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Volumn 14, Issue 2, 2011, Pages 426-428

Transformations of acetone in reactions with carboxylate complexes of palladium: Crystal structure of Pd4(μ-CF3CO 2)4(μ,k2-CH2C(O)CH 3)2(η3-CH2C(OH)CH 2)2•2CH3C(O)CH3

Author keywords

Acetonyl; Carboxylate; Hydroxoallyl; Palladium; Transformation of acetone

Indexed keywords


EID: 79551482057     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.12.018     Document Type: Article
Times cited : (8)

References (28)
  • 22
    • 79551497736 scopus 로고    scopus 로고
    • - 1.
    • - 1.
  • 23
    • 79551481404 scopus 로고    scopus 로고
    • note
    • - 1, 24165 reflections measured, 3480 unique (Rint = 0.0899) which were used in further calculations. The structure was solved by direct methods and refined by full matrix least-squares on F2 with anisotropic thermal parameters for all non-hydrogen atoms except fluorine atoms of disordered -CF3 groups. Both trifluoromethyl groups were found to be rotationally disordered over two and three positions with occupancies ratios 0.53/0.47 and 0.53/0.24/0.23, respectively. Hydroxyl atom H1 was found from difference Fourier synthesis; other hydrogen atoms were placed in calculated positions. All H atoms were refined using a riding model. The final residuals were: R1 = 0.0762, wR2 = 0.1956 for 2661 reflections with I > 2σ(I) and 0.0990, 0.2030 for all data and 251 parameters.
  • 28
    • 79551495088 scopus 로고    scopus 로고
    • note
    • - 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.