Nontrivial redox behavior of nanosized cobalt: New insights from ambient pressure X-ray photoelectron and absorption spectroscopies

ACS Nano

Volumn 5, Issue 3, 2011, Pages 2182-2190

  Papaefthimiou, Vasiliki ^a   Dintzer, Thierry ^a   Dupuis, Véronique ^b   Tamion, Alexandre ^b   Tournus, Florent ^b   Hillion, Arnaud ^b   Teschner, Detre ^c   Hävecker, Michael ^c   Knop Gericke, Axel ^c   Schlögl, Robert ^c   Zafeiratos, Spyridon ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

^b UNIVERSITÉ LYON 1   (France)

^c FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

Author keywords

APPES; cobalt; nanoparticles; NEXAFS; redox properties; wurtzite CoO; XPS

Indexed keywords

APPES; NEXAFS; REDOX PROPERTIES; WURTZITES; XPS;

ABSORPTION; ABSORPTION SPECTROSCOPY; CARBON FILMS; COBALT COMPOUNDS; ELECTROMAGNETIC WAVE ABSORPTION; ELECTRONIC STRUCTURE; METASTABLE PHASES; NANOPARTICLES; OXIDATION; OXIDE FILMS; OXYGEN; PHOTONS; SINGLE CRYSTALS; X RAY PHOTOELECTRON SPECTROSCOPY; X RAYS; ZINC SULFIDE;

COBALT;

COBALT; NANOMATERIAL;

ARTICLE; CHEMISTRY; CONFORMATION; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; NANOTECHNOLOGY; OXIDATION REDUCTION REACTION; PARTICLE SIZE; PRESSURE; SPECTROSCOPY; SURFACE PROPERTY; ULTRASTRUCTURE;

COBALT; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MOLECULAR CONFORMATION; NANOSTRUCTURES; NANOTECHNOLOGY; OXIDATION-REDUCTION; PARTICLE SIZE; PRESSURE; SPECTRUM ANALYSIS; SURFACE PROPERTIES;

EID: 79952917625     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn103392x     Document Type: Article

References (54)

1. Skumryev, V.; Stoyanov, S.; Zhang, Y.; Hadjipanayis, G.; Givord, D.; Nogues, J. Beating The Superparamagnetic Limit With Exchange Bias Nature 2003, 423, 850-853 (Pubitemid 36781272)
2. Csiszar, S. I.; Haverkort, M. W.; Hu, Z.; Tanaka, A.; Hsieh, H. H.; Lin, H.-J.; Chen, C. T.; Hibma, T.; Tjeng, L. H. Controlling Orbital Moment and Spin Orientation in CoO Layers by Strain Phys. Rev. Lett. 2005, 95, 187205
3. Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J.-M. Nano-Sized Transition-Metaloxides as Negative-Electrode Materials for Lithium-Ion Batteries Nature 2000, 407, 496-499
4. Khodakov, A. Y.; Chu, W.; Fongarland, P. Advances In the Development of Novel Cobalt Fischer-Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels Chem. Rev. 2007, 107, 1692-1744 (Pubitemid 46876278)
5. Iglesia, E. Design, Synthesis, and Use of Cobalt-Based Fischer-Tropsch Synthesis Catalysts Appl. Catal. A: Gen. 1997, 161, 59-78 (Pubitemid 127379094)
6. Herranz, T.; Deng, X. Y.; Cabot, A.; Guo, J. G.; Salmeron, M. Influence of the Cobalt Particle Size in the CO Hydrogenation Reaction Studied by in Situ X-ray Absorption Spectroscopy J. Phys. Chem. B 2009, 113, 10721-10727
7. Bezemer, G. L.; Bitter, J. H.; Kuipers, H. P. C. E.; Oosterbeek, H.; Holewijn, J. E.; Xu, X. D.; Kapteijn, F.; van Dillen, A. J.; de Jong, K. P. Cobalt Particle Size Effects in the Fischer-Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts J. Am. Chem. Soc. 2006, 128, 3956-3964
8. den Breejen, J. P.; Radstake, P. B.; Bezemer, G. L.; Bitter, J. H.; Fröseth, V.; Holmen, A.; de Jong, K. P. On the Origin of the Cobalt Particle Size Effects in Fischer-Tropsch Catalysis J. Am. Chem. Soc. 2009, 131, 7197-7203
9. den Breejen, J. P.; Sietsma, J. R. A.; Friedrich, H.; Bitter, J. H.; de Jong, K. P. Design of Supported Cobalt Catalysts with Maximum Activity for the Fischer-Tropsch Synthesis J. Catal. 2010, 270, 146-152
10. Seo, W. S.; Shim, J. H.; Oh, S. J.; Lee, E. K.; Hur, N. H.; Park, J. T. Phase- and Size-Controlled Synthesis of Hexagonal and Cubic CoO Nanocrystals J. Am. Chem. Soc. 2005, 127, 6188-6189 (Pubitemid 40627739)
11. Risbud, A. S.; Snedeker, L. P.; Elcombe, M. M.; Cheetham, A. K.; Seshadri, R. Wurtzite CoO Chem. Mater. 2005, 17, 834-838 (Pubitemid 40261337)
12. 4 Nanocrystals: Their Interconversion and Tuning of Phase and Morphology Chem. Mater. 2010, 22, 4446-4454
13. Venkatesan, M.; Fitzgerald, C. B.; Lunney, J. G.; Coey, J. M. D. Anisotropic Ferromagnetism in Substituted Zinc Oxide Phys. Rev. Lett. 2004, 93, 177206
14. Meyer, W.; Hock, D.; Biedermann, K.; Gubo, M.; Müller, S.; Hammer, L.; Heinz, K. Coexistence of Rocksalt and Wurtzite Structure in Nanosized CoO Films Phys. Rev. Lett. 2008, 101, 016103
15. Meyer, W.; Biedermann, K.; Gubo, M.; Hammer, L.; Heinz, K. Superstructure in the Termination of CoO(111) Surfaces: Low-Energy Electron Diffraction and Scanning Tunneling Microscopy Phys. Rev. B 2009, 79, 121403
16. Brundle, C. R.; Chuang, T. J.; Rice, D. W. X-ray Photoemission Study of Interaction of Oxygen and Air with Clean Cobalt Surfaces Surf. Sci. 1976, 60, 286-300
17. Bridge, M. E.; Lambert, R. M. Oxygen-Chemisorption, Surface Oxidation, and the Oxidation of Carbon Monoxide on Cobalt (0001) Surf. Sci. 1979, 82, 413-424
18. Castro, G. R.; Küppers, J. Interaction of Oxygen with hcp (0001) Recrystallized Cobalt Surfaces Surf. Sci. 1982, 123, 456-470
19. Wang, N. L.; Kaiser, U.; Ganschow, O.; Wiedmann, L.; Benninghoven, A. Oxidation of Cobalt at Room-Temperature, Studied by Combined Static SIMS, Static AES, XPS, and Work Function Investigations Surf. Sci. 1983, 124, 51-67
20. 4 Model Catalyst by Electron Microscopy Catal. Lett. 2001, 73, 41-46 and refs therein (Pubitemid 33617237)
21. Bulavchenko, O. A.; Cherepanova, S. V.; Malakhov, V. V.; Dovlitova, L. S.; Ishchenko, A. V.; Tsybulya, S. V. In Situ XRD Study of Nanocrystalline Cobalt Oxide Reduction Kinet. Catal. 2009, 50, 192-198 and refs therein
22. Martin, M.; Koops, U.; Lakshmi, N. Reactivity of Solids Studied by in Situ XAS and XRD Solid State Ionics 2004, 172, 357-363 and references therein
23. Palasantzas, G.; Vystavel, T.; Koch, S. A.; de Hosson, J. T. M. Coalescence Aspects of Cobalt Nanoparticles During in Situ High-Temperature Annealing J. Appl. Phys. 2006, 99, 024307
24. 4(111) with Oxygen and Water J. Mol. Catal. A 2008, 281, 49-58 (Pubitemid 351215961)
25. 2 Catalysts: XAS Study at the Cobalt L-III,L-II Absorption Edges J. Catal. 2000, 189, 456-462
26. 2 Catalysts For Fischer-Tropsch Synthesis J. Phys. Chem. B 2004, 108, 16201-16207
27. 3(0001) Epitaxial Films Phys. Rev. B 2009, 80, 155457
28. 4(110) and the Effect of Impurity Segregation J. Vac. Sci. Technol. A 2004, 22, 1690-1696
29. Nakamura, I.; Haneda, M.; Hamada, H.; Fujitani, T. Direct Decomposition of Nitrogen Monoxide Over a K-Deposited Co(0001) Surface: Comparison to K-Doped Cobalt Oxide Catalysts J. Electron Spectrosc. Relat. Phenom. 2006, 150, 150-154 (Pubitemid 41737443)
30. Zafeiratos, S.; Dintzer, T.; Teschner, D.; Blume, R.; Hävecker, M.; Knop-Gericke, A.; Schlögl, R. Methanol Oxidation over Model Cobalt Catalysts: Influence of the Cobalt Oxidation State on the Reactivity J. Catal. 2010, 269, 309-317
31. Jaffari, G. H.; Lin, H.-Y.; Ni, C.; Shah, S. I. Physiochemical Phase Transformations in Co/CoO Nanoparticles Prepared by Inert Gas Condensation Mater. Sci. Eng. B 2009, 164, 23-29
32. Boyen, H.-G.; Kästle, G.; Zürn, K.; Herzog, T.; Weigl, F.; Ziemann, P.; Mayer, O.; Jerome, C.; Möller, M.; Spatz, J. P.; et al. Micellar Route to Ordered Arrays of Magnetic Nanoparticles: From Size-Selected Pure Cobalt Dots to Cobalt-Cobalt Oxide Core-Shell Systems Adv. Funct. Mater. 2003, 13, 359-364
33. Khodakov, A. Yu.; Lynch, J.; Basin, D.; Rebours, B.; Zanier, N.; Moisson, B.; Chaumette, P. Reducibility of Cobalt Species in Silica-Supported Fischer-Tropsch Catalysts J. Catal. 1997, 168, 16-25
34. 2 was used. The peaks are normalized in height and shifted at the same BE so as differences in the satellite structure to be pronounced.
35. Escax, V.; Champion, G.; Arrio, M.-A.; Zacchigna, M.; dit Moulin, C. C.; Bleuzen, A. The Co Ligand Field: A Key Parameter in Photomagnetic CoFe Prussian Blue Derivatives Angew. Chem. 2005, 44, 4798-4801 (Pubitemid 41059190)
36. dit Moulin, C. C.; Champion, G.; Cafun, J. -D.; Arrio, M.-A.; Bleuzen, A. Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative Angew. Chem. 2007, 46, 1287-1289 (Pubitemid 46981377)
37. Kumagai, Y.; Ikeno, H.; Oba, F.; Matsunaga, K.; Tanaka, I. Effects of Crystal Structure on Co-L-2,L-3 X-ray Absorption Near-Edge Structure and Electron-Energy-Loss Near-Edge Structure of Trivalent Cobalt Oxides Phys. Rev. B 2008, 77, 155124
38. García-Fernández, P.; García-Lastra, J. M.; Aramburu, J. A.; Barriuso, M. T.; Moreno, M. Strong Dependence of 10 Dq on the Metal-Ligand Distance: Key Role Played by the s-p Hybridization on Ligands Chem. Phys. Lett. 2006, 426, 91-95
39. Meyerheim, H. L.; Tusche, C.; Ernst, A.; Ostanin, S.; Maznichenko, I. V.; Mohseni, K.; Jedrecy, N.; Zegenhagen, J.; Roy, J.; Mertig, I.; Kirschner, J. Wurtzite-Type CoO Nanocrystals in Ultrathin ZnCoO Films Phys. Rev. Lett. 2009, 102, 156102
40. Netze, F. P.; Allegretti, F.; Surnev, S. Low-Dimensional Oxide Nanostructures on Metals: Hybrid Systems with Novel Properties J. Vac. Sci. Technol. B 2010, 28, 1-16
41. Sprouster, D. J.; Giulian, R.; Araujo, L. L.; Kluth, P.; Johannessen, B.; Cookson, D. J.; Foran, G. J.; Ridgway, M. C. Structural and Vibrational Properties of Co Nanoparticles Formed by Ion Implantation J. Appl. Phys. 2010, 107, 014313
42. Tamion, A.; Raufast, C.; Hillenkamp, M.; Bonet, E.; Jouanguy, J.; Canut, B.; Bernstein, E.; Boisron, O.; Wernsdorfer, W.; Dupuis, V. Magnetic Anisotropy of Embedded Co Nanoparticles: Influence of the Surrounding Matrix Phys. Rev. B 2010, 81, 144403
43. Poon, S. W.; Pan, J. S.; Tok, E. S. Nucleation and Growth of Cobalt Nanostructures on Highly Oriented Pyrolytic Graphite Phys. Chem. Chem. Phys. 2006, 8, 3326-3334
44. Salmeron, M.; Schögl, R. Ambient Pressure Photoelectron Spectroscopy: A New Tool for Surface Science and Nanotechnology Surf. Sci. Rep. 2008, 63, 169-199 and refs therein
45. Zonnevylle, M. C.; Geerlings, J. J. C.; van Santen, R. A. Conversion of Surface Carbidic to Subsurface Carbon on Cobalt (0001)-A Theoretical Study Surf. Sci. 1990, 240, 253-262
46. Perez, A.; Dupuis, V.; Tuaillon-Combes, J.; Bardotti, L.; Prevel, B.; Bernstein, E.; Mélinon, P.; Favre, L.; Hannour, A.; Jamet, M. Functionalized Cluster-Assembled Magnetic Nanostructures For Applications to High Integration-Density Devices Adv. Eng. Mater. 2005, 7, 475-485 (Pubitemid 40952729)
47. Tainoff, D.; Bardotti, L.; Tournus, F.; Guiraud, G.; Boisron, O.; Mélinon, P. Self-Organization of Size-Selected Bare Platinum Nanoclusters: Toward Ultradense Catalytic Systems J. Phys. Chem. C 2008, 112, 6842-6849
48. Tamion, A.; Raufast, C.; Bonet, E.; Dupuis, V.; Fournier, T.; Crozes, T.; Bernstein, E.; Wernsdorfer, W. Magnetization Reversal of a Single Cobalt Cluster Using a RF Field Pulse J. Magn. Magn. Mater. 2010, 622, 1315-1318
49. Jamet, M.; Wernsdorfer, W.; Thirion, C.; Mailly, D.; Dupuis, V.; Mélinon, P.; Pérez, A. Magnetic Anisotropy of a Single Cobalt Nanocluster Phys. Rev. Lett. 2001, 86, 4676-4679 (Pubitemid 32471409)
50. Knop-Gericke, A.; Kleimenov, E. V.; Havecker, M.; Blume, R.; Teschner, D.; Zafeiratos, S.; Schlögl, R.; Bukhtiyarov, V. I.; Kaichev, V. V.; Prosvirin, I. P.; et al. X-ray Photoelectron Spectroscopy for Investigation of Heterogeneous Catalytic Processes Adv. Catal. 2009, 52, 213-272
51. Yeh, J. J.; Lindau, I. Atomic Subshell Photoionization Cross-Sections and Asymmetry Parameters-1 Less-Than-or-Equal-to Z Less-Than-or-Equal-to 103 At. Data Nucl. Data Tables 1985, 32, 1-155
52. de Groot, F. High Resolution X-ray Emission and X-ray Absorption Spectroscopy Chem. Rev. 2001, 101, 1779-1808 (Pubitemid 35381677)
53. Ikeno, H.; de Groot, F.; Stavitski, E.; Tanaka, I. Multiplet Calculations of L-2,L-3 X-Ray Absorption Near-Edge Structures for 3d Transition-Metal Compounds J. Phys.: Condens. Matter. 2009, 21, 104208
54. Stavitski, E.; de Groot, F. M. F. The CTM4XAS Program for EELS and XAS Spectral Shape Analysis of Transition Metal L Edges Micron 2010, 41, 687-694