Kraft lignin behavior during reaction in an alkaline medium

Biomass and Bioenergy

Volumn 35, Issue 5, 2011, Pages 2072-2079

  Mancera, C ^a   Ferrando, F ^a   Salvado J ^a   El Mansouri, N E ^a  

^a UNIVERSITAT ROVIRA I VIRGILI   (Spain)

Author keywords

1H NMR; Alkaline hydrolysis; Characterization; Functional groups; Kraft; Lignin

Indexed keywords

1H-NMR; ACID SOLUBLE LIGNIN; ACTIVE SITE; ALKALINE HYDROLYSIS; ALKALINE MEDIUM; ASH CONTENTS; CHEMICAL CHANGE; EFFECTS OF TEMPERATURE; FTIR SPECTROSCOPY; HYDROXYL CONTENT; KLASON LIGNIN; KRAFT; KRAFT LIGNIN; MICRO-REACTOR; NUMBER-AVERAGE; PROTON NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION TEMPERATURE; REACTION TIME; RESPONSE SURFACE; RESPONSE SURFACE METHODOLOGY; STRUCTURAL CHARACTERISTICS; UV SPECTROSCOPY; WEIGHT-AVERAGE MOLECULAR WEIGHT;

ALKALINITY; CHROMATOGRAPHIC ANALYSIS; CHROMATOGRAPHY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FUNCTIONAL GROUPS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHENOLS; POLYDISPERSITY; RESONANCE; SUGARS; SURFACE PROPERTIES; SURFACE REACTIONS; TEMPERATURE; ULTRAVIOLET SPECTROSCOPY;

LIGNIN;

ALKALINITY; ASH; CHROMATOGRAPHY; FTIR SPECTROSCOPY; HYDROLYSIS; LIGNIN; NUCLEAR MAGNETIC RESONANCE; PULP AND PAPER INDUSTRY; SUGAR; TEMPERATURE EFFECT; WEIGHT;

EID: 79953286586     PISSN: 09619534     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biombioe.2011.02.001     Document Type: Article

References (31)

1. Dence C.W., Lin S.Y. Introduction. Methods in lignin chemistry 1992, 3-19. Springer-Verlag, Berlin. C.W. Dence, S.Y. Lin (Eds.).
2. Gosselink R.J.A., De Jong E., Guran B., Abächerli A. Co-ordination network for lignin-standardisation, production and applications adapted to market requirements (EUROLIGNIN). Ind Crops Prod 2004, 20:121-129.
3. Gargulak J.G., Lebo S.E. Commercial use of lignin-based materials. Lignin: historical, biological, and materials perspectives 2000, 304-320. American Chemical Society symposium series. W.G. Glasser, R.A. Northey, T.P. Schultz (Eds.).
4. Glasser W.G., Lora J.H. Recent industrial applications of lignin: a sustainable alternative to nonrenewable materials. J Polym Environ 2002, 10:39-47.
5. Fierro V., Torné V., Montané D., Salvadó J. Activated carbons prepared from kraft lignin by phosphoric acid impregnation. Carbon'03: an international conference on carbon, Oviedo, Spain July 6-10, 2003.
6. Velásquez J.A., Ferrando F., Salvadó J. Effects of kraft lignin addition in the production of binderless fiberboard from steam exploded Miscanthus Sinensis. Ind Crops Prod 2003, 18:17-23.
7. Nimz H.H. Lignin-based wood adhesives. Wood adhesives: Chemistry and technology 1983, 247-288. Marcel Dekker, New York. A. Pizzi (Ed.).
8. Gonçalves A.R., Benar P. Hydroxymethylation and oxidation of organosolv lignins and utilization of the products. Bioresour Technol 2001, 79:103-111.
9. Vázquez G., González J., Freire S., Antorrena G. Effect of chemical modification of lignin on the gluebond performance or lignin-phenolic resins. Bioresour Technol 1997, 60:191-198.
10. Pranda J., Brezny R., Kosick M., Micko M.M. Structure and performance of kraft lignin fractions as components in resole adhesives. Tappi J 1991, 74:176-182.
11. Olivares M., Guzmán J.A., Natho A., Saavedra A. Kraft lignin utilization in adhesives. Wood Sci Technol 1988, 22:157-165.
12. Fredheim G.E., Braaten S.M., Christensen B.E. Comparison of molecular weight and molecular weight distributions of softwood and hardwood lignosulfonates. J Wood Chem Technol 2003, 23:197-215.
13. Alonso M.V., Rodríguez J.J., Oliet M., Rodríguez F., García J., Gilarranz M.A. Characterization and structural modification of ammonic lignosulfonate by methylolation. J Appl Polym Sci 2001, 82:2661-2668.
14. Alonso M.M., Oliet M., Rodrićguez F., Garcića J., Gilarranz M.A., Rodrićguez J.J. Modification of ammonium lignosulfonate by phenolation for use in phenolic resins. Bioresour Technol 2005, 96:1013-1018.
15. Gilarranz M.A., Rodríguez F., Oliet M. Lignin behavior during the autocatalyzed methanol pulping of Eucalyptus Globulus: changes in molecular weight and functionality. Holzforschung 2000, 54:373-380.
16. El Mansouri N.E., Farriol X., Salvadó J. Structural modification and characterization of lignosulfonate by a reaction in alkaline medium for its incorporation into phenolic resins. J Appl Polym Sci 2006, 102:3286-3292.
17. El Mansouri N.E., Salvadó J. Structural characterization of technical lignins for the production of adhesives: application to lignosulfonate, kraft, soda-anthraquinone, organosolv and ethanol process lignins. Ind Crops Prod 2006, 24:8-16.
18. TAPPI standard T-13 2005, Ed. Press.
19. Maekawa E., Ichizawa T., Koshijima T. An evaluation of acid soluble lignin determination in analyses of lignin by the sulphuric acid method. J Wood Chem Technol 1989, 9:549-567.
20. William E.K., Lawrence G.C., Michael M.M., David L.B. The complete analysis of wood polysaccharides using HPLC. J Wood Chem Technol 1991, 11:447-463.
21. Zakis G.F. Functional analysis of lignins and their derivatives 1994, Tappi Press, Atlanta, GA.
22. Faix O. Fourier transform infrared spectroscopy. Methods in lignin chemistry 1992, 83-109. Springer-Verlag, Berlin. C.W. Dence, S.Y. Lin (Eds.).
23. Nada A.M.A., Yousef M.A., Shaffei K.A., Salah A.M. Infrared spectroscopy of some treated lignins. Polym Degrad Stab 1998, 62:157-163.
24. Chum H.L., Johnhson D.K., Ratcliff M.A., Posey F.L., Black S., Goheen D.W., et al. Liquid fuels from lignins. Biochemical conversion program semi-annual review meeting; Golden, Colorado 10-12 June 1985, 53-60. SERI/CP-231-2726, Solar Energy Research Institute, Golden, CO.
25. Glasser W.G., Davé V., Frazier C.E. Molecular weight distribution of semi-commercial lignin derivatives. J Wood Chem Technol 1993, 13:545-559.
26. Yau W.W., Kirkland J.J., Bly D.D. Modern size-exclusion liquid chromatography 1979, John Wiley and Sons, Canada.
27. Kubo S., Uraki Y., Sano Y. Thermomechanical analysis of isolated lignins. Holzforschung 1996, 50:144-150.
28. Lundquist K. Proton (1H) NMR spectroscopy. Methods in lignin chemistry 1992, 242-247. Springer-Verlag, Berlin. C.W. Dence, S.Y. Lin (Eds.).
29. Miller J.E., Evans L., Littlewolf A., Trudell D.E. Batch microreactor studies of lignin and lignin model compound depolymerization by bases in alcohol solvents. Fuel 1999, 78:1363-1366.
30. Sarkanen K.V. Chemistry of solvent pulping. Tappi J 1990, 73:215-219.
31. Forss K.G., Fremer K.-E. The nature and reactions of lignin - A new paradigm 2003, Oy Nord Print Ab, Helsinki.