Synthesis and characterization of crosslinked sulfonated poly(arylene ether sulfone) membranes for high temperature PEMFC applications

International Journal of Hydrogen Energy

Volumn 36, Issue 2, 2011, Pages 1813-1819

  Park, Ki Tae ^a   Chun, Jeong Hwan ^a   Kim, Sang Gon ^a   Chun, Byung Hee ^a   Kim, Sung Hyun ^a  

^a Korea University   (South Korea)

Author keywords

Carboxyl group; High temperature; Low humidity; Polymer electrolyte membrane fuel cell; Sulfonated Poly(arylene ether sulfone)

Indexed keywords

CARBOXYL GROUPS; HIGH TEMPERATURE; LOW HUMIDITY; POLYMER ELECTROLYTE MEMBRANE FUEL CELL; SULFONATED POLY(ARYLENE ETHER SULFONE);

ATMOSPHERIC HUMIDITY; COPOLYMERIZATION; COPOLYMERS; DEIONIZED WATER; ETHERS; HIGH TEMPERATURE APPLICATIONS; ION EXCHANGE; ION EXCHANGE MEMBRANES; KETONES; ORGANIC COMPOUNDS; PHENOLS; POLYELECTROLYTES; POLYMERS; PROTON CONDUCTIVITY; SYNTHESIS (CHEMICAL); WATER CONTENT;

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

EID: 79551480270     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.02.019     Document Type: Conference Paper

References (34)

1. 2-Nafion composite membranes for polymer electrolyte fuel cells (PEFCs) at intermediate temperature. J Power Sources 163 2006 47
2. 2)/Nafion composite membranes for PEMFC operation at high temperature/low humidity J Membr Sci 280 2006 148
3. 2 (M = Zr, Si, Ti) nanocomposite membranes for higher temperature PEM fuel cells Electrochim Acta 51 2005 553
4. S. Ren, G. Sun, C. Li, S. Song, Q. Xin, and X. Yang Sulfated zirconia-Nafion composite membranes for higher temperature direct methanol fuel cells. J Power Sources 157 2006 724
5. R. Zeng, Y. Wang, S. Wang, and P.K. Shen Homogeneous synthesis of PFSI/silica composite membranes for PEMFC operating at low humidity Electrochim Acta 52 2007 3895
6. V. Ramani, H.R. Kunz, and J.M. Fenton Stabilized composite membranes and membrane electrode assemblies for elevated temperature/low relative humidity PEFC operation J Power Sources 152 2005 182
7. 2 particles to catalyst layer. J Power Sources 159 2006 529
8. ® composite membrane for polymer electrolyte membrane fuel cells operation at high temperature and low humidity J Power Sources 177 2008 247
9. ®112 for self-humidifying electrolyte membranes in fuel cells Electrochim Acta 51 2006 3979
10. Y.F. Zhang, S.J. Wang, M. Xiao, S.G. Bian, and Y.Z. Meng The silica-doped sulfonated poly(fluorenyl ether ketone)s membrane using hydroxypropyl methyl cellulose as dispersant for high temperature proton exchange membrane fuel cells Int J Hydrogen Energy 34 2009 4379
11. 4) composite membranes for high-temperature proton-exchange membrane fuel cells Int J Hydrogen Energy 34 2009 8982
12. Guo-Bin Jung, Fang-Bor Weng, Ay Su, Jiun-Sheng Wang, T. Leon Yu, and Hsiu-Li Lin Nafion/PTFE/silicate membranes for high-temperature proton exchange membrane fuel cells Int J Hydrogen Energy 33 2008 2413
13. Q.F. Li, R.H. He, J.O. Jensen, and N.J. Bjerrum Approaches and recent development of polymer electrolyte membranes for fuel cells operating above 100 °C Chem Mater 15 2003 4896
14. M.A. Hickner, H. Ghassemi, Y.S. Kim, B.R. Einsla, and J.E. McGrath Alternative polymer systems for proton exchange membranes (PEMs) Chem Rev 104 2004 4587
15. H.S. Lee, A. Roy, O. Lane, S. Dunn, and J.E. McGrath Hydrophilic- hydrophobic multiblock copolymers based on poly(arylene ether sulfone) via low-temperature coupling reactions for proton exchange membrane fuel cells Polymer 49 2008 715
16. J.K. Lee, W. Li, and A. Manthiram Poly(arylene ether sulfone)s containing pendant sulfonic acid groups as membrane materials for direct methanol fuel cells J Membr Sci 330 2009 73
17. A.S. Badami, O. Lane, H.S. Lee, A. Roy, and J.E. McGrath Fundamental investigations of the effect of the linkage group on the behavior of hydrophilic-hydrophobic poly(arylene ether sulfone) multiblock copolymers for proton exchange membrane fuel cells J Membr Sci 333 2009 1
18. A. Roy, H.S. Lee, and J.E. McGrath Hydrophilic-hydrophobic multiblock copolymers based on poly(arylene ether sulfone)s as novel proton exchange membranes - Part B Polymer 49 2008 5037
19. Y.S. Oh, H.J. Lee, M. Yoo, H.J. Kim, J. Han, and T.H. Kim synthesis of novel crosslinked sulfonated poly(arylene ether sulfone)s using bisazide and their properties for fuel cell application J Membr Sci 323 2008 309
20. W.L. Harrison, F. Wang, J.B. Mecham, V.A. Bhanu, M. Hill, and Y.S. Kim Influence of the bisphenol structure on the direct synthesis of sulfonated poly(arylene ether) copolymers. I J Polym Sci A Polym Chem 41 2003 2264
21. S.J. Im, R. Patel, S.J. Shin, J.H. Kim, and B.R. Min Korean. Sulfonated poly(arylene ether sulfone) membranes based on biphenol for direct methanol fuel cells. J Chem Eng 25 4 2008 732
22. Y.T. Goh, R. Patel, S.J. Im, J.H. Kim, and B.R. Min Korean. Synthesis and characterization of poly(ether sulfone) grafted poly(styrene sulfonic acid) for proton conducting membranes. J Chem Eng 26 2 2009 518
23. Yilser Devrim, Serdar Erkan, Nurcan Ba, and Inci Erolu Preparation and characterization of sulfonated polysulfone/titanium dioxide composite membranes for proton exchange membrane fuel cells Int J Hydrogen Energy 34 2009 3467
24. Erce engül, Hülya Erdener, R. Gültekin Akay, Hayrettin Yücel, Nurcan Ba, and nc Erolu Effects of sulfonated polyether-etherketone (SPEEK) and composite membranes on the proton exchange membrane fuel cell (PEMFC) performance Int J Hydrogen Energy 34 2009 4645
25. M.E. Rogers, and T.E. Long Synthetic methods in step-growth polymers S. Wang, J.E. McGrath, Synthesis of poly(arylene ether)s 2003 John Wiley & Sons, Inc. New York 327
26. J.B. Rose Preparation and properties of poly(arylene ether sulphones)* Polymer 15 1974 456
27. D.S. Kim, K.H. Shin, H.B. Park, Y.S. Chung, S.Y. Nam, and Y.M. Lee Synthesis and characterization of sulfonated poly(arylene ether sulfone) copolymers containing carboxyl groups for direct methanol fuel cells J Membr Sci 278 2006 428
28. Y.S. Kim, M.A. Hickner, L. Dong, B.S. Pivovar, and J.E. McGrath Sulfonated poly(arylene ether sulfone) copolymer proton exchange membranes: composition and morphology effects on the methanol permeability J Membr Sci 243 2004 317
29. K.D. Kreuer On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells J Membr Sci 185 2001 29
30. K.B. Heo, H.J. Lee, H.J. Kim, B.S. Kim, S.Y. Lee, and E. Cho Synthesis and characterization of cross-linked poly(ether sulfone) for a fuel cell membrane J Power Sources 172 2007 215
31. S. Feng, Y. Shang, X. Xie, Y. Wang, and J. Xu Synthesis and characterization of crosslinked sulfonated poly(arylene ether sulfone) membranes for DMFC applications J Membr Sci 335 2009 13
32. W. Li, X. Xu, S. Chen, X. Zhou, L. Li, and D. Chen Esterification crosslinking structures of rayon fibers with 1,2,3,4-butanetetracarboxylic acid and their water-responsive properties Carbohydr Polym 71 2008 574
33. Y. Gao, G.P. Robertson, M.D. Guiver, and X. Jian Synthesis and characterization of sulfonated poly(phthalazinone ether ketone) for proton exchange membrane materials J Polym Sci A Polym Chem 41 2003 497
34. T.A. Zawodzinski, T.E. Springer, J. Davey, R. Jestel, C. Lopez, and J. Valerio A comparative study of water uptake by and transport through ionomeric fuel cell membranes J Electrochem Soc 140 1993 1981