Magnesium chloride precipitation from mixed salt solution using 1,4-dioxan

Chemical Engineering Research and Design

Volumn 89, Issue 3, 2011, Pages 367-372

  Fezei, R ^a   Hammi, H ^a   M'nif, A ^a  

^a CENTRE NATIONAL DE RECHERCHES EN SCIENCES DES MATÉRIAUX   (Tunisia)

Author keywords

Dioxan; Magnesium chloride; Mixed salt solution; Precipitation

Indexed keywords

ALKALI METAL CHLORIDES; COMPLEXOMETRY; CONSTANT TEMPERATURE; DIOXAN; MAGNESIUM CHLORIDE; MAGNESIUM CHLORIDES; MAGNESIUM SULPHATES; MIXED SALT SOLUTION; MIXED SALTS; PHYSICOCHEMICAL PROPERTY; POTENTIOMETRY; PRECIPITATION; REACTION EQUILIBRIUM; SOLID-PHASE; TERNARY COMPOUNDS; X-RAY DIFFRACTOGRAMS; XRD;

ALKALI METALS; ALKALINITY; CHLORINE COMPOUNDS; HYDRATES; MAGNESIUM; PHASE EQUILIBRIA;

PRECIPITATION (CHEMICAL);

EID: 79952006710     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2010.06.007     Document Type: Article

References (11)

1. Barnes J.C., Weakley T.J.R. Role of 1,4-dioxan in solid adducts of hydrated metal halides. Crystal structures of hexa-aquadichloromagnesium-1,4-dioxan (1/1), trans-tetra-aquadibromonickel(II)-1,4-dioxan(1/2), and cis-diaquatetra-bromotin(IV)-1,4-dioxan(1/2). J. Chem. Soc. Dalton Trans. 1976, 1786-1790.
2. Bester Rogac M., Dolar D. Phase equilibria in the (water+1,4-dioxane+magnesium chloride) system. Acta Chim. Slov. 1999, 46:463-470.
3. Boyum, O., Skien, Folkestad, F.E., Heistad and Torvund, A., 1973, U.S. Patent 3,729,550.
4. Büchel K.H., Moretto H.H., Waditsch P. Industrial Inorganic Chemistry 2000, Wiley-VCH, Germany. 2nd ed.
5. Burke, W.E. and Smith, W.A., 1949, U.S. Patent 2,479,001.
6. Fezei R., Hammi H., M'nif A. Selective recovery of bischofite from sebkha el melah natural brine. Lat. Am. Appl. Res. 2009, 39:375-380.
7. Gaska, R.A., 1967, U.S. Patent 3,357,800.
8. Robinson R.A., Stokes R.H. Electrolyte Solutions 1965, Butterworths, London. 2nd ed.
9. Smith, R.P., 1970, U.S. Patent 3,516,785.
10. Weicksel J.A., Lynch C.C. The ternary systems magnesium chloride-dioxane-water, cadmium chloride-dioxane-water and cupric chloride-dioxane-water. J. Am. Chem. Soc. 1950, 72:2632-2636.
11. Weissenberg, U.W., 1969, U.S. Patent 3,440,006.