CuCl electrolysis for hydrogen production in the Cu-Cl thermochemical cycle

Journal of the Electrochemical Society

Volumn 158, Issue 3, 2011, Pages

  Balashov, Victor N ^a   Schatz, Rich S ^a   Chalkova, Elena ^a   Akinfiev, Nikolay N ^a,b   Fedkin, Mark V ^a   Lvov, Serguei N ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b INSTITUTE OF GEOLOGY OF ORE DEPOSITS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT TEMPERATURES; AQUEOUS SOLUTIONS; CURRENT EFFICIENCY; ELECTROLYZERS; FARADAY'S LAWS; GAS EVOLUTION; HIGH EFFICIENCY; HYDROGEN EVOLUTION REACTIONS; HYDROGEN PRODUCTION RATE; LINEAR SWEEP VOLTAMMETRY; MODERATE TEMPERATURE; PURE WATER; REAGENT CONCENTRATION; THERMOCHEMICAL CYCLES; THERMODYNAMIC MODEL; VOLTAGE EFFICIENCIES; WATER ELECTROLYSIS;

COPPER COMPOUNDS; ELECTROCHEMICAL CORROSION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTROLYSIS; ELECTROLYTIC CELLS; HYDROCHLORIC ACID; OXYGEN; TEMPERATURE;

HYDROGEN PRODUCTION;

EID: 79551602939     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.3521253     Document Type: Article

References (40)

1. B. C. R. Ewan and R. W. K. Allen, Int. J. Hydrogen Energy, 30, 809 (2005). 10.1016/j.ijhydene.2005.02.003
2. R. Elder and R. Allen, Prog. Nucl. Energy, 51, 500 (2009). 10.1016/j.pnucene.2008.11.001
3. M. A. Lewis, J. G. Masin, and P. A. O'Hare, Int. J. Hydrogen Energy, 34, 4115 (2009). 10.1016/j.ijhydene.2008.06.045
4. V. D. Dang and M. Steinberg, Energy Convers. Manage., 20, 85 (1980). 10.1016/0196-8904(80)90013-8 (Pubitemid 11472357)
5. R. H. Carty, M. M. Mazumder, J. D. Schreider, and J. B. Pangborn, Thermochemical Hydrogen Production, Vols. 1-4, Gas Research Institute for the Institute of Gas Technology, Chicago, IL (1981).
6. B. W. McQuillan, L. C. Brown, G. E. Besenbruch, R. Tolman, T. Cramer, and B. E. Russ, Annual Report GA-A24972, San Diego, CA (2005).
7. M. C. Petri, B. Yildiz, and A. E. Klickman, Int. J. Nucl. Hydrogen Production Appl., 1, 79 (2006). 10.1504/IJNHPA.2006.009871
8. M. A. Lewis and J. G. Masin, Int. J. Hydrogen Energy, 34, 4125 (2009). 10.1016/j.ijhydene.2008.07.085
9. M. Dokya and Y. Kotera, Int. J. Hydrogen Energy, 1, 117 (1976). 10.1016/0360-3199(76)90064-1
10. M. F. Orhan, I. Dincer, and M. A. Rosen, Chem. Eng. Sci., 64, 860 (2009). 10.1016/j.ces.2008.10.047
11. G. F. Naterer, V. N. Daggupati, G. Marin, K. S. Gabriel, and Z. L. Wang, Int. J. Hydrogen Energy, 33, 5451 (2008). 10.1016/j.ijhydene.2008.06.005
12. G. F. Naterer, K. Gabriel, Z. L. Wang, V. N. Daggupati, and R. Gravelsins, Int. J. Hydrogen Energy, 33, 5439 (2008). 10.1016/j.ijhydene.2008. 05.035
13. G. Naterer, S. Suppiah, M. Lewis, K. Gabriel, I. Dincer, M. A. Rosen, M. Fowler, G. Rizvi, E. B. Easton, B. M. Ikeda, Int. J. Hydrogen Energy, 34, 2901 (2009). 10.1016/j.ijhydene.2009.01.090
14. R. Sharna, N. N. Akinfiev, S. Hipple, M. V. Fedkin, and S. N. Lvov, J. Electrochem. Soc., To be submitted.
15. H. Fricke, Philos. Mag., 14, 310 (1932).
16. J. R. Macdonald and W. B. Johnson, in Impedance Spectroscopy, E. Barsoukov, and, J. R. Macdonald, Editors, p. 1, Wiley Interscience, John Wiley & Sons, Hoboken, NJ (2005).
17. V. N. Balashov, M. V. Fedkin, and S. N. Lvov, J. Electrochem. Soc., 156, C209 (2009). 10.1149/1.3121205
18. D. R. Franceschetti and J. R. Macdonald, in Impedance Spectroscopy, E. Barsoukov, and, J. R. Macdonald, Editors, p. 80, Wiley Interscience, John Wiley & Sons, Hoboken, NJ (2005).
19. Yu. V. Shvarov and E. N. Bastrakov, HCh: a software package for geochemical equilibrium modelling (user's guide). Australian Geological Survey Organization, Record 1999/25.
20. J. J. Fritz, J. Phys. Chem., 84, 2241 (1980). 10.1021/j100455a006
21. J. J. Fritz and E. K. Onigsberger, Solubility Data Series, Vol. 65: Copper(I) Halides and Pseudohalides, Oxford University Press, Oxford (1996).
22. L. Ciavatta and M. Iuliano, Ann. Chim. (Rome), 88, 71 (1998).
23. H. F. Holmes, R. H. Busey, J. M. Simonson, R. E. Mesmer, D. G. Archer, and R. H. Wood, J. Chem. Thermodyn., 19, 863 (1987). 10.1016/0021-9614(87)90033- 4
24. H. C. Helgeson, D. H. Kirkham, and G. C. Flowers, Am. J. Sci., 281, 1249 (1981). 10.2475/ajs.281.10.1249
25. H. C. Helgeson and D. H. Kirkham, Am. J. Sci., 276, 97 (1976). 10.2475/ajs.276.2.97
26. M. Setchenow, Ann. Chim. Phys., 25, 225 (1892).
27. V. A. Pokrovskii, Geochim. Cosmochim. Acta, 63, 1107 (1999). 10.1016/S0016-7037(98)00313-5 (Pubitemid 29485373)
28. J. J. Fritz, J. Chem. Eng. Data, 27, 188 (1982). 10.1021/je00028a027
29. Properties of Aqueous Solutions of Electrolytes, I. D. Zaytsev, Editor, CRC Press, Boca Raton, FL (1992).
30. W. Liu and D. C. McPail, Chem. Geol., 221, 21 (2005). 10.1016/j.chemgeo.2005.04.009 (Pubitemid 41150153)
31. E. L. Shock and H. C. Helgeson, Geochim. Cosmochim. Acta, 52, 2009 (1988). 10.1016/0016-7037(88)90181-0
32. N. N. Akinfiev and A. V. Zotov, Geochem. Intl., 39, 990 (2001).
33. J. W. Johnson, E. H. Oelkers, and H. C. Helgeson, Comput. Geosci., 18, 899 (1992). 10.1016/0098-3004(92)90029-Q (Pubitemid 23589871)
34. G. B. Naumov, B. N. Ryzhenko, and I. L. Khodakovsky, Handbook of Thermodynamic Data, Atomizdat, Moscow (1971).
35. NIST Webbook, http://webbook.nist.gov, last accessed: December 21, 2010.
36. D. M. Sherman, Geochim. Cosmochim. Acta, 71, 714 (2007). 10.1016/j.gca.2006.09.015 (Pubitemid 46112222)
37. Yu. V. Shvarov, " UT-HEL: A Program for the Calculation of HKF Parameters of Water Species (Version 2.0).," Geology Department, Moscow State University, Moscow (1995).
38. N. N. Akinfiev, Geochem. Intl., 32, 116 (1995).
39. G. Poma, Atti Accad. Naz. Lincei, Cl. Sci. Fis., Mat. Nat., Rend. 0001-4435, 18-1, 133 (1909) (cited in Copper (I) Halides and Pseudohalides. Solubility Data Series, James J.Fritz and Erich Königsberger, Editors, Oxford University Press, 1996; p. 121).
40. G. Edgar and L. S. Cannon, J. Am. Chem. Soc., 44, 2842 (1922). 10.1021/ja01433a018