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Volumn 29, Issue 1, 2011, Pages 72-85

Thermodynamic and spectroscopic studies on Am(III) and Eu(III) in the extraction system of N,N,N',N'-Tetraoctyl-3-Oxapentane-1,5-Diamide in n-Dodecane/nitric acid

Author keywords

Americium(III); Europium(III); N,N,N',N' tetraoctyl 3 oxapentane 1,5 diamide (TODGA); Solvent extraction; Thermodynamic parameters

Indexed keywords

BINDING MODES; DHDECMP; DIAMIDES; DODECANE; EXTRACTANTS; EXTRACTION SYSTEMS; LUMINESCENCE LIFETIME; N,N,N',N'-TETRAOCTYL-3-OXAPENTANE-1,5-DIAMIDE (TODGA); PHOSPHINE OXIDE; PHOSPHONATES; SPECTROSCOPIC STUDIES; THERMODYNAMIC PARAMETER; THERMODYNAMIC PARAMETERS; TRIVALENT F-ELEMENTS;

EID: 79551699519     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2011.539127     Document Type: Article
Times cited : (55)

References (27)
  • 2
    • 0029674876 scopus 로고    scopus 로고
    • Actinide partitioning from HLW in a continuous DIDPA extraction process by means of centrifugal extractors
    • Morita, Y.; Glatz, J.-P.; Kubota, M.; Koch, L.; Pagliosa, G.; Römer, K.; Nicholl, A. Actinide partitioning from HLW in a continuous DIDPA extraction process by means of centrifugal extractors. Solv. Extr. Ion Exch. 1996, 14(3), 385-400.
    • (1996) Solv. Extr. Ion Exch. , vol.14 , Issue.3 , pp. 385-400
    • Morita, Y.1    Glatz, J.-P.2    Kubota, M.3    Koch, L.4    Pagliosa, G.5    Römer, K.6    Nicholl, A.7
  • 3
    • 84972959207 scopus 로고
    • The TRUEX process - a process for the extraction of the transuranic elements from nitric acid in wastes utilizing modified PUREX solvent
    • Horwitz, E.P.; Kalina, D.G.; Diamond, H.D.; Vandergrift, G.F.; Schultz, W.W. The TRUEX process - a process for the extraction of the transuranic elements from nitric acid in wastes utilizing modified PUREX solvent. Solv. Extr. Ion Exch. 1985, 3(1-2), 75-109.
    • (1985) Solv. Extr. Ion Exch. , vol.3 , Issue.1-2 , pp. 75-109
    • Horwitz, E.P.1    Kalina, D.G.2    Diamond, H.D.3    van der Grift, G.F.4    Schultz, W.W.5
  • 4
    • 0024091593 scopus 로고
    • The TRUEX process and the management of liquid TRU waste
    • Schultz, W.W.; Horwitz, E.P. The TRUEX process and the management of liquid TRU waste. Sep. Sci. Technol. 1988, 23, 1191-1210.
    • (1988) Sep. Sci. Technol. , vol.23 , pp. 1191-1210
    • Schultz, W.W.1    Horwitz, E.P.2
  • 6
    • 0034491817 scopus 로고    scopus 로고
    • Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process
    • Courson, O.; Lebrun, M.; Malmbeck, R.; Pagliosa, G.; Römer, K.; Sätmark, B.; Glatz, J.-P. Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process. Radiochim. Acta 2000, 88, 857-863.
    • (2000) Radiochim. Acta , vol.88 , pp. 857-863
    • Courson, O.1    Lebrun, M.2    Malmbeck, R.3    Pagliosa, G.4    Römer, K.5    Sätmark, B.6    Glatz, J.-P.7
  • 7
    • 0034494211 scopus 로고    scopus 로고
    • Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 - "Hot" continuous counter-current experiment
    • Malmbeck, R.; Courson, O.; Pagliosa, G.; Römer, K.; Sätmark, B.; Glatz, J.-P.; Baron, P. Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 - "Hot" continuous counter-current experiment. Radiochim. Acta 2000, 88, 865-871.
    • (2000) Radiochim. Acta , vol.88 , pp. 865-871
    • Malmbeck, R.1    Courson, O.2    Pagliosa, G.3    Römer, K.4    Sätmark, B.5    Glatz, J.-P.6    Baron, P.7
  • 8
    • 0001072741 scopus 로고
    • Chinese experience in the removal of actinides from highly active waste by trialkylphosphine-oxide extraction
    • Zhu, Y.; Jiao, R. Chinese experience in the removal of actinides from highly active waste by trialkylphosphine-oxide extraction. Nucl. Technol. 1994, 108, 361-369.
    • (1994) Nucl. Technol. , vol.108 , pp. 361-369
    • Zhu, Y.1    Jiao, R.2
  • 9
    • 0035087621 scopus 로고    scopus 로고
    • The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3- n-dodecane system
    • Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori S. The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3- n-dodecane system. Solv. Extr. Ion Exch. 2001, 19(1), 91-103.
    • (2001) Solv. Extr. Ion Exch. , vol.19 , Issue.1 , pp. 91-103
    • Sasaki, Y.1    Sugo, Y.2    Suzuki, S.3    Tachimori, S.4
  • 10
    • 33847688865 scopus 로고    scopus 로고
    • An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA system
    • Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA system. Solv. Extr. Ion Exch. 2007, 25(2), 187-204.
    • (2007) Solv. Extr. Ion Exch. , vol.25 , Issue.2 , pp. 187-204
    • Sasaki, Y.1    Rapold, P.2    Arisaka, M.3    Hirata, M.4    Kimura, T.5    Hill, C.6    Cote, G.7
  • 12
    • 1542477471 scopus 로고
    • Terbium(III) and europium(III) ions as luminescent probes and stains for biomolecular systems
    • Richardson, F. S. Terbium(III) and europium(III) ions as luminescent probes and stains for biomolecular systems. Chem. Rev. 1982, 82, 541-552.
    • (1982) Chem. Rev. , vol.82 , pp. 541-552
    • Richardson, F.S.1
  • 15
    • 18544394716 scopus 로고
    • Luminescence study on determination of the hydration number of Cm(III)
    • Kimura, T.; Choppin, G. R. Luminescence study on determination of the hydration number of Cm(III). J. Alloys Comp. 1994, 213-214, 313-317.
    • (1994) J. Alloys Comp. , vol.213-214 , pp. 313-317
    • Kimura, T.1    Choppin, G.R.2
  • 16
    • 0032092582 scopus 로고    scopus 로고
    • Luminescence study on determination of the innersphere hydration number of Am(III) and Nd(III)
    • Kimura, T.; Kato, Y. Luminescence study on determination of the innersphere hydration number of Am(III) and Nd(III). J. Alloys Comp. 1998, 271-273, 867-871.
    • (1998) J. Alloys Comp. , vol.271-273 , pp. 867-871
    • Kimura, T.1    Kato, Y.2
  • 17
    • 0032118672 scopus 로고    scopus 로고
    • Luminescence study on hydration states of lanthanide(III)- polyaminopolycarboxylate complexes in aqueous solution
    • Kimura, T.; Kato, Y. Luminescence study on hydration states of lanthanide(III)- polyaminopolycarboxylate complexes in aqueous solution. J. Alloys Comp. 1998, 275-277, 806-810.
    • (1998) J. Alloys Comp. , vol.275-277 , pp. 806-810
    • Kimura, T.1    Kato, Y.2
  • 18
    • 0032089888 scopus 로고    scopus 로고
    • Comparative study on the hydration states of Cm(III) and Eu(III) in solution and in cation exchange resin
    • Kimura, T.; Kato, Y.; Takeishi, H.; Choppin, G. R. Comparative study on the hydration states of Cm(III) and Eu(III) in solution and in cation exchange resin. J. Alloys Comp. 1998, 271-273, 719-722.
    • (1998) J. Alloys Comp. , vol.271-273 , pp. 719-722
    • Kimura, T.1    Kato, Y.2    Takeishi, H.3    Choppin, G.R.4
  • 19
    • 1542633877 scopus 로고    scopus 로고
    • Characterization of Eu(III) species sorbed on silica and montmorillonite by laser-induced fluorescence spectroscopy
    • Takahashi, Y.; Kimura, T.; Kato, Y.; Minai, Y.; Tominaga, T. Characterization of Eu(III) species sorbed on silica and montmorillonite by laser-induced fluorescence spectroscopy. Radiochim. Acta 1998, 82, 227-232.
    • (1998) Radiochim. Acta , vol.82 , pp. 227-232
    • Takahashi, Y.1    Kimura, T.2    Kato, Y.3    Minai, Y.4    Tominaga, T.5
  • 20
    • 0034819341 scopus 로고    scopus 로고
    • Sorption behavior and coordination state of Eu(III) and Cm(III) in hydrochloric acid-methanol mixture/cation exchange resin system studied by timeresolved laser-induced fluorescence spectroscopy
    • Arisaka, M.; Kimura, T.; Suganuma, H.; Yoshida, Z. Sorption behavior and coordination state of Eu(III) and Cm(III) in hydrochloric acid-methanol mixture/cation exchange resin system studied by timeresolved laser-induced fluorescence spectroscopy. Radiochim. Acta 2001, 89, 593-598.
    • (2001) Radiochim. Acta , vol.89 , pp. 593-598
    • Arisaka, M.1    Kimura, T.2    Suganuma, H.3    Yoshida, Z.4
  • 21
    • 0036424992 scopus 로고    scopus 로고
    • Direct evidence for enhanced inner-sphere chloro complexation of Eu(III) and Cm(III) in anion exchange resin phase studied by time-resolved laser-induced fluorescence spectroscopy
    • Arisaka, M.; Kimura, T.; Suganuma, H.; Yoshida, Z. Direct evidence for enhanced inner-sphere chloro complexation of Eu(III) and Cm(III) in anion exchange resin phase studied by time-resolved laser-induced fluorescence spectroscopy. Radiochim. Acta 2002, 90, 193-197.
    • (2002) Radiochim. Acta , vol.90 , pp. 193-197
    • Arisaka, M.1    Kimura, T.2    Suganuma, H.3    Yoshida, Z.4
  • 23
    • 23944462445 scopus 로고    scopus 로고
    • N,N,N',N'-tetraoctyl diglycolamide (TODGA): A promising extractant for actinide-partitioning from high-level waste (HLW)
    • Ansari, S.A.; Pathak, P.N.; Manchanda, V.K.; Husain, M.; Prasad, A.K.; Parmar, V.S. N,N,N',N'-tetraoctyl diglycolamide (TODGA): a promising extractant for actinide-partitioning from high-level waste (HLW). Solv. Extr. Ion Exch. 2005, 23(4), 463-479.
    • (2005) Solv. Extr. Ion Exch. , vol.23 , Issue.4 , pp. 463-479
    • Ansari, S.A.1    Pathak, P.N.2    Manchanda, V.K.3    Husain, M.4    Prasad, A.K.5    Parmar, V.S.6
  • 24
    • 33745432843 scopus 로고    scopus 로고
    • Extraction of actinides using N,N,N',N'-tetraoctyl diglycolamide (TODGA): A thermodynamic study
    • Ansari, S.A.; Pathak, P.N.; Husain, M.; Prasad, A.K.; Parmar, V.S.; Manchanda, V.K. Extraction of actinides using N,N,N',N'-tetraoctyl diglycolamide (TODGA): A thermodynamic study. Radiochim. Acta 2006, 94, 307-312.
    • (2006) Radiochim. Acta , vol.94 , pp. 307-312
    • Ansari, S.A.1    Pathak, P.N.2    Husain, M.3    Prasad, A.K.4    Parmar, V.S.5    Manchanda, V.K.6
  • 25
    • 0032215907 scopus 로고    scopus 로고
    • Thermodynamics of extraction of Am(III) and Eu(III) from nitrate and thiocyanate media with octyl(phenyl)-N, N-diisobutylcarbamoylmethylphosphine oxide
    • Mathur, J.M.; Nash, K.L. Thermodynamics of extraction of Am(III) and Eu(III) from nitrate and thiocyanate media with octyl(phenyl)-N, N-diisobutylcarbamoylmethylphosphine oxide. Solv. Extr. Ion Exch. 1998, 16 (6), 1341-1356.
    • (1998) Solv. Extr. Ion Exch. , vol.16 , Issue.6 , pp. 1341-1356
    • Mathur, J.M.1    Nash, K.L.2
  • 26
    • 0000858669 scopus 로고
    • The extraction of selected transplutonium(III) and lanthanide(III) ions by dihexyl-N, N-diethylcarbamoylmethyl phosphonate from aqueous nitrate madia
    • Horwitz, E.P.; Muscatello, A.C.; Kalina, D.G.; Kaplan, L. The extraction of selected transplutonium(III) and lanthanide(III) ions by dihexyl-N, N-diethylcarbamoylmethyl phosphonate from aqueous nitrate madia. Sep. Sci. Technol. 1981, 16, 417-437.
    • (1981) Sep. Sci. Technol. , vol.16 , pp. 417-437
    • Horwitz, E.P.1    Muscatello, A.C.2    Kalina, D.G.3    Kaplan, L.4


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