanium complex having two phenoxy-imine chelate ligands. Chem. Lett. 30, 576-578 (2001).
    • (2001) Chem. Lett. , vol.30 , pp. 576-578
    • Saito, J.1    Mitani, M.2    Mohri, J.3    Ishii, S.4    Yoshida, Y.5    Matsugi, T.6    Kojoh, S.7    Kashiwa, N.8    Fujita, T.9
  • 43
    • 34248188762 scopus 로고    scopus 로고
    • Living olefin polymerization and block copolymer formation with FI catalysts
    • DOI 10.1295/polymj.PJ2006152
    • Sakuma, A., Weiser, M.- S. & Fujita, T. Living olefin polymerization and block copolymer formation with FI catalysts. Polym. J. 39, 193-207 (2007). (Pubitemid 46707068)
    • (2007) Polymer Journal , vol.39 , Issue.3 , pp. 193-207
    • Sakuma, A.1    Weiser, M.-S.2    Fujita, T.3
  • 44
    • 0034808791 scopus 로고    scopus 로고
    • A new catalyst for highly syndiospecific living olefin polymerization: Homopolymers and block copolymers from ethylene and propylene
    • DOI 10.1021/ja0157189
    • Tian, J., Hustad, P. D. & Coates, G. W. A new catalyst for highly syndiospecific living olefin polymerization: homopolymers and block copolymers from ethylene and propylene. J. Am. Chem. Soc. 123, 5134-5135 (2001). (Pubitemid 32905684)
    • (2001) Journal of the American Chemical Society , vol.123 , Issue.21 , pp. 5134-5135
    • Tian, J.1    Hustad, P.D.2    Coates, G.W.3
  • 45
    • 0037055030 scopus 로고    scopus 로고
    • Fluorine- and trimethylsilyl-containing phenoxy-imine Ti complex for highly syndiotactic living polypropylenes with extremely high melting temperatures
    • DOI 10.1021/ja026229r
    • Mitani, M., Furuyama, R., Mohri, J.- I., Saito, J., Ishii, S., Terao, H., Kashiwa, N. & Fujita, T. Fluorine- and trimethylsilyl-containing phenoxy-imine Ti complex for highly syndiotactic living polypropylenes with extremely high melting temperatures. J. Am. Chem. Soc. 124, 7888-7889 (2002). (Pubitemid 34755495)
    • (2002) Journal of the American Chemical Society , vol.124 , Issue.27 , pp. 7888-7889
    • Mitani, M.1    Furuyama, R.2    Mohri, J.-I.3    Saito, J.4    Ishii, S.5    Terao, H.6    Kashiwa, N.7    Fujita, T.8
  • 47
    • 70350765054 scopus 로고    scopus 로고
    • Highly active syndiospecific living polymerization of higher 1-alkene with ansa-fluorenylamidodimethyltitanium complex
    • Cai, Z., Ohmagari, M., Nakayama, Y. & Shiono, T. Highly active syndiospecific living polymerization of higher 1-alkene with ansa-fluorenylamidodimethyltitanium complex. Macromol. Rapid Commun. 30, 1812-1816 (2009).
    • (2009) Macromol. Rapid Commun. , vol.30 , pp. 1812-1816
    • Cai, Z.1    Ohmagari, M.2    Nakayama, Y.3    Shiono, T.4
  • 48
    • 4544325855 scopus 로고    scopus 로고
    • A novel synthetic procedure for stereoblock poly(propylene) with a living polymerization system
    • Nishii, K., Shiono, T. & Ikeda, T. A novel synthetic procedure for stereoblock poly(propylene) with a living polymerization system. Macromol. Rapid Commun. 25, 1029-1031 (2004).
    • (2004) Macromol. Rapid Commun. , vol.25 , pp. 1029-1031
    • Nishii, K.1    Shiono, T.2    Ikeda, T.3
  • 49
    • 33745243703 scopus 로고    scopus 로고
    • Synthesis of crystallizable sydiotactic-atactic stereoblock polypropylene using a living polymerization system
    • Cai, Z., Nakayama, Y. & Shiono, T. Synthesis of crystallizable sydiotactic-atactic stereoblock polypropylene using a living polymerization system. Kinet. Catal. 47, 274-277 (2006).
    • (2006) Kinet. Catal. , vol.47 , pp. 274-277
    • Cai, Z.1    Nakayama, Y.2    Shiono, T.3
  • 50
    • 78149334433 scopus 로고    scopus 로고
    • Synthesis of stereoblock polypropylene by change of temperature in living polymerization
    • Cai, Z., Nakayama, Y. & Shiono, T. Synthesis of stereoblock polypropylene by change of temperature in living polymerization. Macromol. Res. 18, 737-741 (2010).
    • (2010) Macromol. Res. , vol.18 , pp. 737-741
    • Cai, Z.1    Nakayama, Y.2    Shiono, T.3
  • 51
    • 52449094197 scopus 로고    scopus 로고
    • Facile synthesis of tailor-made stereoblock polypropylenes via successive variation of monomer pressure
    • Cai, Z., Nakayama, Y. & Shiono, T. Facile synthesis of tailor-made stereoblock polypropylenes via successive variation of monomer pressure. Macromolecules 41, 6596-6598 (2008).
    • (2008) Macromolecules , vol.41 , pp. 6596-6598
    • Cai, Z.1    Nakayama, Y.2    Shiono, T.3
  • 52
    • 79953698016 scopus 로고    scopus 로고
    • Polypropylene polymerization-synthesis of elastomeric polypropylene
    • Shmulinson, M. & Eisen, M. Polypropylene polymerization-synthesis of elastomeric polypropylene. J. Am. Chem. Soc. 125, 2179-2194 (2003).
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 2179-2194
    • Shmulinson, M.1    Eisen, M.2
  • 53
    • 0035533124 scopus 로고    scopus 로고
    • The vinyl homopolymerization of norbornene
    • DOI 10.1002/1521-3927(20010401)22:7<479::AID-MARC479>3.0.CO;2-C
    • Janiak, C. & Lassahn, P. G. The vinyl homopolymerization of norbornene. Macromol. Rapid Commun. 22, 479-492 (2001). (Pubitemid 33279372)
    • (2001) Macromolecular Rapid Communications , vol.22 , Issue.7 , pp. 479-492
    • Janiak, C.1    Lassahn, P.G.2
  • 54
    • 61349101920 scopus 로고    scopus 로고
    • Metal catalysts for the vinyl/addition polymerization of norbornene
    • Blank, F. & Janiak, C. Metal catalysts for the vinyl/addition polymerization of norbornene. Coord. Chem. Rev. 253, 827-861 (2009).
    • (2009) Coord. Chem. Rev. , vol.253 , pp. 827-861
    • Blank, F.1    Janiak, C.2
  • 55
    • 0037137398 scopus 로고    scopus 로고
    • Living polymerization of norbornene via vinyl addition with ansa-fluorenylamidodimethyltitanium complex
    • DOI 10.1021/ma025586j
    • Hasan, T., Nishii, K., Shiono, T. & Ikeda, T. Living polymerization of norbornene via vinyl addition with ansa-fluorenylamidodimethyltitanium complex. Macromolecules 35, 8933-8935 (2002). (Pubitemid 35421914)
    • (2002) Macromolecules , vol.35 , Issue.24 , pp. 8933-8935
    • Hasan, T.1    Nishii, K.2    Shiono, T.3    Ikeda, T.4
  • 56
    • 6344230140 scopus 로고    scopus 로고
    • Highly efficient Ti-based catalyst systems for vinyl addition polymerization of norbornene
    • Hasan, T., Ikeda, T. & Shiono, T. Highly efficient Ti-based catalyst systems for vinyl addition polymerization of norbornene. Macromolecules 37, 7432-7436 (2004).
    • (2004) Macromolecules , vol.37 , pp. 7432-7436
    • Hasan, T.1    Ikeda, T.2    Shiono, T.3
  • 57
    • 70449642958 scopus 로고    scopus 로고
    • Recent progress in the vinylic polymerization and copolymerization of norbornene catalyzed by transition metal catalysts
    • Ma, R., Hou, Y., Gao, J. & Bao, F. Recent progress in the vinylic polymerization and copolymerization of norbornene catalyzed by transition metal catalysts. Polym. Rev. 49, 249-287 (2009).
    • (2009) Polym. Rev. , vol.49 , pp. 249-287
    • Ma, R.1    Hou, Y.2    Gao, J.3    Bao, F.4
  • 58
    • 0642305148 scopus 로고    scopus 로고
    • Polyolefins with high glass transition temperatures
    • Henschke, O., Koller, F. & Arnold, M. Polyolefins with high glass transition temperatures. Macromol. Rapid Commun. 18, 617-623 (1997).
    • (1997) Macromol. Rapid Commun. , vol.18 , pp. 617-623
    • Henschke, O.1    Koller, F.2    Arnold, M.3
  • 59
    • 0037853129 scopus 로고    scopus 로고
    • Propene-norbornene copolymers: Synthesis and analysis of polymer structure by 13C NMR spectroscopy and ab initio chemical shift computations
    • Boggioni, L., Bertini, F., Zannoni, G., Tritto, I., Carbone, P., Ragazzi, M. & Ferro, D. R. Propene-norbornene copolymers: synthesis and analysis of polymer structure by 13C NMR spectroscopy and ab initio chemical shift computations. Macromolecules 36, 882-890 (2003).
    • (2003) Macromolecules , vol.36 , pp. 882-890
    • Boggioni, L.1    Bertini, F.2    Zannoni, G.3    Tritto, I.4    Carbone, P.5    Ragazzi, M.6    Ferro, D.R.7
  • 60
    • 36248950240 scopus 로고    scopus 로고
    • Copolymerization of propylene and norbornene with different metallocene catalysts
    • DOI 10.1016/j.polymer.2007.10.013, PII S0032386107009925
    • Kaminsky, W., Derlin, S. & Hoff, M. Copolymerization of propylene and norbornene with different metallocene catalysts. Polymer 48, 7271-7278 (2007). (Pubitemid 350137430)
    • (2007) Polymer , vol.48 , Issue.25 , pp. 7271-7278
    • Kaminsky, W.1    Derlin, S.2    Hoff, M.3
  • 61
    • 22744456887 scopus 로고    scopus 로고
    • Norbornene copolymerization with α-olefins using methylene-bridged ansa-zirconocene
    • DOI 10.1016/j.poly.2005.02.019, PII S0277538705001063
    • Jung, H. Y., Hong, S.- D., Jung, M. W., Lee, H. & Park, Y.- W. Norbornene copolymerization with a-olefins using methylene-bridged ansa-zirconocene. Polyhedron 24, 1269-1273 (2005). (Pubitemid 41033080)
    • (2005) Polyhedron , vol.24 , Issue.11 , pp. 1269-1273
    • Hye, Y.J.1    Hong, S.-D.2    Min, W.J.3    Lee, H.4    Park, Y.-W.5
  • 62
    • 34547865381 scopus 로고    scopus 로고
    • Tailored branched polyolefins by metallocene catalysis
    • DOI 10.1002/macp.200700053
    • Kaminsky, W., Hoff, M. & Derlin, S. Tailored branched polyolefins by metallocene catalysis. Macromol. Chem. Phys. 208, 1341-1348 (2007). (Pubitemid 47252137)
    • (2007) Macromolecular Chemistry and Physics , vol.208 , Issue.13 , pp. 1341-1348
    • Kaminsky, W.1    Matthias Hoff, S.D.2
  • 63
    • 35248838240 scopus 로고    scopus 로고
    • Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene
    • DOI 10.1039/b708534f
    • Li, X., Nishiura, M., Mori, K., Mashiko, T. & Hou, Z. Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene. Chem. Commun. 28, 4137-4139 (2007). (Pubitemid 47561640)
    • (2007) Chemical Communications , Issue.40 , pp. 4137-4139
    • Li, X.1    Nishiura, M.2    Mori, K.3    Mashiko, T.4    Hou, Z.5
  • 64
    • 9744230766 scopus 로고    scopus 로고
    • Ethene-norbornene copolymer with high norbornene content produced by ansa-fluorenylamidodimethyltitanium complex using a suitable activator
    • Hasan, T., Ikeda, T. & Shiono, T. Ethene-norbornene copolymer with high norbornene content produced by ansa-fluorenylamidodimethyltitanium complex using a suitable activator. Macromolecules 37, 8503-8509 (2004).
    • (2004) Macromolecules , vol.37 , pp. 8503-8509
    • Hasan, T.1    Ikeda, T.2    Shiono, T.3
  • 65
    • 0032637858 scopus 로고    scopus 로고
    • Ethylene/norbornene copolymerizations with titanium CpA catalysts
    • McKnight, A. L. & Waymouth, R. M. Ethylene/norbornene copolymerizations with titanium CpA catalysts. Macromolecules 32, 2816-2825 (1999).
    • (1999) Macromolecules , vol.32 , pp. 2816-2825
    • McKnight, A.L.1    Waymouth, R.M.2
  • 66
    • 4644328164 scopus 로고    scopus 로고
    • Living random copolymerization of ethene and norbornene using ansa-fluorenylamidodimethyltitanium complex
    • Hasan, T., Shiono, T. & Ikeda, T. Living random copolymerization of ethene and norbornene using ansa-fluorenylamidodimethyltitanium complex. Macromol. Symp. 213, 123-129 (2004).
    • (2004) Macromol. Symp. , vol.213 , pp. 123-129
    • Hasan, T.1    Shiono, T.2    Ikeda, T.3
  • 67
    • 14644388139 scopus 로고    scopus 로고
    • Random copolymerization of propene and norbornene with ansa- fluorenylamidodimethyltitanium-based catalysts
    • DOI 10.1021/ma0481171
    • Hasan, T., Ikeda, T. & Shiono, T. Random copolymerization of propene and norbornene with ansa-fluorenylamidodimethyltitanium-based catalysts. Macromolecules 38, 1071-1074 (2005). (Pubitemid 40308161)
    • (2005) Macromolecules , vol.38 , Issue.4 , pp. 1071-1074
    • Hasan, T.1    Ikeda, T.2    Shiono, T.3
  • 68
    • 77952539947 scopus 로고    scopus 로고
    • Highly active living random copolymerization of norbornene and 1-alkene with ansa-fluorenylamidodimethyl titanium derivative: Substituent effects on fluorenyl ligand
    • Cai, Z., Harada, R., Nakayama, Y. & Shiono, T. Highly active living random copolymerization of norbornene and 1-alkene with ansa- fluorenylamidodimethyl titanium derivative: substituent effects on fluorenyl ligand. Macromolecules 43, 4527-4531 (2010).
    • (2010) Macromolecules , vol.43 , pp. 4527-4531
    • Cai, Z.1    Harada, R.2    Nakayama, Y.3    Shiono, T.4
  • 69
    • 0035953294 scopus 로고    scopus 로고
    • Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents
    • Forsyth, J., Perena, J. M., Benavente, R., Perez, E., Tritto, I., Boggioni, L. & Brintzinger, H.- H. Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents. Macromol. Chem. Phys. 202, 614-620 (2001).
    • (2001) Macromol. Chem. Phys. , vol.202 , pp. 614-620
    • Forsyth, J.1    Perena, J.M.2    Benavente, R.3    Perez, E.4    Tritto, I.5    Boggioni, L.6    Brintzinger - H, H.7
  • 70
    • 57349173573 scopus 로고    scopus 로고
    • Random copolymerization of norbornene with higher 1-alkene with ansa-fluorenylamidodimethyltitanium catalyst
    • Shiono, T., Sugimoto, M., Hasan, T., Cai, Z. & Ikeda, T. Random copolymerization of norbornene with higher 1-alkene with ansa- fluorenylamidodimethyltitanium catalyst. Macromolecules 41, 8292-8294 (2008).
    • (2008) Macromolecules , vol.41 , pp. 8292-8294
    • Shiono, T.1    Sugimoto, M.2    Hasan, T.3    Cai, Z.4    Ikeda, T.5
  • 71
    • 41449102806 scopus 로고    scopus 로고
    • 2: Practical production of ultrahigh to very low molecular weight amorphous atactic polypropenes of extremely narrow polydispersity
    • DOI 10.1021/ja078120v
    • Zhang, W. & Sita Lawrence, R. Highly efficient, living coordinative chain-transfer polymerization of propene with ZnEt2: practical production of ultrahigh to very low molecular weight amorphous atactic polypropenes of extremely narrow polydispersity. J. Am. Chem. Soc. 130, 442-443 (2008). (Pubitemid 351455549)
    • (2008) Journal of the American Chemical Society , vol.130 , Issue.2 , pp. 442-443
    • Zhang, W.1    Sita, L.R.2
  • 72
    • 56549100986 scopus 로고    scopus 로고
    • Living coordinative chain-transfer polymerization and copolymerization of ethene, a-olefins, and a,o-nonconjugated dienes using dialkylzinc as 'surrogate' chain-growth sites
    • Zhang, W., Wei, J. & Sita, L. R. Living coordinative chain-transfer polymerization and copolymerization of ethene, a-olefins, and a,o-nonconjugated dienes using dialkylzinc as 'surrogate' chain-growth sites. Macromolecules 41, 7829-7833 (2008).
    • (2008) Macromolecules , vol.41 , pp. 7829-7833
    • Zhang, W.1    Wei, J.2    Sita, L.R.3
  • 73
    • 33646444730 scopus 로고    scopus 로고
    • Catalytic production of olefin block copolymers via chain shuttling polymerization
    • Arriola, D. J., Carnahan, E. M., Hustad, P. D., Kuhlman, R. L. & Wenzel, T. T. Catalytic production of olefin block copolymers via chain shuttling polymerization. Science 312, 714-719 (2006).
    • (2006) Science , vol.312 , pp. 714-719
    • Arriola, D.J.1    Carnahan, E.M.2    Hustad, P.D.3    Kuhlman, R.L.4    Wenzel, T.T.5
  • 74
    • 35348836587 scopus 로고    scopus 로고
    • Continuous production of ethylene-based diblock copolymers using coordinative chain transfer polymerization
    • DOI 10.1021/ma0717791
    • Hustad, P. D., Kuhlman, R. L., Arriola, D. J., Carnahan, E. M. & Wenzel, T. T. Continuous production of ethylene-based diblock copolymers using coordinative chain transfer polymerization. Macromolecules 40, 7061-7064 (2007). (Pubitemid 47583046)
    • (2007) Macromolecules , vol.40 , Issue.20 , pp. 7061-7064
    • Hustad, P.O.1    Kuhlman, R.L.2    Arriola, D.J.3    Carnahan, E.M.4    Wenzel, T.T.5
  • 75
    • 0013217248 scopus 로고    scopus 로고
    • Combination system of fluorine-containing phenoxy-imine Ti complex and chain transfer agent: A new methodology for multiple production of monodisperse polymers
    • DOI 10.1246/cl.2003.238
    • Mitani, M., Mohri, J.-i., Furuyama, R., Ishii, S. & Fujita, T. Combination system of fluorine-containing phenoxy-imine Ti complex and chain transfer agent: a new methodology for multiple production of monodisperse polymers. Chem. Lett. 32, 238-239 (2003). (Pubitemid 36702955)
    • (2003) Chemistry Letters , vol.32 , Issue.3 , pp. 238-239
    • Mitani, M.1    Mohri, J.-I.2    Furuyama, R.3    Ishii, S.4    Fujita, T.5
  • 76
    • 33749652995 scopus 로고    scopus 로고
    • Catalytic synthesis of monodisperse polypropylene using a living polymerization system with ansa-fluorenylamidodimethyltitanium-based catalyst
    • DOI 10.1021/ma061244s
    • Cai, Z., Shigemasa, M., Nakayama, Y. & Shiono, T. Catalytic synthesis of monodisperse polypropylene using a living polymerization system with ansa-fluorenylamidodimethyltitanium- based catalyst. Macromolecules 39, 6321-6323 (2006). (Pubitemid 44555069)
    • (2006) Macromolecules , vol.39 , Issue.19 , pp. 6321-6323
    • Cai, Z.1    Shigemasa, M.2    Nakayama, Y.3    Shiono, T.4
  • 77
    • 52049116467 scopus 로고    scopus 로고
    • Catalytic synthesis of a monodisperse olefin block copolymer using a living polymerization system
    • Cai, Z., Nakayama, Y. & Shiono, T. Catalytic synthesis of a monodisperse olefin block copolymer using a living polymerization system. Macromol. Rapid Commun. 29, 525-529 (2008).
    • (2008) Macromol. Rapid Commun. , vol.29 , pp. 525-529
    • Cai, Z.1    Nakayama, Y.2    Shiono, T.3


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