-
1
-
-
79952439487
-
-
For recent reviews, see
-
For recent reviews, see: a) M. Melaimi, M. Soleilhavoup, G. Bertrand, Angew. Chem. 2010, 122, 8992-9032;
-
(2010)
Angew. Chem.
, vol.122
, pp. 8992-9032
-
-
Melaimi, M.1
Soleilhavoup, M.2
Bertrand, G.3
-
2
-
-
78449247161
-
-
Angew. Chem. Int. Ed. 2010, 49, 8810-8849;
-
(2010)
Angew. Chem. Int. Ed.
, vol.49
, pp. 8810-8849
-
-
-
3
-
-
84908659806
-
-
b) S. Díaz-González, N. Marion, S. P. Nolan, Chem. Rev. 2009, 109, 3612-3676;
-
(2009)
Chem. Rev.
, vol.109
, pp. 3612-3676
-
-
Díaz-González, S.1
Marion, N.2
Nolan, S.P.3
-
4
-
-
61349141828
-
-
c) P. de Frémont, N. Marion, S. P. Nolan, Coord. Chem. Rev. 2009, 253, 862-892;
-
(2009)
Coord. Chem. Rev.
, vol.253
, pp. 862-892
-
-
De Frémont, P.1
Marion, N.2
Nolan, S.P.3
-
6
-
-
53049091364
-
-
Angew. Chem. Int. Ed. 2008, 47, 3122-3172.
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 3122-3172
-
-
-
7
-
-
0001286592
-
-
A. J. Arduengo III, R. L. Harlow, M. Kline, J. Am. Chem. Soc. 1991, 113, 361-363.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 361-363
-
-
Arduengo III, A.J.1
Harlow, R.L.2
Kline, M.3
-
9
-
-
0037090932
-
-
Angew. Chem. Int. Ed. 2002, 41, 1290-1309.
-
(2002)
Angew. Chem. Int. Ed.
, vol.41
, pp. 1290-1309
-
-
-
10
-
-
53549112066
-
-
a) T. D. Forster, K. E. Krahulic, H. M. Tuononen, R. McDonald, M. Parvez, R. Roesler, Angew. Chem. 2006, 118, 6504-6507;
-
(2006)
Angew. Chem.
, vol.118
, pp. 6504-6507
-
-
Forster, T.D.1
Krahulic, K.E.2
Tuononen, H.M.3
McDonald, R.4
Parvez, M.5
Roesler, R.6
-
11
-
-
33749234189
-
-
Angew. Chem. Int. Ed. 2006, 45, 6356-6359;
-
(2006)
Angew. Chem. Int. Ed.
, vol.45
, pp. 6356-6359
-
-
-
12
-
-
39749201505
-
-
b) A. Kausamo, H. M. Tuononen, K. E. Krahulic, R. Roesler, Inorg. Chem. 2008, 47, 1145-1154;
-
(2008)
Inorg. Chem.
, vol.47
, pp. 1145-1154
-
-
Kausamo, A.1
Tuononen, H.M.2
Krahulic, K.E.3
Roesler, R.4
-
13
-
-
70149092528
-
-
c) K. E. Krahulic, H. M. Tuononen, M. Parvez, R. Roesler, J. Am. Chem. Soc. 2009, 131, 5858-5865;
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 5858-5865
-
-
Krahulic, K.E.1
Tuononen, H.M.2
Parvez, M.3
Roesler, R.4
-
14
-
-
16244401431
-
-
d) K. E. Krahulic, G. D. Enright, M. Parvez, R. Roesler, J. Am. Chem. Soc. 2005, 127, 4142-4143;
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 4142-4143
-
-
Krahulic, K.E.1
Enright, G.D.2
Parvez, M.3
Roesler, R.4
-
15
-
-
22944464456
-
-
e) C. Präsang, B. Donnadieu, G. Bertrand, J. Am. Chem. Soc. 2005, 127, 10182-10183;
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 10182-10183
-
-
Präsang, C.1
Donnadieu, B.2
Bertrand, G.3
-
17
-
-
33748782011
-
-
g) Y. Ishida, B. Donnadieu, G. Bertrand, Proc. Natl. Acad. Sci. USA 2006, 103, 13585-13588.
-
(2006)
Proc. Natl. Acad. Sci. USA
, vol.103
, pp. 13585-13588
-
-
Ishida, Y.1
Donnadieu, B.2
Bertrand, G.3
-
18
-
-
0000038315
-
-
a) D. Enders, K. Breuer, G. Raabe, J. Runsink, J. H. Teles, J.-P. Melder, K. Ebel, S. Brode, Angew. Chem. 1995, 107, 1119-1122;
-
(1995)
Angew. Chem.
, vol.107
, pp. 1119-1122
-
-
Enders, D.1
Breuer, K.2
Raabe, G.3
Runsink, J.4
Teles, J.H.5
Melder, J.-P.6
Ebel, K.7
Brode, S.8
-
21
-
-
0036263823
-
-
Angew. Chem. Int. Ed. 2002, 41, 1743-1745;
-
(2002)
Angew. Chem. Int. Ed.
, vol.41
, pp. 1743-1745
-
-
-
22
-
-
33746249544
-
-
c) D. Enders, O. Niemeier, T. Balensiefer, Angew. Chem. 2006, 118, 1491-1495;
-
(2006)
Angew. Chem.
, vol.118
, pp. 1491-1495
-
-
Enders, D.1
Niemeier, O.2
Balensiefer, T.3
-
23
-
-
33745716505
-
-
Angew. Chem. Int. Ed. 2006, 45, 1463-1467;
-
(2006)
Angew. Chem. Int. Ed.
, vol.45
, pp. 1463-1467
-
-
-
24
-
-
78449236419
-
-
d) G. Guisado-Barrios, J. Bouffard, B. Donnadieu, G. Bertrand, Angew. Chem. 2010, 122, 4869-4872;
-
(2010)
Angew. Chem.
, vol.122
, pp. 4869-4872
-
-
Guisado-Barrios, G.1
Bouffard, J.2
Donnadieu, B.3
Bertrand, G.4
-
25
-
-
77954027024
-
-
Angew. Chem. Int. Ed. 2010, 49, 4759-4762.
-
(2010)
Angew. Chem. Int. Ed.
, vol.49
, pp. 4759-4762
-
-
-
26
-
-
70349966722
-
-
Rhodium and molybdenum complexes of diaminocarbenes containing a 1,1′-disubstituted ferrocene moiety in its backbone have been described
-
Rhodium and molybdenum complexes of diaminocarbenes containing a 1,1′-disubstituted ferrocene moiety in its backbone have been described: a) D. M. Khramov, E. L. Rosen, V. M. Lynch, C. W. Bielawski, Angew. Chem. 2008, 120, 2299-2302;
-
(2008)
Angew. Chem.
, vol.120
, pp. 2299-2302
-
-
Khramov, D.M.1
Rosen, E.L.2
Lynch, V.M.3
Bielawski, C.W.4
-
27
-
-
53549118600
-
-
Angew. Chem. Int. Ed. 2008, 47, 2267-2270;
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 2267-2270
-
-
-
29
-
-
0043087293
-
-
A molybdenum-containing four-membered metalla-amidinato complex has been reported
-
A molybdenum-containing four-membered metalla-amidinato complex has been reported: H. Brunner, W. Meier, J. Wachter, I. Bernal, E. Raabe, J. Organomet. Chem. 1989, 362, 95-103.
-
(1989)
J. Organomet. Chem.
, vol.362
, pp. 95-103
-
-
Brunner, H.1
Meier, W.2
Wachter, J.3
Bernal, I.4
Raabe, E.5
-
30
-
-
33645386795
-
-
For polymetallic species featuring NHC-based connectors, see
-
For polymetallic species featuring NHC-based connectors, see: a) P. L. Arnold, S. T. Liddle, Organometallics 2006, 25, 1485-1491;
-
(2006)
Organometallics
, vol.25
, pp. 1485-1491
-
-
Arnold, P.L.1
Liddle, S.T.2
-
32
-
-
68149183477
-
-
c) A. Zanardi, J. A. Mata, E. Peris, Organometallics 2009, 28, 4335-4339;
-
(2009)
Organometallics
, vol.28
, pp. 4335-4339
-
-
Zanardi, A.1
Mata, J.A.2
Peris, E.3
-
33
-
-
70349908273
-
-
d) A. Zanardi, J. A. Mata, E. Peris, J. Am. Chem. Soc. 2009, 131, 14531-14537;
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 14531-14537
-
-
Zanardi, A.1
Mata, J.A.2
Peris, E.3
-
34
-
-
77958027694
-
-
e) Y. Wang, Y. Xie, M. Y. Abraham, P. Wei, H. F. Schaeler III, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2010, 132, 14370-14372.
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 14370-14372
-
-
Wang, Y.1
Xie, Y.2
Abraham, M.Y.3
Wei, P.4
Schaeler III, H.F.5
Schleyer, P.V.R.6
Robinson, G.H.7
-
36
-
-
0003036739
-
-
For the reactivity of NHC ligands involving deprotonation of N-H groups, see
-
For the reactivity of NHC ligands involving deprotonation of N-H groups, see: a) F. E. Hahn, M. Tamm, J. Organomet. Chem. 1993, 456, C11-C14;
-
(1993)
J. Organomet. Chem.
, vol.456
-
-
Hahn, F.E.1
Tamm, M.2
-
37
-
-
0037415847
-
-
b) F. E. Hahn, V. Langenhahn, N. Meier, T. Lügger, W. P. Fehlhammer, Chem. Eur. J. 2003, 9, 704-712;
-
(2003)
Chem. Eur. J.
, vol.9
, pp. 704-712
-
-
Hahn, F.E.1
Langenhahn, V.2
Meier, N.3
Lügger, T.4
Fehlhammer, W.P.5
-
39
-
-
78149343882
-
-
d) F. E. Hahn, A. R. Naziruddin, A. Hepp, T. Pape, Organometallics 2010, 29, 5283-5288.
-
(2010)
Organometallics
, vol.29
, pp. 5283-5288
-
-
Hahn, F.E.1
Naziruddin, A.R.2
Hepp, A.3
Pape, T.4
-
40
-
-
79952638311
-
-
note
-
1H NMR spectrum. These signals are split up at low temperature (see the Supporting Information). Most probably the fluxional process involves reversible transfer of the N-Ph group from the carbamoyl moiety to the vicinal carbonyl ligand, thus rendering equivalent both halves of the bipy ligand.
-
-
-
-
41
-
-
79952692499
-
-
CCDC 740746 (3a) and 804379 (4a) contain the suplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
-
CCDC 740746 (3a) and 804379 (4a) contain the suplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data request/cif.
-
-
-
-
42
-
-
0035912001
-
-
D. Lafrance, J. L. Davis, R. Dhawan, B. A. Arndtsen, Organometallics 2001, 20, 1128-1136.
-
(2001)
Organometallics
, vol.20
, pp. 1128-1136
-
-
Lafrance, D.1
Davis, J.L.2
Dhawan, R.3
Arndtsen, B.A.4
-
43
-
-
37049090849
-
-
F. J. García-Alonso, A. Llamazares, V. Riera, M. Vivanco, M. R. Díaz, S. García-Granda, J. Chem. Soc. Chem. Commun. 1991, 1058-1060.
-
(1991)
J. Chem. Soc. Chem. Commun.
, pp. 1058-1060
-
-
García-Alonso, F.J.1
Llamazares, A.2
Riera, V.3
Vivanco, M.4
Díaz, M.R.5
García-Granda, S.6
-
44
-
-
68949157444
-
-
For a recent review on Fischer carbenes, see
-
For a recent review on Fischer carbenes, see: K. H. Dötz, J. Stendel, Jr., Chem. Rev. 2009, 109, 3227-3274.
-
(2009)
Chem. Rev.
, vol.109
, pp. 3227-3274
-
-
Dötz, K.H.1
Stendel Jr., J.2
-
45
-
-
50249163848
-
-
For related derivatization reactions by O functionalization of NHCs incorporating an enolate backbone, see
-
For related derivatization reactions by O functionalization of NHCs incorporating an enolate backbone, see: a) V. César, N. Lugan, G. Lavigne, J. Am. Chem. Soc. 2008, 130, 11286-11287;
-
(2008)
J. Am. Chem. Soc.
, vol.130
, pp. 11286-11287
-
-
César, V.1
Lugan, N.2
Lavigne, G.3
-
46
-
-
68149136528
-
-
b) L. Benhamou, V. César, H. Gornitzka, N. Lugan, G. Lavigne, Chem. Commun. 2009, 4720-4722;
-
(2009)
Chem. Commun.
, pp. 4720-4722
-
-
Benhamou, L.1
César, V.2
Gornitzka, H.3
Lugan, N.4
Lavigne, G.5
-
47
-
-
77957197531
-
-
c) V. César, N. Lugan, G. Lavigne, Chem. Eur. J. 2010, 16, 11432-11442;
-
(2010)
Chem. Eur. J.
, vol.16
, pp. 11432-11442
-
-
César, V.1
Lugan, N.2
Lavigne, G.3
-
48
-
-
77953193730
-
-
d) L. Benhamou, N. Vujkovic, V. César, H. Gornitzka, N. Lugan, G. Lavigne, Organometallics 2010, 29, 2616-2630.
-
(2010)
Organometallics
, vol.29
, pp. 2616-2630
-
-
Benhamou, L.1
Vujkovic, N.2
César, V.3
Gornitzka, H.4
Lugan, N.5
Lavigne, G.6
-
49
-
-
0035904265
-
-
a) M. F. Semmelhack, A. Lindenschmidt, D. Ho, Organometallics 2001, 20, 4114-4117;
-
(2001)
Organometallics
, vol.20
, pp. 4114-4117
-
-
Semmelhack, M.F.1
Lindenschmidt, A.2
Ho, D.3
-
50
-
-
0000343309
-
-
b) Y. Li, S. Kim, C. Kang, J. Ko, S. O. Kang, P. J. Carroll, Organometallics 1998, 17, 1109-1115;
-
(1998)
Organometallics
, vol.17
, pp. 1109-1115
-
-
Li, Y.1
Kim, S.2
Kang, C.3
Ko, J.4
Kang, S.O.5
Carroll, P.J.6
-
51
-
-
0001423668
-
-
c) A. Rabier, N. Lugan, R. Mathieu, G. L. Geoffroy, Organometallics 1994, 13, 4676-4678;
-
(1994)
Organometallics
, vol.13
, pp. 4676-4678
-
-
Rabier, A.1
Lugan, N.2
Mathieu, R.3
Geoffroy, G.L.4
-
53
-
-
53849128564
-
-
For examples, see
-
For examples, see: a) G. C. Vougioukalakis, R. H. Grubbs, Chem. Eur. J. 2008, 14, 7545-7556;
-
(2008)
Chem. Eur. J.
, vol.14
, pp. 7545-7556
-
-
Vougioukalakis, G.C.1
Grubbs, R.H.2
-
54
-
-
3042739617
-
-
b) F. E. Hahn, M. Paus, D. Le Van, T. Lügger, Angew. Chem. 2003, 115, 5402-5405;
-
(2003)
Angew. Chem.
, vol.115
, pp. 5402-5405
-
-
Hahn, F.E.1
Paus, M.2
Le Van, D.3
Lügger, T.4
-
55
-
-
0242635994
-
-
Angew. Chem. Int. Ed. 2003, 42, 5243-5246;
-
(2003)
Angew. Chem. Int. Ed.
, vol.42
, pp. 5243-5246
-
-
-
56
-
-
4544235332
-
-
c) A. O. Larsen, W. Leu, C. N. Oberhuber, J. E. Campbell, A. H. Hoveyda, J. Am. Chem. Soc. 2004, 126, 11130-11131.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 11130-11131
-
-
Larsen, A.O.1
Leu, W.2
Oberhuber, C.N.3
Campbell, J.E.4
Hoveyda, A.H.5
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