Hypersensitivity in the luminescence and 4f-4f absorption properties of mono- and dinuclear Eu III and Er III complexes based on fluorinated β-diketone and diimine/ bis-diimine Ligands

Journal of Fluorescence

Volumn 21, Issue 1, 2011, Pages 81-93

  Irfanullah, Mir ^a   Iftikhar, Khalid ^a  

^a JAMIA MILLIA ISLAMIA CENTRAL UNIVERSITY   (India)

Author keywords

4f 4f absorption; Erbium; Europium; Hypersensitivity; Luminescence; Solvent effect

Indexed keywords

4F-4F ABSORPTION; ABSORPTION PROPERTY; ANCILLARY LIGANDS; BAND SHAPES; BIOLOGICAL APPLICATIONS; BIPYRIDYL; BULK COMPOSITIONS; COORDINATING SOLVENTS; COORDINATION SPHERE; COORDINATION STRUCTURES; DIIMINE LIGAND; DIKETONATE COMPLEXES; DIKETONES; DINUCLEAR; DONOR SOLVENTS; ERBIUM COMPLEXES; EU COMPLEXES; HETEROCYCLIC LIGANDS; HYPERSENSITIVE TRANSITIONS; HYPERSENSITIVITY; LANTHANIDE COMPLEX; LUMINESCENCE INTENSITY; LUMINESCENCE PROPERTIES; MONONUCLEAR COMPLEXES; NON-AQUEOUS SOLVENTS; OSCILLATOR STRENGTHS; PHENANTHROLINES; RADIATIVE RATES; SOLVENT EFFECT; SOLVENT INTERACTIONS;

ABSORPTION; ERBIUM; EUROPIUM; KETONES; LIGANDS; LUMINESCENCE; LUMINESCENCE OF INORGANIC SOLIDS; NEODYMIUM COMPOUNDS; PYRIDINE; SOLVENTS; SPHERES;

COMPLEXATION;

EID: 79951517082     PISSN: 10530509     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10895-010-0691-4     Document Type: Article

References (48)

1. JCG Bünzli 2006 Benefiting from the unique properties of lanthanide ions Acc Chem Res 39 53 61 10.1021/ar0400894 16411740
2. E Brunet J Olga JC Rodriguez-Ubis 2007 Supramolecularly organized lanthanide complexes for efficient metal excitation and luminescence as sensors in organic and biological applications Curr Chem Biol 1 11 39 1:CAS:528:DC%2BD2sXhsFaltr0%3D 10.2174/187231307779814039
3. J Kido Y Okamoto 2002 Organo lanthanide metal complexes for electroluminescent materials Chem Rev 102 2357 2368 1:CAS:528: DC%2BD38Xjs1Snt70%3D 10.1021/cr010448y 12059271 (Pubitemid 35381658)
4. K Binnemans 2009 Lanthanide-based luminescent hybrid materials Chem Rev 109 4283 4374 1:CAS:528:DC%2BD1MXptleltLk%3D 10.1021/cr8003983 19650663
5. Leonard JP, dos Santos CMG, Plush SE. McCabe T, Gunnlaugsson T (2007) pH driven self-assembly of a ternary lanthanide luminescence complex: the sensing of anions using a β-diketonate-Eu(III) displacement assay. Chem Commun (2):129-131 (Pubitemid 44974565)
6. I Hemmilä V Laitala 2005 Progress in lanthanides as luminescent probes J Fluoresc 15 529 542 10.1007/s10895-005-2826-6 16167211 (Pubitemid 41361160)
7. N Sabatini M Guardigli JM Lehn 1993 Luminescent lanthanide complexes as photochemical supramolecular devices Coord Chem Rev 123 201 228 10.1016/0010-8545(93)85056-A
8. MHV Werts 2005 Making sense of lanthanide luminescence Sci Prog 88 101 131 1:CAS:528:DC%2BD28XmtFKgtrs%3D 10.3184/003685005783238435 16749431
9. S Lis M Elbanowski B Ma̧kowska Z Hatejko 2002 Energy transfer in solution of lanthanide complexes J Photochem Photobiol A 150 233 247 1:CAS:528:DC%2BD38XltVOrsLg%3D 10.1016/S1010-6030(01)00637-2
10. Binnemans K (2005) Rare-earth beta-diketonates. In: Gschneidner KA Jr, Bünzli JCG, Pecharsky VK (eds) Handbook on the physics and chemistry of rare earths, vol 35. Elsevier, Amsterdam, pp 107-272
11. DG Karraker 1967 Hypersensitive transitions of six-, seven-, and eight-coordinate neodymium, holmium, and erbium chelates Inorg Chem 6 1863 1868 1:CAS:528:DyaF2sXltVektrY%3D 10.1021/ic50056a022
12. AA Ansari M Irfanullah K Iftikhar 2007 Optical absorption and NMR spectroscopic studies on paramagnetic neodymium(III) complexes with β-diketone and heterocyclic amines: the environment effect on 4f-4f hypersensitive transitions Spectrochim Acta A 67 1178 1188 1:STN:280: DC%2BD2szpslegtw%3D%3D 10.1016/j.saa.2006.10.005 (Pubitemid 47017758)
13. AA Ansari HA Hussain K Iftikhar 2007 Optical absorption spectroscopic studies on holmium(III) complexes with β-diketone and heterocyclic amines: the environment effect on 4f-4f hypersensitive transitions Spectrochim Acta A 68 1305 1312 1:STN:280:DC%2BD2sjgvVOnug%3D%3D 10.1016/j.saa.2007.02.007 (Pubitemid 350161403)
14. K Binnemans RV Deun CG Walrand SR Collinson F Martin DW Bruce C Wickleder 2000 Spectroscopic behaviour of lanthanide(III) coordination compounds with Schiff base ligands Phys Chem Chem Phys 2 3753 3757 1:CAS:528: DC%2BD3cXlslKrsbY%3D 10.1039/b003379k
15. III in nonaqueous solutions Polyhedron 16 4153 4161 1:CAS:528:DyaK2sXntVOktb8%3D 10.1016/S0277-5387(97) 00138-1 (Pubitemid 127346095)
16. AA Ansari N Singh AF Khan SP Singh K Iftikhar 2007 Solvent effect on optical properties of hydrated lanthanide tris-acetylacetone J Lumin 127 446 452 1:CAS:528:DC%2BD2sXptFyksr4%3D 10.1016/j.jlumin.2007.02.057 (Pubitemid 47238863)
17. I Hemmilä VM Mukkala H Takalo 1995 Effect of C-H bonds on the quenching of luminescent lanthanide chelates J Fluoresc 5 159 163 10.1007/BF00727533
18. SV Eliseeva OV Kotova F Gumy SN Semenov VG Kessler LS Lepnev JCG Bünzli NP Kuzmina 2008 Role of the ancillary ligand N, N- dimethylaminoethanol in the sensitization of EuIII and TbIII luminescence in dimeric β-diketonates J Phys Chem A 112 3614 3226 1:CAS:528: DC%2BD1cXjsFGisrk%3D 10.1021/jp711305u 18358016
19. S Biju MLP Reddy AH Cowley KV Vasudeven 2009 Molecular ladders of lanthanide-3-phenyl-4-benzoyl-5-isoxazolonate and bis(2-(diphenylphosphino) phenyl) ether oxide complexes: the role of the ancillary ligand in the sensitization of Eu and Tb luminescence Cryst Growth Des 9 3562 3569 1:CAS:528:DC%2BD1MXmtl2msbw%3D 10.1021/cg900304g
20. CS Springer Jr DW Meek RE Sievers 1967 Rare earth chelates of 1, 1, 1, 2, 2, 3, 3-heptafluoro-7, 7-dimethyl-4, 6-octanedione Inorg Chem 6 1105 1110 1:CAS:528:DyaF2sXkt1yrsLk%3D 10.1021/ic50052a009
21. K Iftikhar M Sayeed N Ahmad 1982 Mixed-ligand complexes of trivalent lanthanide ions with.beta.-diketones and heterocyclic amines Inorg Chem 21 80 84 1:CAS:528:DyaL38XksFaisA%3D%3D 10.1021/ic00131a015
22. M Irfanullah K Iftikhar 2009 New dinuclear lanthanide(III) complexes based on 6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octanedione and 2, 2′-bipyrimidine Inorg Chem Commun 12 296 299 1:CAS:528: DC%2BD1MXjslOrsbY%3D 10.1016/j.inoche.2009.01.007
23. M Sayeed N Ahmad 1981 Mixed ligand complexes of trivalent lanthanide ions with β-diketones and heterocyclic amines and their use as possible shift reagents J Inorg Nucl Chem 43 3197 3202 1:CAS:528:DyaL38XksVylsLs%3D 10.1016/0022-1902(81)80088-7
24. LR Melby NJ Rose E Abramson JC Caris 1964 Synthesis and fluorescence of some trivalent lanthanide complexes J Am Chem Soc 86 5117 5125 1:CAS:528:DyaF2MXnt1Gl 10.1021/ja01077a015
25. DR van Staveren GA van Albada JG Haasnoot H Kooijman AMM Lanfredi PJ Nieuwenhuizen AL Spek F Ugozzoli T Weyhermüller J Reedijk 2001 Increase in coordination number of lanthanide complexes with 2, 2′-bipyridine and 1, 10-phenanthroline by using β-diketonates with electron-withdrawing groups Inorg Chim Acta 315 163 171 10.1016/S0020-1693(01)00334-6 (Pubitemid 32304492)
26. 1H NMR, 4f-4f absorption and photoluminescence Inorg Chim Acta 10.1016/j.ica.2010.04.040
27. FS Richardson 1982 Terbium(III) and europium(III) ions as luminescent probes and stains for biomolecular systems Chem Rev 82 541 552 1:CAS:528:DyaL38XmtFWktr0%3D 10.1021/cr00051a004
28. Y Hasegawa T Si T Yoshida H Kawai T Kawai 2008 Enhanced deep-red luminescence of tris(hexafluoroacetylacetonato)samarium(III) complex with phenanthroline in solution by control of ligand coordination J Phys Chem A 112 803 807 1:CAS:528:DC%2BD1cXmtFOnuw%3D%3D 10.1021/jp075855d 18197640 (Pubitemid 351291636)
29. M Latva H Takalo VM Mukkala C Matachescu JC Rodríguez-Ubis J Kankare 1997 Correlation between the lowest triplet state energy level of the ligand and lanthanide(III) luminescence quantum yield J Lumin 75 149 169 1:CAS:528:DyaK2sXlvVKktLY%3D 10.1016/S0022-2313(97)00113-0 (Pubitemid 127403587)
30. 2) and its dependence on ligand triplet state energy J Lumin 93 199 204 1:CAS:528:DC%2BD3MXkt1Kmtbo%3D 10.1016/S0022-2313(01)00194-6 (Pubitemid 32546728)
31. B Yan YS Song 2004 Spectroscopic study on the photophysical properties of lanthanide complexes with 2, 2′-bipyridyl-N, N′-dioxide J Fluoresc 14 289 293 1:CAS:528:DC%2BD2cXjt1eitrc%3D 10.1023/B:JOFL.0000024561.55183.26 15615211
32. DBA Raj S Biju MLP Reddy 2008 One-, two-, and three-dimensional arrays of Eu-4, 4, 5, 5, 5-pentafluoro-1-(naphthalen-2-yl)pentane-1, 3-dione complexes: synthesis, crystal structure and photophysical properties Inorg Chem 47 8091 8100 1:CAS:528:DC%2BD1cXhtVWhs7zL 10.1021/ic8004757
33. YS Yang ML Gong YY Li HY Lei SL Wu 1994 Effects of the structure of ligands and their Ln complexes on the luminescence of the central Ln ions J Alloys Compd 207 112 114 10.1016/0925-8388(94)90189-9
34. A Fratini G Richards E Larder S Swavey 2008 Neodymium, gadolinium, and terbium complexes containing hexafluoroacetylacetonate and 2, 2′-bipyrimidine: structural and spectroscopic characterization Inorg Chem 47 1030 1036 1:CAS:528:DC%2BD1cXitFaktA%3D%3D 10.1021/ic701805t 18171057
35. III) β-diketonate complexes with diimines and bis-diimine bridging ligand. J Lumin. doi: 10.1016/j.jlumin.2010.05.015
36. Q Li T Li J Wu 2001 Luminescence of europium(III) and terbium(III) complexes incorporated in poly(vinyl pyrrolidone) matrix J Phys Chem B 105 12293 12296 1:CAS:528:DC%2BD3MXotlWmsr0%3D 10.1021/jp012922+ (Pubitemid 35338332)
37. C Piguet JCG Bünzli 1999 Mono- and polymetallic lanthanide- containing functional assemblies: a field between tradition and novelty Chem Soc Rev 28 347 358 1:CAS:528:DyaK1MXntFWqtr8%3D 10.1039/a804240c
38. WT Carnall PR Fields BG Wybourne 1965 Spectral intensities of the trivalent lanthanides and actinides in solution. I. Pr, Nd, Er, Tm, and Yb J Chem Phys 42 3797 3806 1:CAS:528:DyaF2MXktVSqt7c%3D 10.1063/1.1695840
39. K Iftikhar N Ahmad 1985 Complexes of β-diketone and heterocyclic amines: synthesis and spectroscopic studies Polyhedron 4 333 342 1:CAS:528:DyaL2MXitlSrtr0%3D 10.1016/S0277-5387(00)84509-X
40. H Wang G Qian Z Wang M Wang 2005 Spectroscopic properties and Judd-Ofelt theory analysis of erbium chelate Spectrochim Acta A 62 146 152 10.1016/j.saa.2004.12.018 (Pubitemid 41562597)
41. RD Peacock 1975 The intensities of lanthanide f of transitions Struct Bond 22 83 122 1:CAS:528:DyaE28XitlOqug%3D%3D 10.1007/BFb0116556
42. AA Khan K Iftikhar 1994 Mixed-ligand lanthanide complexes-VII. Complexes of 1, 10-phenanthroline and thiocyanate Polyhedron 13 3199 3208 1:CAS:528:DyaK2MXjtVWrtL4%3D 10.1016/S0277-5387(00)83382-3
43. DG Karraker 1971 Spectral studies on the Nd and Er chelates of heptafluorodimethyloctanedione J Inorg Nucl Chem 33 3713 3718 1:CAS:528:DyaE38Xlt1eltg%3D%3D 10.1016/0022-1902(71)80278-6
44. Walrand CG, Binnemans K (1998) Spectral intensities of f-f transitions. In: Gschneidner KA, Eyring L Jr (eds) Handbook on the physics and chemistry of rare earths, vol 25. Elsevier, Amsterdam, pp 101-264
45. CK Jørgensen BR Judd 1964 Hypersensitive pseudoquadrupole transitions in lanthanides Mol Phys 8 281 290 10.1080/00268976400100321
46. AA Khan AK Saxena K Iftikhar 1997 Mixed-ligand lanthanide complexes X. Interaction of trivalent lanthanides with 1, 10-phenanthroline and thiocyanate in alcohol Polyhedron 16 4143 4151 1:CAS:528:DyaK2sXntVOktLc%3D 10.1016/S0277-5387(97)00139-3 (Pubitemid 127346094)
47. Y Hasegawa Y Kimura K Murakoshi Y Wada J Kim N Nakashima T Yamanaka S Yanagida 1996 Enhanced emission of deuterated tris(hexafluoroacetoacetylacetonato) neodymium(III) complex in solution by suppression of radiationless transition via vibrational excitation J Phys Chem 100 10201 10205 1:CAS:528:DyaK28XjtFWmtb8%3D 10.1021/jp960290z (Pubitemid 126789343)
48. HF Brito OL Malta JFS Menezes 2000 Luminescent properties of diketonates of trivalent europium with dimethyl sulfoxide J Alloys Compd 303 336 339 10.1016/S0925-8388(00)00604-6