Site-selective Suzuki-Miyaura reactions of the bis(triflate) of 1,3-dihydroxyanthraquinone

Tetrahedron Letters

Volumn 52, Issue 10, 2011, Pages 1093-1095

  Akrawi, Omer A ^a   Hussain, Munawar ^a   Langer, Peter ^a,b  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

Author keywords

Anthraquinones; Catalysis; Palladium; Regioselectivity; Suzuki Miyaura reaction

Indexed keywords

1 (3 CHLOROPHENYL) 3 (4 TOLYL)ANTHRACENE 9,10 DIONE; 1,3 BIS(4 ETHYLPHENYL)ANTHRACENE 9,10 DIONE; 1,3 DIHYDROXYANTHRAQUINONE; 4 (3 CHLOROPHENYL) 9,10 DIOXO 9,10 DIHYDROANTHRACEN 2 YLTRIFLUOROMETHANESULFONATE; ANTHRAQUINONE DERIVATIVE; CARBONYL DERIVATIVE; PALLADIUM; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; CATALYSIS; CYCLOADDITION; DRUG STRUCTURE; DRUG SYNTHESIS; ONE POT SYNTHESIS; PROTON NUCLEAR MAGNETIC RESONANCE; SUZUKI REACTION;

EID: 79551684234     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.12.098     Document Type: Article

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30. +: 240.04226; found: 240.042311.
31. +: 503.94083; found: 503.94066.
32. 4), filtered, and concentrated in vacuo. The residue was purified by column chromatography (EtOAc/heptanes).
33. +: 415.16926; found: 415.168812.
34. 2 (20 mL) was added, the solution was filtered, and the filtrate was concentrated in vacuo. The residue was purified by column chromatography (EtOAc/heptanes).
35. +: 465.98841; found: 465.987174.
36. 4), filtered, and then concentrated in vacuo. The residue was purified by column chromatography (EtOAc/heptanes).
37. +: 407.08333; found: 407.082634.
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