Reactive extraction of glycolic acid using tri- n -butyl phosphate and tri- n -octylamine in six different diluents: Experimental data and theoretical predictions

Industrial and Engineering Chemistry Research

Volumn 50, Issue 5, 2011, Pages 3041-3048

  Datta, Dipaloy ^a   Kumar, Sushil ^a  

^a BIRLA INSTITUTE OF TECHNOLOGY AND SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACID CONCENTRATIONS; ACID MOLECULES; AQUEOUS SOLUTIONS; DISTRIBUTION COEFFICIENT; EXPERIMENTAL DATA; EXPERIMENTAL VALUES; EXTRACTANT MOLECULES; EXTRACTANTS; GLYCOLIC ACIDS; ISOTHERMAL CONDITIONS; LINEAR SOLVATION ENERGY RELATIONSHIPS; N-HEXANE; REACTIVE EXTRACTION; SOLUTE-SOLVENT INTERACTION; THEORETICAL PREDICTION; TRI-N-BUTYL PHOSPHATE; TRI-N-OCTYLAMINE;

BENZENE; COMPLEXATION; DICHLOROMETHANE; EQUILIBRIUM CONSTANTS; MATHEMATICAL MODELS; PARAFFINS; SOLUTIONS;

HEXANE;

EID: 79951989009     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102024u     Document Type: Conference Paper

References (23)

1. Xu Li, N.; Fox, W.; Zaher, N.; Dicosimo, C. F. Method for the Production of Glycolic Acid from Ammonium Glycolate by Direct Deammoniation. Patent WO/2006/069129, June 23, 2006.
2. Kumar, S.; Babu, B. V. Process intensification for separation of carboxylic acids from fermentation broths using reactive extraction J. Future Eng. Technol. 2008, 3 (3) 21
3. Kertes, A. S.; King, C. J. Extraction chemistry of fermentation product carboxylic acids Biotechnol. Bioeng. 1986, 28, 269
4. John, A. D. Lange's Handbook of Chemistry, 20 th ed.; McGraw-Hill: New York, 1972.
5. Tamada, J. A.; Kertes, A. S.; King, C. J. Extraction of carboxylic acids with amine extractants. 1. Equilibria and law of mass action modeling Ind. Eng. Chem. Res. 1990, 29, 1319
6. Tamada, J. A.; King, C. J. Extraction of carboxylic acids with amine extractants. 2. Chemical interactions and interpretation of data Ind. Eng. Chem. Res. 1990, 29, 1327
7. Yang, S. T.; White, S. A.; Hsu, S. T. Extraction of carboxylic acids with tertiary and quaternary amines Ind. Eng. Chem. Res. 1991, 30, 1335
8. Kumar, S.; Babu, B. V. Extraction of pyridine-3-carboxylic acid using 1-dioctylphosphoryloctane (TOPO) with different diluents: Equilibrium studies J. Chem. Eng. 2009, 54 (9) 2669
9. Keshav, A.; Wasewar, K. L.; Chand, S. Extraction of propionic acid with tri-n-octyl amine in different diluents Sep. Purif. Technol. 2008, 63, 179
10. Uslu, H.; Inci, I. (Liquid + liquid) equilibria of the (water + propionic acid + Aliquat 336 + organic solvents) at T = 298.15 K J. Chem.Thermodyn. 2007, 39, 804
11. Kumar, S.; Datta, D.; Babu, B. V. Experimental data and theoretical (Chemodel using the differential evolution approach and Linear Solvation Energy Relationship model) predictions on reactive extraction of monocarboxylic acids using tri-n-octylamine J. Chem. Eng. Data 2010, 55, 4290
12. Inci, I. Distribution of glycolic acid between water and different organic solutions Chem. Biochem. Eng. Q. 2002, 16 (2) 81
13. Li, Y.; Wang, Y.; Li, Y.; Dai, Y. Extraction of glyoxylic acid, glycolic acid, acrylic acid, and benzoic acid with trialkylphosphine oxide J. Chem. Eng. Data 2003, 48, 621
14. Qin, W.; Zhang, Y.; Li, Z.; Dai, Y. Extraction equilibria of glycolic and glyoxylic acids with trialkylphosphine oxide and trioctylamine as extractant J. Chem. Eng. Data 2003, 48, 430
15. Yunhai, S.; Houyong, S.; Deming, L.; Qinghua, L.; Dexing, C.; Yongchuan, Z. Separation of glycolic acid from glycolonitrile hydrolysate by reactive extraction with tri- n -octylamine Sep. Purif. Technol. 2006, 49, 20
16. Inci, I.; Uslu, H. Extraction of glycolic acid from aqueous solutions by trioctyl methylammonium chloride and organic solvents J. Chem. Eng. Data 2005, 50, 536
17. Asci, Y. S.; Inci, I. Extraction of glycolic acid from aqueous solutions by Amberlite LA-2 in different diluent solvents J. Chem. Eng. Data 2009, 54, 2791
18. Tamada, J. A.; Kertes, A. S.; King, C. J. Extraction of carboxylic acids with amine extractants. 3. Effect of temperature, water co-extraction, and process considerations Ind. Eng. Chem. Res. 1990, 29, 1333
19. Yankov, D.; Molinier, J.; Albet, J.; Malmary, G.; Kyuchoukov, G. Lactic acid extraction from aqueous solutions with tri-n-octylamine dissolved in decanol and dodecane Biochem. Eng. J. 2004, 21 (1) 63
20. Kamlet, M. J.; Abboud, J. L. M.; Abraham, M. H.; Taft, R. W. Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, π*, α, and β, and some methods for simplifying the generalized solvatochromic equation J. Org. Chem. 1983, 48, 2877
21. Bizek, V.; Horacek, J.; Kousova, A.; Herberger, A.; Prochazka, J. Mathematical model of extraction of malic acid with amine Chem. Eng. Sci. 1992, 47, 1433
22. Niitsu, M.; Sekine, T. Solvent extraction of ionic solutes in aqueous solutions Bull. Chem. Soc. Jpn. 1978, 51, 705
23. Yerger, E. A.; Barrow, G. M. Acid-base reactions in non-dissociating solvents: Acetic acid and diethylamine in carbon tetrachloride and chloroform J. Am. Chem. Soc. 1955, 77, 4474