Synthesis and characterization of the dicopper(II)-containing 22-palladate(II)[CuII2PdII22P V12O60(OH)8]20-

Angewandte Chemie - International Edition

Volumn 50, Issue 11, 2011, Pages 2639-2642

  Barsukova Stuckart, Maria ^a   Izarova, Natalya V ^a,e   Jameson, Geoffrey B ^b   Ramachandran, Vasanth ^c   Wang, Zhenxing ^c   Van Tol, Johan ^c   Dalal, Naresh S ^c   Ngo Biboum, Rosa ^d   Keita, Bineta ^d   Nadjo, Louis ^d   Kortz, Ulrich ^a  

^a JACOBS UNIVERSITY BREMEN   (Germany)

^b MASSEY UNIVERSITY   (New Zealand)

^c FLORIDA STATE UNIVERSITY   (United States)

^d UNIVERSITÉ PARIS SUD   (France)

^e NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

Author keywords

copper; magnetic properties; palladium; polyoxometalates; structure elucidation

Indexed keywords

DICOPPER; MAGNETIC EXCHANGE COUPLING; POLYANIONS; POLYOXOMETALATES; SODIUM SALT; STRUCTURE ELUCIDATION;

OXIDES;

MAGNETIC PROPERTIES;

EID: 79952259330     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201006734     Document Type: Article

References (27)

1. E. V. Chubarova, M. H. Dickman, B. Keita, L. Nadjo, F. Miserque, M. Mifsud, I. W. C. E. Arends, U. Kortz, Angew. Chem. 2008, 120, 9685-9689
2. Angew. Chem. Int. Ed. 2008, 47, 9542-9546
3. J. C. Goloboy, W. G. Klemperer, Angew. Chem. 2009, 121, 3614-3616
4. Angew. Chem. Int. Ed. 2009, 48, 3562-3564
5. N. V. Izarova, M. H. Dickman, R. Ngo Biboum, B. Keita, L. Nadjo, V. Ramachandran, N. S. Dalal, U. Kortz, Inorg. Chem. 2009, 48, 7504-7506.
6. N. V. Izarova, R. Ngo Biboum, B. Keita, M. Mifsud, I. W. C. E. Arends, G. B. Jameson, U. Kortz, Dalton Trans. 2009, 9385-9387
7. M. Delferro, C. Graiff, L. Elviri, G. Predieri, Dalton Trans. 2010, 39, 4479-4481.
8. M. Barsukova, N. V. Izarova, R. Ngo Biboum, B. Keita, L. Nadjo, V. Ramachandran, N. S. Dalal, N. S. Antonova, J. J. Carbõ, J. M. Poblet, U. Kortz, Chem. Eur. J. 2010, 16, 9076-9085.
9. N. V. Izarova, N. Vankova, T. Heine, R. Ngo Biboum, B. Keita, L. Nadjo, U. Kortz, Angew. Chem. 2010, 122, 1930-1933
10. Angew. Chem. Int. Ed. 2010, 49, 1886-1889
11. N. V. Izarova, N. Vankova, A. Banerjee, G. B. Jameson, T. Heine, F. Schinle, O. Hampe, U. Kortz, Angew. Chem. 2010, 122, 7975-7980
12. Angew. Chem. Int. Ed. 2010, 49, 7807-7811.
13. 3, T=173(2) K.
14. Crystal data and details of the X-ray diffraction experiment are in the Supporting Information. Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository numbers CSD-422151 and -422152 (SQUEEZEd. data).
15. I. D. Brown, D. Altermatt, Acta Crystallogr. Sect. B 1985, 41, 244-247.
16. B. Bleaney, K. D. Bowers, Proc. R. Soc. A 1952, 214, 451-465.
17. P. Chaudhuri, M. Winter, B. P. C. Della Védova, E. Bill, A. Trautwein, S. Gehring, P. Fleischhauer, B. Nuber, J. Weiss, Inorg. Chem. 1991, 30, 2148-2157.
18. J. van Tol, EPR Calc, National High Magnetic Field Laboratory, Tallahassee, FL 32310.
19. D. E. Billing, B. J. Hathaway, P. Nicholls, J. Chem. Soc. A 1970, 1877-1881
20. R. J. Dudley, B. J. Hathaway, P. G. Hodgson, J. Chem. Soc. A 1971, 3355-3358
21. X-M. Chen, T. C. W. Mak, Inorg. Chem. 1994, 33, 2444-2447.
22. B. Cage, A. Hasan, L. Pardi, J. Krzystek, L. C. Brunel, N. S. Dalal, J. Magn. Reson. 1997, 124, 495-498
23. S. Nellutla, J. van Tol, N. S. Dalal, L. H. Bi, U. Kortz, B. Keita, L. Nadjo, G. A. Khitrov, A. G. Marshall, Inorg. Chem. 2005, 44, 9795-9806.
24. C. Batchelor-McAuley, C. E. Banks, A. O. Simm, T. G. J. Jones, R. G. Compton, ChemPhysChem 2006, 7, 1081-1085.
25. F. Li, P. Bertoncello, I. Ciani, G. Mantovani, P. R. Unwin, Adv. Funct. Mater. 2008, 18, 1685-1693.
26. Figure 1 was generated by Diamond Version 3.2 (copyright Crystal Impact GbR).
27. J. van Tol, L. C. Brunel, r. J. Wylde, Rev. Sci. Instrum., 2005, 76, 074101-074108.