Hydrogel assisted nickel nanoparticle synthesis and their use in hydrogen production from sodium boron hydride

International Journal of Hydrogen Energy

Volumn 36, Issue 3, 2011, Pages 1998-2006

  Ozay, Ozgur ^a   Aktas, Nahit ^b   Inger, Erk ^c   Sahiner, Nurettin ^a,d  

^a ÇANAKKALE ONSEKIZ MART UNIVERSITY   (Turkey)

^b YUZUNCU YIL UNIVERSITY   (Turkey)

^c GAZI UNIVERSITY   (Turkey)

^d Nanomaterial and Nanotechnology Laboratory   (Turkey)

Author keywords

Catalysis; Hydrogel nanoreactor; Hydrogen; NaBH4 Hydrolysis; Nanocluster; Ni nanoparticles

Indexed keywords

ACTIVATION ENTHALPIES; BASIC MEDIUM; BORON HYDRIDES; HYDROGEL NETWORKS; HYDROLYSIS REACTION; IN-SITU; INITIAL CONCENTRATION; NABH4 HYDROLYSIS; NI METAL; NI NANOPARTICLES; NICKEL NANOPARTICLES;

ACTIVATION ENERGY; BORON; BORON COMPOUNDS; CATALYSIS; CATALYSTS; HYDROGEN PRODUCTION; HYDROLYSIS; NANOCLUSTERS; NANOPARTICLES; NANOREACTORS; SODIUM; SYNTHESIS (CHEMICAL);

HYDROGELS;

EID: 79551618335     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.11.045     Document Type: Article

References (32)

1. M. Zahmakiran, and S. Özkar Zeolite-Confined ruthenium(0) nanoclusters catalyst: record catalytic activity, reusability, and lifetime in hydrogen generation from the hydrolysis of sodium borohydride Langmuir 25 2009 2667 2678
2. C.H. Liu, B.H. Chen, C.H. Hsueh, J.R. Ku, M.S. Jeng, and F. Tsau Hydrogen generation from hydrolysis of sodium borohydride using Ni-Ru nanocompozite as catalysts Int J Hydrogen Energy 34 2009 2153 2163
3. M. Zahmakran, and S. Özkar Water dispersible acetate stabilized ruthenium(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohyride J Mol Catal A Chem 258 2006 95 103
4. M. Rakap, and S. Özkar Intrazeolite cobalt (0) nanoclusters as low-cost and reusable catalyst for hydrogen generation from the hydrolysis of sodium borohydride Appl Catal B 91 2009 21 29
5. U.B. Demirci, and F. Garin Kinetics of Ru-promoted sulphated zirconia catalysed hydrogen generation by hydrolysis of sodium tetrahydroborate J Mol Catal A Chem 279 2008 57 62
6. K.W. Cho, and H.S. Kwon Effects of electrodeposited Co and Co-P catalysts on the hydrogen generation properties from hydrolysis of alkaline sodium borohydride solution Catal Today 120 2007 298 304
7. Ö Metin, and S. Özkar Hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride using water-soluble polymer-stabilized cobalt(0) nanoclusters catalyst Energy Fuel 23 2009 3517 3526
8. M. Zahmakran, and S. Özkar Zeolite framework stabilized rhodium(0) nanoclusters catalyst for the hydrolysis of ammonia-borane in air: outstanding catalytic activity, reusability and lifetime Appl Catal B 89 2009 104 110
9. W. Ye, H. Zhang, D. Xu, L. Ma, and B. Yi Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst J Power Sources 164 2007 544 548
10. 4 solution Int J Hydrogen Energy 34 2009 2164 2173
11. U.B. Demirci, O. Akdim, and P. Miele Aluminum chloride for accelerating hydrogen generation from sodium borohydride J Power Sources 192 2009 310 315
12. J.C. Ingersoll, N. Mani, J.C. Thenmozhiyal, and A. Muthaiah Catalytic hydrolysis of sodium borohydride by a novel nickel-cobalt-boride catalyst J Power Sources 173 2007 450 457
13. Özkar S. Metin Ö Hydrogen generation from the hydrolysis of sodium borohydride by using water dispersible, hydrogenphosphate-stabilized nickel (0) nanoclusters as catalyst Int J Hydrogen Energy 32 2007 1707 1715
14. H.B. Dai, Y. Liang, P. Wang, and H.M. Cheng Amorphous cobalt-boron/nickel foam as an effective catalyst for hydrogen generation from alkaline sodium borohydride solution J Power Sources 177 2008 17 23
15. D. Xu, P. Dai, X. Liu, C. Cao, and Q. Guo Carbon-supported cobalt catalyst for hydrogen generation from alkaline sodium borohydride solution J Power Sources 182 2008 616 620
16. 4 solution Catal Today 120 2007 305 310
17. 4 solution using carbon-supported Co-B as catalyst Int J Hydrogen Energy 32 2007 4711 4716
18. K.S. Eom, K.W. Cho, and H.S. Kwon Effects of electroless deposition conditions on microstructures of cobalt-phosphorous catalysts and their hydrogen generation properties in alkaline sodium borohydride solution J Power Sources 180 2008 484 490
19. 4 solution Int J Hydrogen Energy 34 2009 2622 2630
20. O. Akdim, U.B. Demirci, A. Brioude, and P. Miele Fluorinated cobalt for catalyzing hydrogen generation from sodium borohydride Int J Hydrogen Energy 34 2009 5417 5421
21. O. Akdim, U.B. Demirci, and P. Miele More reactive cobalt chloride in the hydrolysis of sodium borohydride Int J Hydrogen Energy 34 2009 9444 9449
22. U.B. Demirci, and F. Garin Promoted sulphated-zirconia catalysed hydrolysis of sodium tetrahydroborate Catal Commun 9 2008 1167 1172
23. M. Zahmakiran, and S. Özkar Intrazeolite ruthenium(0) nanoclusters: a superb catalyst for the hydrogenation of benzene and the hydrolysis of sodium borohydride Langmuir 24 2008 7065 7067
24. S. Ozkar, and M. Zahmakran Hydrogen generation from hydrolysis of sodium borohydride using Ru(0) nanoclusters as catalyst J Alloy Compd 404-406 2005 728 731
25. U.B. Demirci, and F. Garin Ru-based bimetallic alloys for hydrogen generation by hydrolysis of sodium tetrahydroborate J Alloy Compd 463 2008 107 111
26. Y. Liang, H.-B. Dai, L.-P. Ma, P. Wang, and H.-M. Cheng Hydrogen generation from sodium borohydride solution using a ruthenium support on graphite catalyst Int J Hydrogen Energy 35 2010 3023 3028
27. N. Sahiner In situ metal particle preparation in cross-linked poly (2-acrylamido-2 methyl 1-propansulfonic acid) hydrogel networks Colloid Polym Sci 285 2006 283 292
28. K. Zhang, Y. Luo, and Z. Li Synthesis and characterization of a pH-and ionic strength -responsive hydrogel Soft Matter 5 4 2007 183 195
29. N. Sahiner, and M. Singh In situ micro/nano-hydrogel synthesis from acrylamide derivates with lecithin organogel system Polymer 48 2007 2827 2834
30. N. Sahiner, H. Ozay, O. Ozay, and N. Aktas New catalytic route: hydrogels as templates and reactors for in situ Ni nanoparticle synthesis and usage in the reduction of 2- and 4-nitrophenols' Appl Catal A Gen 385 2010 201 207
31. O. Metin, and S. Ozkar Synthesis and characterization of poly(N-vinyl-2-pyrrolidone)-stabilized water-soluble nickel(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohydride J Mol Catal A Chem 295 2008 39 46
32. D. Hua, Y. Hanxi, A. Xinping, and C. Chuansin Hydrogen production from catalytic hydrolysis of sodium borohydride using nickel boride catalyst Int J Hydrogen Energy 28 2003 1095 1100