Gas-phase reactions of the bare Th2+ and U2+ ions with small alkanes, CH4, C2H6, and C 3H8: Experimental and theoretical study of elementary organoactinide chemistry

Journal of the American Chemical Society

Volumn 133, Issue 6, 2011, Pages 1955-1970

  Di Santo, Emanuela ^a   Santos, Marta ^b   Michelini, Maria C ^a   Marçalo, Joaquim ^b   Russo, Nino ^a   Gibson, John K ^c  

^a UNIVERSITY OF CALABRIA   (Italy)

^b INSTITUTO TECNOLÓGICO E NUCLEAR   (Portugal)

^c LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTINIDE IONS; BOND FORMATION; C-C ACTIVATIONS; DIVALENT STATE; EMPIRICAL MODEL; ENERGETIC BARRIERS; ENERGETIC DIFFERENCES; FOURIER TRANSFORM ION CYCLOTRON RESONANCE MASS SPECTROMETRY; GAS-PHASE REACTIONS; ION-MOLECULE REACTION; ORGANOACTINIDE CHEMISTRY; POTENTIAL ENERGY PROFILES; POTENTIAL REACTIONS; PRODUCT DISTRIBUTIONS; REACTION PATHWAYS; THEORETICAL STUDY; VALENCE ELECTRON;

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; FOURIER TRANSFORMS; IONS; MASS SPECTROMETRY; PARAFFINS; PHASE INTERFACES; REACTION PRODUCTS;

EXPERIMENTS;

ACTINIDE; ALKANE; ETHANE; METHANE; PROPANE; THORIUM; URANIUM;

ADDITION REACTION; ARTICLE; BIOENERGY; CHEMICAL REACTION; COMPARATIVE STUDY; CYCLOTRON; DENSITY FUNCTIONAL THEORY; EMPIRICISM; ENERGY TRANSFER; FOURIER TRANSFORM MASS SPECTROMETRY; GAS; MOLECULE; REACTION ANALYSIS;

EID: 79951541698     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109621n     Document Type: Article

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