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Volumn 9, Issue 6, 2011, Pages 1731-1735

Synthesis, structures and optical properties of trisilasumanene and its related compounds

Author keywords

[No Author keywords available]

Indexed keywords

CARBON ATOMS; RELATED COMPOUNDS; SUMANENE; TRIPHENYLENES;

EID: 79952165541     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0ob00987c     Document Type: Article
Times cited : (55)

References (30)
  • 25
    • 66749131150 scopus 로고    scopus 로고
    • A Gaussian 03 suite of programs was used for the calculations. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. et al. Gaussian, Inc., Wallingford CT. 2004
    • A Gaussian 03 suite of programs was used for the calculations. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, GAUSSIAN 03, Revision E.01; Gaussian, Inc., Wallingford CT. 2004
    • GAUSSIAN 03, Revision E.01
    • Frisch, M.J.1    Trucks, G.W.2    Schlegel, H.B.3    Scuseria, G.E.4    Robb, M.A.5
  • 26
    • 0002991047 scopus 로고    scopus 로고
    • To know the intrinsic nature of a trisilasumanene framework, strictly speaking, a compound where each of the silicon atoms has two hydrogen atoms should be investigated. However, it seems rather difficult to prepare this compound and hence in this paper we synthesized alkyl-substituted derivatives, which would have the second most intrinsic nature of a trisilasumanene framework. Indeed, σ*-π* conjugation in compounds 1 and 5 is concluded to be rather small Calculations for solvent effect, based on the gas-phase optimized geometries, were carried out using the polarized continuum model (PCM) and the dielectric constant (ε = 8.93) of dichloromethane. The maximum absorption wavelengths were essentially unchanged. See:
    • K. Tamao S. Yamaguchi J. Organomet. Chem. 2000 611 5
    • (2000) J. Organomet. Chem. , vol.611 , pp. 5
    • Tamao, K.1    Yamaguchi, S.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.