Total syntheses of (±)-(Z)- and (±)-(E)-9-(bromomethylene)-1, 5,5-trimethylspiro[5.5]undeca-1,7-dien-3-one and (±)-majusculone

Synthesis

Volumn , Issue 5, 2011, Pages 715-722

  Zhu, Jia Liang ^a   Huang, Po Wei ^a   You, Ruei Yi ^a   Lee, Fa Yan ^a   Tsao, Sheng Wei ^a   Chen, I Chia ^b  

^a NATIONAL DONG HWA UNIVERSITY   (Taiwan)

^b CARDINAL TIEN COLLEGE OF HEALTHCARE AND MANAGEMENT   (Taiwan)

Author keywords

chamigrenes; Diels Alder reaction; majusculone; sesquiterpenes; total syntheses

Indexed keywords

CHAMIGRENES; DIELS-ALDER REACTION; MAJUSCULONE; SESQUITERPENES; TOTAL SYNTHESIS;

OLEFINS;

SYNTHESIS (CHEMICAL);

(9 BROMOMETHYLENE 1,5,5, TRIMETHYLSPIRO[5.5]UNDECA 1,7 DIEN 3 XYLOXY) TERT BUTYLDIMETHYLSILANE; 1 BUT 3 ENYL 2,6,6 TRIMETHYL 4 OXOCYCLOHEX 2 ENECARBOXYLIC ACID ETHYL ESTER; 1 BUT 3 ENYL 4 (TERT BUTYLDIMETHYLSILYLOXY) 2,6,6 TRI METHYLCYCLOHEX 3 ENECARBOXYCYLIC ACID ETHYL ESTER; 1 BUT 3 ENYL 4 (TERT BUTYLDIMETHYLSILYLOXY) 2,6,6 TRIMETHYLCYCLOHEX 2 ENECARBOXYCYCLOHEX 2 ENECARBOXYLIC ACID ETHYL ESTER; 1 BUT 3 ENYL 4 HYDROXY 2,6,6 TRIMETHYLCYCLOHEX 2 ENECARBOXYCYLIC ACID ETHYL ESTER; 4 (TERT BUTYLDIMETHYLSILYLOXY) 1 CYANO 2,6,6 TRIMETHYLCYCLOHEX 3 ENECARBOXYLIC ACID ETHYL ESTER; 4 (TERT BUTYLDIMETHYLSILYLOXY) 2,6 TRIMETHYLCYCLOHEX 3 ENYL ETHANONE; 4 (TERT BUTYLDIMETHYLSILYLOXY) 2,6,6 TRIMETHYL 1 (3 OXOBUTYL)CYCLOHEX 2 ENECARBOXYLIC ACID ETHYL ESTER; 9 (BROMOMETHYLENE) 1,5,5, TRIMETHYLSPIRO[5.5]UNDECA 1,7 DIEN 3 ONE; 9 (TERT BUTYLDIMETHYLSILOXY) 7,11,11 TRIMETHYL SPIRO [5.5] UNDECA 1,7 DIEN 3ONE; 9 BROMOMETHYLENE 1,5,5, TRIMETHYLSPIRO[5.5]UNDECA 1,7 DIEN 3 OL; ETHYL 2 CYANO 3 METHYLBUT 2 ENOATE; MAJUSCULONE; SESQUITERPENOID; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CONTROLLED STUDY; DIELS ALDER REACTION; DRUG ANALYSIS; DRUG STRUCTURE; DRUG SYNTHESIS;

EID: 79951849817     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258412     Document Type: Article

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