메뉴 건너뛰기




Volumn 50, Issue 13, 2011, Pages 3010-3012

A fischer carbene within an Arduengo carbene

Author keywords

Carbene ligands; Fischer carbenes; Gold; Manganese; N heterocyclic carbenes

Indexed keywords

ARDUENGO CARBENE; BASIC CONDITIONS; BIPYRIDYL; CARBENE LIGANDS; CHEMICAL EQUATIONS; FISCHER CARBENE COMPLEX; FISCHER CARBENES; HETEROMETALLIC COMPOUNDS; METALLIC IONS; METHYL TRIFLATES; N-HETEROCYCLIC CARBENES; TRANSLOCATION PROCESS;

EID: 79952682346     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201007937     Document Type: Article
Times cited : (38)

References (56)
  • 2
    • 78449247161 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2010, 49, 8810-8849;
    • (2010) Angew. Chem. Int. Ed. , vol.49 , pp. 8810-8849
  • 6
    • 53049091364 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 3122-3172.
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 3122-3172
  • 9
    • 0037090932 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 1290-1309.
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1290-1309
  • 11
    • 33749234189 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 6356-6359;
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 6356-6359
  • 21
    • 0036263823 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 1743-1745;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1743-1745
  • 23
    • 33745716505 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 1463-1467;
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 1463-1467
  • 25
    • 77954027024 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2010, 49, 4759-4762.
    • (2010) Angew. Chem. Int. Ed. , vol.49 , pp. 4759-4762
  • 26
    • 70349966722 scopus 로고    scopus 로고
    • Rhodium and molybdenum complexes of diaminocarbenes containing a 1,1′-disubstituted ferrocene moiety in its backbone have been described
    • Rhodium and molybdenum complexes of diaminocarbenes containing a 1,1′-disubstituted ferrocene moiety in its backbone have been described: a) D. M. Khramov, E. L. Rosen, V. M. Lynch, C. W. Bielawski, Angew. Chem. 2008, 120, 2299-2302;
    • (2008) Angew. Chem. , vol.120 , pp. 2299-2302
    • Khramov, D.M.1    Rosen, E.L.2    Lynch, V.M.3    Bielawski, C.W.4
  • 27
    • 53549118600 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 2267-2270;
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 2267-2270
  • 29
    • 0043087293 scopus 로고
    • A molybdenum-containing four-membered metalla-amidinato complex has been reported
    • A molybdenum-containing four-membered metalla-amidinato complex has been reported: H. Brunner, W. Meier, J. Wachter, I. Bernal, E. Raabe, J. Organomet. Chem. 1989, 362, 95-103.
    • (1989) J. Organomet. Chem. , vol.362 , pp. 95-103
    • Brunner, H.1    Meier, W.2    Wachter, J.3    Bernal, I.4    Raabe, E.5
  • 30
    • 33645386795 scopus 로고    scopus 로고
    • For polymetallic species featuring NHC-based connectors, see
    • For polymetallic species featuring NHC-based connectors, see: a) P. L. Arnold, S. T. Liddle, Organometallics 2006, 25, 1485-1491;
    • (2006) Organometallics , vol.25 , pp. 1485-1491
    • Arnold, P.L.1    Liddle, S.T.2
  • 36
    • 0003036739 scopus 로고
    • For the reactivity of NHC ligands involving deprotonation of N-H groups, see
    • For the reactivity of NHC ligands involving deprotonation of N-H groups, see: a) F. E. Hahn, M. Tamm, J. Organomet. Chem. 1993, 456, C11-C14;
    • (1993) J. Organomet. Chem. , vol.456
    • Hahn, F.E.1    Tamm, M.2
  • 40
    • 79952638311 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum. These signals are split up at low temperature (see the Supporting Information). Most probably the fluxional process involves reversible transfer of the N-Ph group from the carbamoyl moiety to the vicinal carbonyl ligand, thus rendering equivalent both halves of the bipy ligand.
  • 41
    • 79952692499 scopus 로고    scopus 로고
    • CCDC 740746 (3a) and 804379 (4a) contain the suplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • CCDC 740746 (3a) and 804379 (4a) contain the suplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data request/cif.
  • 44
    • 68949157444 scopus 로고    scopus 로고
    • For a recent review on Fischer carbenes, see
    • For a recent review on Fischer carbenes, see: K. H. Dötz, J. Stendel, Jr., Chem. Rev. 2009, 109, 3227-3274.
    • (2009) Chem. Rev. , vol.109 , pp. 3227-3274
    • Dötz, K.H.1    Stendel Jr., J.2
  • 45
    • 50249163848 scopus 로고    scopus 로고
    • For related derivatization reactions by O functionalization of NHCs incorporating an enolate backbone, see
    • For related derivatization reactions by O functionalization of NHCs incorporating an enolate backbone, see: a) V. César, N. Lugan, G. Lavigne, J. Am. Chem. Soc. 2008, 130, 11286-11287;
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 11286-11287
    • César, V.1    Lugan, N.2    Lavigne, G.3
  • 55
    • 0242635994 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 5243-5246;
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 5243-5246


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.