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See the Supporting Information for details of the X-ray structure analyses.
-
See the Supporting Information for details of the X-ray structure analyses.
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55
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79551679352
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The outer diameters were calculated from the H-H distances of the methyl H atoms plus two times the van der Waals radius of the H atom (0.12 nm). The inner diameters were analogously calculated as P-P distances minus two times the van der Waals radius of the P atom (0.18 nm).
-
The outer diameters were calculated from the H-H distances of the methyl H atoms plus two times the van der Waals radius of the H atom (0.12 nm). The inner diameters were analogously calculated as P-P distances minus two times the van der Waals radius of the P atom (0.18 nm).
-
-
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56
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79551669973
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5] complexes show a disorder over two positions, both of which exhibit π stacking.
-
5] complexes show a disorder over two positions, both of which exhibit π stacking.
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57
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79551656218
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The calculated MAS NMR spectrum of 4 is consistent with the observed signal range. However, the simultaneous presence of 3 in the MAS sample cannot be definitely excluded from experimental data because of the broadness of the signals and the similar chemical shifts.
-
The calculated MAS NMR spectrum of 4 is consistent with the observed signal range. However, the simultaneous presence of 3 in the MAS sample cannot be definitely excluded from experimental data because of the broadness of the signals and the similar chemical shifts.
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50149091940
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84977293067
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The drawings were generated with the SCHAKAL 99 software by E. Keller, Albert-Ludwigs-Universität Freiburg, Germany.
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