Kinetic study of the liquid-phase selective hydrogenation of 1-butyne in presence of 1-butene over a commercial palladium-based catalyst

Chemical Engineering Research and Design

Volumn 89, Issue 4, 2011, Pages 384-397

  Alves, J A ^a,b   Bressa, S P ^a,c   Martinez O M ^a,b   Barreto, G F ^a,b  

^a UNIVERSIDAD NACIONAL DE LA PLATA   (Argentina)

^b Facultad de Ciencias Naturales e Instituto M Lillo   (Argentina)

^c Centro Científico y Tecnológico Consejo Nacional de Investigaciones Científicas y Técnicas   (Argentina)

Author keywords

1 Butyne; Eggshell catalyst; Liquid phase hydrogenation; Palladium; Selectivity

Indexed keywords

1-BUTENE; 1-BUTYNE; AVERAGE DEVIATION; DATA ANALYSIS; DIFFUSION LIMITATIONS; EGGSHELL CATALYST; EXPERIMENTAL CONDITIONS; EXPERIMENTAL DATA; FIRST ORDER KINETICS; HYDROGEN PARTIAL PRESSURES; HYDROGENATION RATE; HYDROREFINING; KINETIC EXPRESSION; KINETIC INVESTIGATIONS; KINETIC MODELS; KINETIC STUDY; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; LIQUID PHASE; LIQUID-PHASE HYDROGENATION; MOLE FRACTION; N-BUTENE; OPERATING CONDITION; PARAMETER ESTIMATE; SELECTIVE HYDROGENATION; SELECTIVITY; SEVEN-LEVEL;

BUTENES; DATA REDUCTION; HYDROGEN; HYDROGENATION; INTERNET PROTOCOLS; KINETIC THEORY; LIQUIDS; PARAMETER ESTIMATION;

CATALYST SELECTIVITY;

EID: 79953057964     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2010.09.003     Document Type: Article

References (26)

1. Akgerman A., Gainer J.L. Diffusion of gases in liquids. Ind. Eng. Chem. Fundam. 1972, 11(3):373-379.
2. Anderson J.R., Pratt K.C. Introduction to Characterization and Testing of Catalysts 1985, Academic Press, Sidney.
3. Alves J.A., Bressa S.P., Martínez O.M., Barreto G.F. Kinetic study of the liquid-phase hydrogenation of 1-butyne over a commercial palladium/alumina catalyst. Chem. Eng. J. 2007, 125(3):127-196.
4. Ardiaca N.O., Bressa S.P., Alves J.A., Martínez O.M., Barreto G.F. experimental procedure for kinetic studies on egg-shell catalysts. the case of liquid-phase hydrogenation of 1,3-butadiene and n-butenes on commercial Pd catalysts. Catal. Today 2001, 64(3-4):205-215.
5. Boitiaux J.P., Cosyns J., Vasudevan S. Hydrogenation of highly unsaturated hydrocarbons over highly dispersed palladium catalyst. Part I. Behaviour of small metal particles. Appl. Catal. 1983, 6(1):41-51.
6. Boitiaux J.P., Cosyns J., Derrien M.L., Leger G. Proper design of butadiene selective hydrogenation process for masimum 1-butene yield by using comprehensive kinetic modelling. Proc. AIChe Spring National Meeting, Paper 1453 1985, American Institute of Chemical Engineers (AIChE), New York.
7. Boitiaux J.P., Cosyns J., Robert E. Hydrogenation of unsaturated hydrocarbons on palladium, platinum and rhodium catalysts. Part I. Kinetic study of 1-butene 1,3-butadiene and 1-butyne hydrogenation on platinum. Appl. Catal. 1987, 32:145-168.
8. Bond G.C., Wells P.B. The mechanism of the hydrogenation of unsaturated hydrocarbons on transition metal catalysts. Adv. Catal. 1963, 15:91-226.
9. Box G.E.P. Fitting empirical data. Ann. N. Y. Acad. Sci. 1960, 86:792-816.
10. Bressa S.P., Martínez O.M., Barreto G.F. Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst. Ind. Eng. Chem. Res. 2003, 42(10):2081-2092.
11. Derrien M.L. Selective hydrogenation applied to the refining of petrochemical raw materials produced by steam cracking. Stud. Surf. Sci. Catal. 1986, 27:613-666.
12. Graboski M., Daubert T. A modified soave equation of state for phase equilibrium calculations. Systems containing hydrogen. Ind. Eng. Chem. Process Des. Dev. 1979, 18(2):300-306.
13. Gunn D.J. Transfer of heat or mass to particles. Int. J. Heat Mass Transfer 1978, 21(4):467-476.
14. Hub S., Touroude R. Mechanism of catalytic hydrogenation of but-1-yne on palladium. J. Catal. 1988, 114(2):411-421.
15. Hub S., Hilaire L., Touroude R. Hydrogenation of but-1-yne and but-1-ene on palladium catalysts. Particle size effect. Appl. Catal. 1988, 36:307-322.
16. Jackson R. Transport in porous catalysts. Chemical Engineering Monographs 1977, Elsevier Scientific Publishing Company, Amsterdam.
17. Kiperman S.L. Some problems of chemical kinetics in heterogeneous hydrogenation catalysis. Stud. Surf. Sci. Catal. 1986, 27:1-52.
18. Maetz Ph., Touroude R. Modification of surface reactivity by adsorbed species on supported palladium and platinum catalysts during the selective hydrogenation of but-1-yne. Appl. Catal. A-Gen. 1997, 149(1):189-206.
19. McClung R., Novalany R. Choosing a selective hydrogenation system. Petrochem. Gas Process. 2002, Autumn:147-155.
20. Molnár Á., Sarkány A., Varga M. Hydrogenation of carbon-carbon multiple bonds: chemo-, regio- and stereo-selectivity. J. Mol. Catal. A-Chem. 2001, 173(1-2):185-221.
21. Ramachandran P.A., Chaudhari R.V. Three-phase Catalytic Reactors, Series: Topic in Chemical Engineering 1983, Gordon and Breach Science Publishers Inc., London.
22. Reid R.C., Prausnitz J.M., Poling B.E. The Properties of Gases and Liquids 1987, McGraw-Hill, New York. 4th edition.
23. Satterfield C.N. Trickle-bed reactors. AIChE J. 1975, 21(3):209-228.
24. Stewart W.E., Caracotsios M., Sorensen J.P. Parameter estimation from multiresponse data. AIChE J. 1992, 38(5):641-650.
25. 4 stream. Chem. Ind. 1993, 742-745.
26. Weisz P.B., Hicks J.S. The behaviour of porous catalysts particles in view of internal mass and heat diffusion effects. Chem. Eng. Sci. 1962, 17:265-275.