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Volumn 115, Issue 12, 2011, Pages 3003-3012

Calorimetric investigation of triazole-bridged Fe(II) spin-crossover one-dimensional materials: Measuring the cooperativity

Author keywords

[No Author keywords available]

Indexed keywords

DIFFERENTIAL SCANNING CALORIMETRY; ENTHALPY; MAGNETIC VARIABLES MEASUREMENT; NITROGEN COMPOUNDS; POLYMERS;

EID: 79953035530     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp109489g     Document Type: Article
Times cited : (78)

References (63)
  • 12
    • 21244503358 scopus 로고    scopus 로고
    • references therein
    • Spiering, H. Top. Curr. Chem. 2004, 235, 171-195 and references therein
    • (2004) Top. Curr. Chem. , vol.235 , pp. 171-195
    • Spiering, H.1
  • 48
    • 84906409022 scopus 로고    scopus 로고
    • note
    • -1). Unfortunately, the amount of sample used was at the bottom margin of the setup, and the quality of the data at high temperatures was poor. This made the determination of a normal heat capacity curve difficult, if not incorrect, probably at the origin of the discrepancy observed.
  • 54
    • 84906394518 scopus 로고    scopus 로고
    • note
    • LS and evaluated through UV-vis-NIR spectroscopy at low temperature.
  • 55
    • 84906409023 scopus 로고    scopus 로고
    • note
    • Another reason to model the warming branch of the compounds with hysteresis is that the correlation is intended with calorimetric figures that are determined upon warming. Moreover, in the present compounds it is possible that secondary rearrangements triggered by the spin transition participate in the observation of hysteresis, since for some compounds gradual SCO curves do show hysteresis. In this frame, it is not incorrect to use a mean-field model on only one branch of the hysteresis.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.