Kinetics of structure II gas hydrate formation for propane and ethane using an in-situ particle size analyzer and a Raman spectrometer

Chemical Engineering Science

Volumn 66, Issue 11, 2011, Pages 2468-2474

  Al Otaibi, Faisal ^a   Clarke, Matthew ^a   Maini, Brij ^a   Bishnoi, P R ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

Crystallization; Formation; Gas hydrates; Kinetics; Particle size analysis; Raman spectroscopy

Indexed keywords

EQUIMOLAR MIXTURES; EXPERIMENTAL DATA; FORMATION; HYDRATE FORMATION; IN-SITU; INTRINSIC RATE CONSTANT; PARTICLE SIZE ANALYZERS; RAMAN SPECTROMETERS; SEMI-BATCH;

CRYSTALLIZATION; ETHANE; GAS HYDRATES; HYDRATION; PARTICLE SIZE; PROPANE; RAMAN SCATTERING; RAMAN SPECTROSCOPY; RATE CONSTANTS; SPECTROMETERS; SPECTROMETRY; SPECTRUM ANALYSIS;

PARTICLE SIZE ANALYSIS;

EID: 79953703972     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2011.03.012     Document Type: Article

References (27)

1. Al Otaibi, F.D., Clarke, M.A., Maini, B., Bishnoi, P.R., 2010. Formation Kinetics of Structure I Clathrates of Methane and Ethane using an in-situ Particle Size Analyser, Energy and Fuels, 2010, Submitted for publication.
2. Bergeron S., Servio P. Reaction rate constant of propane hydrate formation. A.I.Ch.E. Journal 2008, 54:2964-2970.
3. 2 gas hydrate decomposition using in-situ particle size analysis. Chemical Engineering Science 2004, 59:2983-2993.
4. 2 gas hydrate formation using in situ particle size analysis. Chemical Engineering Science 2005, 60:695-709.
5. Clarke, M.A., Bishnoi, P.R., 2005b. A high-pressure optical sampling cell for the application of Raman microscopy in gas hydrate formation and decomposition kinetics. In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway, June 13-16, 2005, pp. 86-90.
6. Claussen W.F. A second water structure for inert gas hydrates. Journal of Chemical Physics 1951, 19:1425-1429.
7. Englezos P., Dholabhai P., Kalogerakis N., Bishnoi P.R. Kinetics of methane and ethane hydrate formation. Chemical Engineering Science 1987, 42:2647-2658.
8. Englezos P., Dholabhai P., Kalogerakis N., Bishnoi P.R. Kinetics of gas hydrate formation from mixtures of methane and ethane. Chemical Engineering Science 1987, 42:2659-2666.
9. Giavarini C., Maccioni F., Santarelli M.L. Formation kinetics of propane hydrates. Industrial and Engineering Chemistry Research 2003, 42:1517-1521.
10. Gnanendran N., Amin R. Modelling hydrate formation kinetics of a hydrate promoter-water-natural gas system in a semi-batch spray reactor. Chemical Engineering Science 2004, 59:3849-3863.
11. Hammerschmidt E.G. Formation of gas hydrates in natural gas transmission lines. Industrial and Engineering Chemistry 1934, 26:851-855.
12. Herri J.M., Gruy J.S., Pic S., Cournil M. Methane hydrate crystallisation mechanism from in-situ particle sizing. A.I.Ch.E. Journal 1999, 45:590-603.
13. Jeffery G.A., McMullan R.K. The clathrate hydrates. Progress in Inorganic Chemistry 1967, 8:45-53.
14. Konstantin A., Udachin K.A., Ripmeester J.A. A complex clathrate hydrate structure showing bimodal guest hydration. Nature 1999, 397:420-423.
15. MEGHA, 1996. Megha Technologies Inc., Calgary, Alberta, Canada.
16. Prasad P.S.R., Sowjanya Y., Prasad K.R. Micro-Raman investigations of mixed gas hydrates. Vibrational Spectroscopy 2009, 50:319-323.
17. Ribeiro C.P., Lage P.L.C. Modelling of hydrate formation kinetics: state-of-the-art and future directions. Chemical Engineering Science 2008, 63:2007-2034.
18. Ripmeester J.A., Tse J.S., Ratcliffe C.I. Some structural studies of clathrate hydrates. Journal de Physique 1987, 114:2173-2181.
19. Sharma, S., 1996. Gas Hydrate Particle Size Measurements, M.Sc. Thesis, University of Calgary.
20. Skovborg P., Rasmussen P. A mass transport limited model for the growth of methane and ethane gas hydrates. Chemical Engineering Science 1994, 49:1131-1141.
21. Sloan E.D., Koh C.A. Clathrate Hydrates of Natural Gases 2007, Marcell Dekker, Inc., New York, NY. 3rd Edition.
22. Subramanian S., Kini R.A., Dec S.F., Sloan E.D. Methane and ethane can form structure II hydrates. Chemical Engineering Science 2000, 55:1981-1999.
23. Udachin K.A., Enright G.D., Ratcliffe C.I., Ripmeester J.A. Structure, stoichiometry, and morphology of bromine hydrate. Journal of the American Chemical Society 1997, 119:11481-11486.
24. Udachin K.A., Ratcliffe C.I., Ripmeester J.A. A dense and efficient clathrate hydrate structure with unusual cages. Angewandte Chemie 2001, 40:1303-1305.
25. von Stackelberg M., Müller H.R. Feste gas hydrate II. Zeitungen Elektrochemie 1954, 58:25-36.
26. Vysniauskus A., Bishnoi P.R. A kinetic study of methane hydrate formation. Chemical Engineering Science 1983, 38:1061-1072.
27. Vysniauksas A., Bishnoi P.R. Kinetics of ethane hydrate formation. Chemical Engineering Science 1985, 40:299-303.