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While a change of wrapping tendency of the salalen ligands upon formation of the cationic active species is not excluded, the high activity (consistent with a cis relationship between active sites), and the very high stereoregularity (consistent with non-averaging of tacticities, see below) both support the preservation of the fac-mer wrapping.
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CCDC 802925 and 802926 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
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It should be noted, though, that aluminum cocatalysts are known to react with imine functionalities of chelating ligands and affect stereoselectivity. See Ref. [9a].
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