Confined metallophilicity within a coordination prism

Chemistry - A European Journal

Volumn 17, Issue 15, 2011, Pages 4113-4117

  Gao, Guo Fen ^a   Li, Mian ^a   Zhan, Shun Ze ^a   Lv, Zhi ^a   Chen, Guang Hui ^a   Li, Dan ^a  

^a SHANTOU UNIVERSITY   (China)

Author keywords

cage compounds; Cu Cu interactions; density functional calculations; luminescence; metallophilicity

Indexed keywords

CAGE COMPOUNDS; CU-CU INTERACTIONS; DENSITY FUNCTIONAL CALCULATIONS; DFT CALCULATION; METALLOPHILICITY; PYRAZOLATE; STACKING MODES; STOKES SHIFT;

DENSITY FUNCTIONAL THEORY; OLIGOMERS; PRISMS;

LUMINESCENCE;

EID: 79953214959     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201100081     Document Type: Article

References (30)

1. M. Jansen, Angew. Chem. 1987, 99, 1136-1149
2. Angew. Chem. Int. Ed. Engl. 1987, 26, 1098-1110.
3. H. Schmidbaur, A. Schier, Chem. Soc. Rev. 2008, 37, 1931-1951.
4. J. M. Zuo, M. Kim, M. O'Keeffe, J. C. H. Spence, Nature 1999, 401, 49-52.
5. K. M. Merz, Jr., R. Hoffmann, Inorg. Chem. 1988, 27, 2120-2127.
6. P. Pyykkö, Chem. Rev. 1997, 97, 597-636.
7. F. A. Cotton, X. Feng, D. J. Timmons, Inorg. Chem. 1998, 37, 4066-4069.
8. H. V. R. Dias, H. V. K. Diyabalanage, M. A. Rawashdeh-Omary, M. A. Franzman, M. A. Omary, J. Am. Chem. Soc. 2003, 125, 12072-12073.
9. H. V. R. Dias, H. V. K. Diyabalanage, M. G. Eldabaja, O. Elbjeirami, M. A. Rawashdeh-Omary, M. A. Omary, J. Am. Chem. Soc. 2005, 127, 7489-7501.
10. M. A. Omary, M. A. Rawashdeh-Omary, M. W. A. Gonser, O. Elbjeirami, T. Grimes, T. R. Cundari, Inorg. Chem. 2005, 44, 8200-8210.
11. T. Grimes, M. A. Omary, H. V. R. Dias, T. R. Cundari, J. Phys. Chem. A 2006, 110, 5823-5830.
12. J. He, Y.-G. Yin, T. Wu, D. Li, X.-C. Huang, Chem. Commun. 2006, 2845-2847.
13. J.-P. Zhang, S. Kitagawa, J. Am. Chem. Soc. 2008, 130, 907-917.
14. M. A. Carvajal, S. Alvarez, J. J. Novoa, Chem. Eur. J. 2004, 10, 2117-2132.
15. C.-M. Che, Z. Mao, V. M. Miskowski, M.-C. Tse, C.-K. Chan, K.-K. Cheung, D. L. Phillips, K.-H. Leung, Angew. Chem. 2000, 112, 4250-4254
16. Angew. Chem. Int. Ed. 2000, 39, 4084-4088.
17. C.-M. Che, S.-W. Lai, Coord. Chem. Rev. 2005, 249, 1296-1309.
18. R. D. Köhn, G. Seifert, Z. Pan, M. F. Mahon, G. Kociok-Köhn, Angew. Chem. 2003, 115, 818-820
19. Angew. Chem. Int. Ed. 2003, 42, 793-796.
20. K. Singh, J. R. Long, P. Stavropoulos, J. Am. Chem. Soc. 1997, 119, 2942-2943
21. Inorg. Chem. 1998, 37, 1073-1079.
22. H. L. Hermann, G. Boche, P. Schwerdtfeger, Chem. Eur. J. 2001, 7, 5333-5342.
23. I. I. Vorontsov, A. Yu. Kovalevsky, Y.-S. Chen, T. Graber, M. Gembicky, I. V. Novozhilova, M. A. Omary, P. Coppens, Phys. Rev. Lett. 2005, 94, 193003.
24. K. A. Barakat, T. R. Cundari, M. A. Omary, J. Am. Chem. Soc. 2003, 125, 14228-14229.
25. V. R. Bojan, Fernández, E. J. A. Laguna, J. M. Lõpez-de-Luzuriaga, M. Monge, M. E. Olmos, C. Silvestru, J. Am. Chem. Soc. 2005, 127, 11564-11565.
26. M. Iwamura, S. Takeuchi, T. Tahara, J. Am. Chem. Soc. 2007, 129, 5248-5256.
27. T. Osuga, T. Murase, K. Ono, Y. Yamauchi, M. Fujita, J. Am. Chem. Soc. 2010, 132, 15553-15555. This most recent paper published during the submission of this work shows a gold(I)-pyrazolate-trimer array with a frontal mode, which is confined in a host coordination cage, showing the importance of such an unprecedented stacking mode in this system of complexes.
28. J. A. Alonso, A. Mañanes, Theor. Chem. Acc. 2006, 117, 467-472.
29. Gaussian 03, Revision C.02, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, Gaussian, Inc., Wallingford CT, 2004.
30. Note added in proof (7.3.2011): During the proof of the this work a paper was published that described the synthesis, structure, and luminescence of a Cu6 coordination cage with a staggered mode (, T. Jozak, Y. Sun, Y. Schmitt, S. Lebedkin, M. Kappes, W. R. Thiel, Chem. Eur. J. 2011, 17, 3384-3389).