Two new interpenetrating networks assembled from 5-methylisophthalic acid and bipyridyl ligand with copper(II) salts

Inorganic Chemistry Communications

Volumn 14, Issue 3, 2011, Pages 493-496

  Xu, Bo ^a,b   Li, Guoliang ^a   Yang, Hongxun ^a   Gao, Shuiying ^a   Cao, Rong ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Bipyridyl ligand; Coordination polymer; Copper(II) complex; Interpenetrating network

Indexed keywords

EID: 79952185006     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.01.009     Document Type: Article

References (25)

1. T.C.W. Mak, X.L. Zhao, Q.M. Wang, and G.C. Guo Synthesis and structural characterization of silver(I) double and multiple salts containing the acetylenediide dianion Coord. Chem. Rev. 251 2007 2311 2333
2. S.R. Batten, and R. Robson Interpenetrating nets: ordered, periodic entanglement Angew. Chem. Int. Ed. 37 1998 1460 1494
3. C. Liu, J. Zhou, L. Wang, Z. Liao, and H. Xu J. Inorg. Biochem. 75 1999 233 (Pubitemid 35377799)
4. L. Carlucci, G. Ciani, and D.M. Proserpio Coord. Chem. Rev. 246 2003 247 289
5. O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Essaoudi, and J. Kim Reticular synthesis and the design of new materials Nature 423 2003 705 714 (Pubitemid 36735687)
6. L.J. Murray, M. Dinca, and J.R. Long Chem. hydrogen storage in metal-organic frameworks Soc. Rev. 38 2009 1294 1314
7. Q.R. Fang, G.F. Zhu, M. Xue, J.Y. Sun, F.X. Sun, and S.L. Qiu Structure, luminescence, and adsorption properties of two chiral microporous metal-organic frameworks Inorg. Chem. 45 2006 3582 3587
8. D. Zhao, D.Q. Yuan, D.F. Sun, and H.C. Zhou Stabilization of metal-organic frameworks with high surface areas by the incorporation of mesocavities with microwindows J. Am. Chem. Soc. 131 2009 9186 9188
9. W. Eerenstein, N.D. Mathur, and J.F. Scott Multiferroic and magnetoelectric materials Nature 442 2006 759 765 (Pubitemid 44261898)
10. Z.G. Guo, R. Cao, X. Wang, H.F. Li, W.B. Yuan, G.J. Wang, H.H. Wu, and J. Li A multifunctional 3d ferroelectric and nlo-active porous metal-organic framework J. Am. Chem. Soc. 131 2009 6894 6895
11. W.H. Bi, R. Cao, D.F. Sun, D.Q. Yuan, X. Li, Y.Q. Wang, X.J. Li, and M.C. Hong Isomer separation, conformation control of flexible cyclohexanedicarboxylate ligand in cadmium complexes Chem. Commun. 2004 2104 2105 (Pubitemid 39389533)
12. X.J. Li, X.Y. Wang, S. Gao, and R. Cao Two three-dimensional metal-organic frameworks containing one-dimensional hydroxyl/carboxylate mixed bridged metal chains: syntheses, crystal structures, and magnetic properties Inorg. Chem. 45 2006 1508 1516
13. F. Li, T.H. Li, X.J. Li, X. Li, Y.L. Wang, and R. Cao Synthesis of chiral coordination polymers by spontaneous resolution Cryst. Growth Des. 6 2006 1458 1462 (Pubitemid 44000228)
14. B. Xu, J. Lü, and R. Cao Anion-assisted structural variation of cadmium coordination polymers: from 2D → 3D inclined polycatenation to 2D → 3D polythreading Cryst. Growth Des. 9 2009 3003 3005
15. Compounds 1 and 2 were isolated by mixing Cu(NO3)2·6H2O (0.2 mmol), bpmp (or bpe) (0.2 mmol), H2mip (0.2 mmol), and NaOH (0.4 mmol) in 8 ml water and stirred for 30 min in air. Then the mixture was transferred to 25 mL stainless-steel reactors with Teflon liner and heated to 120 °C in 3 hours. The temperature was kept at 120 °C for 3 days and cooled to room temperature during 24 hours. Green rod crystals of both 1 and 2 were isolated by filtration, washed with distilled water, and dried in air (yield based on Cu: 59% and 67% for 1-2, respectively). For 1, Anal. Calcd. C17H18N2O5Cu (393.89): C 51.84, H 4.61, N 7.11; found: C 51.78, H 4.57, N 7.23. IR (KBr, cm-1): 3641 (bs), 3059(m), 2948(m), 2820(m), 1623(s), 1571(m), 1356(s), 1127(w), 1009(w), 848(w), 732(s), 490(m). For 2, Anal. Calcd. C15H12N1O4Cu (333.81): C 53.97, H 3.62, N 4.20; found: C 53.88, H 3.65, N 4.24. IR (KBr, cm-1): 3637 (bs), 3078(m), 2918(m), 1848(w), 1625(s), 1587(m), 1217(s), 1107(w), 1022(w), 837(w), 731(s), 495(m).
16. 2 = 0.0894. X-ray single crystal diffraction data collections of 1-2 were performed on a Rigaku Mercury CCD. The structure was solved by direct methods and refined with full-matrix least-squares technique (SHELXTL-97) [14]. All non-hydrogen atoms were treated anisotropically. The positions of the hydrogen atoms attached to carbon atoms were generated geometrically. The idealized positions of the H atoms of water molecules were located from Fourier difference maps and refined isotropically (O-H bond fixed at 0.85 A°).
17. V.A. Blatov IUCr Comput. Commun. Newslett. 7 2006 4 see also http:// www.topos.ssu.samara.ru
18. V.A. Blatov, L. Carlucci, G. Ciani, and D.M. Proserpio Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database Cryst. Eng. Commun. 6 2004 378 395
19. H.Y. He, H.D. Yin, D.Q. Wang, H.Q. Ma, G.Q. Zhang, and D.F. Sun Preparation, crystal structure, and properties of five metal-organic complexes based on a triangular nonplanar carboxylate ligand Eur. J. Inorg. Chem. 2010 4822 4830
20. C.P. Li, J. Chen, Q. Yu, and M. Du Structural modulation and properties of silver(I) coordination frameworks with benzenedicarboxyl tectons and trans-1-(2-Pyridyl)-2-(4-pyridyl)ethylene Spacer Cryst. Growth Des. 10 2010 1623 1632
21. B.F. Abrahams, S.R. Batten, H. Hamit, B.F. Hoskins, and R. Robson A cubic 3,4-connected net with large cavities in solvated [Cu3(tpt)4](ClO4)3 (tpt = 2, 4, 6-Tri(4-pyridyl)-1,3,5-triazine) Angew. Chem. 108 1996 1794 1796
22. 3OH) J. Am. Chem. Soc. 117 1995 5385 5386
23. D.P. Martin, M.R. Montney, R.M. Supkowski, and R.L. LaDuca Cadmium glutarate coordination polymers containing hydrogen-bonding capable tethering organodiimines: from double interpenetration to supramolecular cavities containing an unprecedented water tape morphology Cryst. Growth Des. 8 2008 3091 3097
24. M.R. Montney, S.K. Mallika, R.M. Supkowski, and R.L. LaDuca Diverse entangled metal-organic framework materials incorporating kinked organodiimine and flexible aliphatic dicarboxylate ligands: Synthesis, structure, physical properties, and reversible structural reorganization Inorg. Chem. 46 2007 7362 7370
25. G.M. Sheldrick SHELXS-97, Program for Crystal Structure Solution and Refinement 1997 University of Göttingen Germany