Volatile organic compounds in pesticide formulations: Methods to estimate ozone formation potential

Atmospheric Environment

Volumn 45, Issue 14, 2011, Pages 2404-2412

  Zeinali, Mazyar ^a,c   McConnell, Laura L ^b   Hapeman, Cathleen J ^b   Nguyen, Anh ^b   Schmidt, Walter F ^b   Howard, Cody J ^b  

^a NEnvironmental LLC   (United States)

^b AGRICULTURAL RESEARCH SERVICE   (United States)

^c International Council on Clean Transportation   (United States)

Author keywords

Agriculture; Ozone formation potential; Pesticide; Thermogravimetric analysis; Volatile organic compounds

Indexed keywords

ACTIVE INGREDIENTS; ALTERNATE METHOD; ASSESSMENT APPROACHES; CHEMICAL COMPOSITIONS; CONSTANT-EMISSIONS; ENVIRONMENTAL FATE; EVOLVED GAS ANALYSIS; FLEXIBLE SIMULATION; FOURIER TRANSFORM INFRARED; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; GROUND-LEVEL OZONE; LITTLE RESEARCH; MANAGEMENT PRACTICES; MAXIMUM FLUX; MAXIMUM INCREMENTAL REACTIVITIES; OZONE FORMATION; OZONE FORMATION POTENTIAL; PESTICIDE FORMULATIONS; PRODUCT ASSESSMENT; REACTIVITY PREDICTION; SCREENING TOOL; TGA-FTIR; TOTAL MASS; VOC EMISSIONS; VOLATILE COMPONENTS;

AGRICULTURE; AIR POLLUTION; CHEMICAL ANALYSIS; COMPUTER SIMULATION; ESTIMATION; FOURIER TRANSFORMS; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; OZONE; PESTICIDES; VOLATILE ORGANIC COMPOUNDS;

THERMOGRAVIMETRIC ANALYSIS;

OZONE; PESTICIDE; VOLATILE ORGANIC COMPOUND;

AGRICULTURAL EMISSION; ATMOSPHERIC POLLUTION; CHEMICAL COMPOSITION; EMISSION CONTROL; ENVIRONMENTAL FATE; FTIR SPECTROSCOPY; GAS CHROMATOGRAPHY; MANAGEMENT PRACTICE; MASS SPECTROMETRY; OZONE; PESTICIDE; THERMOGRAVIMETRY; VAPOR PRESSURE; VOLATILE ORGANIC COMPOUND;

ARTICLE; ENVIRONMENTAL FACTOR; FOURIER TRANSFORM MASS SPECTROMETRY; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; PRIORITY JOURNAL; SIMULATION; THERMOGRAVIMETRY;

EID: 79953267317     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2011.02.015     Document Type: Article

References (42)

1. Ambrose D., Connett J.E., Green J.H.S., Hales J.L., Head A.J., Martin J.F. Thermodynamic properties of organic oxygen compounds 42. Physical and thermodynamic properties of benzaldehyde. Journal of Chemical Thermodynamics 1975, 7:1143-1157.
2. Arnot J.A., Gobas F.A.P.C. A generic QSAR for assessing the bioaccumulation potential of organic chemicals in aquatic food webs. QSAR and Combinatorial Science 2003, 22:337-345.
3. Ashworth D.J., Ernst F.F., Xuan R., Yates S.R. Laboratory assessment of emission reduction strategies for the agricultural fumigants 1,3-dichloropropene and chloropicrin. Environmental Science and Technology 2009, 43:5073-5078. 10.1021/Es900049g.
4. Standard D 3539-87. Evaporation Rates of Volatile Liquids by Shell Thin-film Evaporometer 1987, ASTM, ASTM International, West Conshohocken, PA.
5. Atkinson R., Tuazon E.C., Aschmann S.M. Atmospheric chemistry of 2-pentanone and 2-heptanone. Environmental Science and Technology 2000, 34:623-631.
6. Atkinson R. Gas-phase tropospheric chemistry of organic-compounds - a review. Atmospheric Environment Part A-General Topics 1990, 24:1-41.
7. Aunan K., Berntsen T.K., Seip H.M. Surface ozone in China and its possible impact on agricultural crop yields. AMBIO 2000, 29:294-301.
8. Burkhard L.P., Armstrong D.E., Andren A.W. Vapor-pressures for biphenyl, 4-chlorobiphenyl, 2,2',3,3',5,5',6,6'-octachlorobiphenyl, and decachlorobiphenyl. Journal of Chemical and Engineering Data 1984, 29:248-250.
9. Carter W.P.L. Development of ozone reactivity scales for volatile organic-compounds. Journal of the Air and Waste Management Association 1994, 44:881-899.
10. Carter W.P.L. Development of the SAPRC-07 chemical mechanism. Atmospheric Environment 2010, 10.1016/j.atmosenv.2010.01.026.
11. Estimation of Volatile Emissions Potential of Pesticides by Thermogravimetry 2005, CDPR, Retrieved September, 2010, from. http://www.cdpr.ca.gov/docs/emon/vocs/vocproj/tga_method.pdf.
12. The Pesticide VOC Emissions Inventory 2008, CDPR, Retrieved September, 2010, from. http://www.cdpr.ca.gov/docs/emon/vocs/vocproj/faq_voc_emission_inventory.pdf.
13. Pilot Project: Estimating Pesticide Product VOC Emission Speciation and Reactivity Based on Product Composition 2009, CDPR, Retrieved September, 2010, from. http://www.cdpr.ca.gov/docs/emon/vocs/vocproj/reactivity_proposal_oros.pdf.
14. Conservation Management Practices Guide: Reducing Volatile Organic Compound (VOC) Emissions from Agricultural Pesticide Applications 2010, CDPR, Retrieved September, 2010, from. http://www.cdpr.ca.gov/docs/emon/vocs/vocproj/reducing_voc_emissions.pdf.
15. Cervenkova I., Boublik T. Vapor-pressures, refractive-indexes, and densities at 20.0-degrees-C, and vapor liquid equilibrium at 101.325 Kpa, in the tert-amyl methyl-ether methanol system. Journal of Chemical and Engineering Data 1984, 29:425-427.
16. Chao J., Lin C.T., Chung T.H. Vapor pressure of coal chemicals. Journal of Physical and Chemical Reference Data 1983, 12:1033-1063.
17. Daubert T.E., Danner R.P. Data Compilation: Tables of Properties of Pure Compounds 1985, American Institute of Chemical Engineers, New York.
18. Daubert T.E., Danner R.P. Physical and Thermodynamic Properties of Pure Chemicals: Data Compilation 1989, Taylor and Francis, Washington D.C.
19. Duffus J.H., Nordber M., Templeton D.M. Glossary of terms used in toxicology. Pure and Applied Chemistry 2007, 79:1153-1344. second ed. 10.1351/pac200779071153.
20. Dumont M.J., Kong X., Narine S.S. Polyurethanes from benzene polyols synthesized from vegetable oils: dependence of physical properties on structure. Journal of Applied Polymer Science 2010, 117:3196-3203. 10.1002/app.32224.
21. Gamerdinger A.P., Lemley A.T., Wagenet R.J. Nonequilibrium sorption and degradation of 3,2-chloro-s-triazine herbicides in soil-water systems. Journal of Environmental Quality 1991, 20:815-822.
22. Guth J.A., Reischmann F.J., Allen R., Arnold D., Hassink J., Leake C.R., Skidmore M.W., Reeves G.L. Volatilisation of crop protection chemicals from crop and soil surfaces under controlled conditions-prediction of volatile losses from physico-chemical properties. Chemosphere 2004, 57:871-887. 10.1016/j.chemosphere.2004.08.011.
23. Howard C.J., Kumar A., Mitloehner F., Stackhouse K., Green P.G., Flocchini R.G., Kleeman M.J. Direct measurements of the ozone formation potential from livestock and poultry waste emissions. Environmental Science and Technology 2010, 44:2292-2298. 10.1021/Es901916b.
24. Karyakin N.V., Rabinovi Ib, Pakhomov L.G. Heats of sublimation of naphthalene and its monosubstituted beta-derivatives. Russian Journal of Physical Chemistry, USSR 1968, 42:954.
25. Kumar A., Howard Cody J., Derrick Doniche, Malkina Irina L., Mitloehner Frank M., Kleeman Michael J., Alaimo Christopher P., Flocchini Robert G., Green Peter G. Determination of volatile organic compound emissions and ozone formation from spraying solvent-based pesticides. Journal of Environmental Quality 2010, 10.2134/jeq2009.0495.
26. Macknick A.B., Prausnitz J.M. Vapor-pressures of heavy liquid hydrocarbons by a group-contribution method. Industrial & Engineering Chemistry Fundamentals 1979, 18:348-351.
27. Meylan W.M., Howard P.H. Computer estimation of the atmospheric gas-phase reaction-rate of organic-compounds with hydroxyl radicals and ozone. Chemosphere 1993, 26:2293-2299.
28. Ozone-forming Potential of Reformulated Gasoline 1999, National Research Council (NRC), National Academy Press, Washington, D.C.
29. Neely W.B., Blau G.E. Environmental Exposure from Chemicals 1985, vol. I. CRC Press, Boca Raton, FL.
30. Papiernik S.K., Yates S.R., Gan J.Y. An approach for estimating the permeability of agricultural films. Environmental Science and Technology 2001, 35:1240-1246.
31. Perry R.H., Green D.W. Perry's Chemical Engineer's Handbook 1984, McGraw-Hill, London.
32. Phousongphouang P.T., Arey J. Rate constants for the gas-phase reactions of a series of alkylnaphthalenes with the OH radical. Environmental Science and Technology 2002, 36:1947-1952. 10.1021/Es011434c.
33. Price D.M., Church S.P. FTIR evolved gas analysis of the decomposition products of cellulose diacetate. Thermochimica Acta 1997, 294:107-112.
34. Ruzicka V., Zabransky M., Ruzicka K., Majer V. Vapor-pressures for a group of high-boiling alkylbenzenes under environmental-conditions. Thermochimica Acta 1994, 245:121-144.
35. 8-Hour Ozone Non-attainment Areas 2010, US EPA, Retrieved September, 2010, from. http://www.epa.gov/oar/oaqps/greenbk/ca8.html.
36. Estimation Program Interface (EPI) Suite 2010, US EPA, Retrieved September, 2010, from. http://www.epa.gov/oppt/exposure/pubs/episuite.htm.
37. van Wesenbeeck I., Driver J., Ross J. Relationship between the evaporation rate and vapor pressure of moderately and highly volatile chemicals. Bulletin of Environmental Contamination and Toxicology 2008, 80:315-318. 10.1007/s00128-008-9380-2.
38. Wang D., Xiao R., Zhang H., He G. Comparison of catalytic pyrolysis of biomass with MCM-41 and CaO catalysts by using TGA-FTIR analysis. Journal of Analytical and Applied Pyrolysis 2010, 89:171-177. 10.1016/j.jaap.2010.07.008.
39. Warren C.S., Parkerton T.F., Rohde A.M., Prince R.C., Manning R., Letinski D.J. Development of a multimedia model for the fate prediction of hydrocarbon fluids in agrochemical formulations. Journal of ASTM International 2008, 5:11. 10.1520/JAI101637.
40. Woodrow J.E., Seiber J.N., Dary C. Predicting pesticide emissions and downwind concentrations using correlations with estimated vapor pressures. Journal of Agricultural and Food Chemistry 2001, 49:3841-3846. 10.1021/Jf010358u.
41. Yaws C.L. Handbook of Vapour Pressure 1994, vols. I, II, III. Gulf Publishing, Houston, TX.
42. Zhang P., Song L., Lu H., Wang J., Hu Y. The thermal property and flame retardant mechanism of intumescent flame retardant paraffin system with metal. Industrial and Engineering Chemistry Research 2010, 49:6003-6009. 10.1021/ie1001422.