The production of separate streams of pure hydrogen and carbon dioxide from coal via an iron-oxide redox cycle

Chemical Engineering Journal

Volumn 166, Issue 3, 2011, Pages 1052-1060

  Muller C R ^a   Bohn, C D ^b   Song, Q ^b   Scott, S A ^b   Dennis, J S ^b  

^a ETH ZURICH   (Switzerland)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

Chemical looping combustion; Coal; Gasification; Hydrogen; Iron oxide; Sulphur dioxide

Indexed keywords

CHEMICAL LOOPING COMBUSTION; CHEMICAL-LOOPING PROCESS; CYCLIC STABILITY; LOW RANK COALS; MECHANICAL MIXING; OPERATING CYCLE; REDOX CYCLES; SOLID FUELS; SUBBITUMINOUS COAL; SULPHUR DIOXIDE; SYN-GAS;

BITUMINOUS COAL; CARBON DIOXIDE; COAL COMBUSTION; COAL INDUSTRY; FUELS; GASIFICATION; GLOBAL WARMING; GREENHOUSE GASES; HYDROGEN; OXIDATION; REDOX REACTIONS; SULFUR; SULFUR DETERMINATION; SULFUR DIOXIDE; SYNTHESIS GAS;

IRON OXIDES;

EID: 79451476311     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2010.11.067     Document Type: Article

References (24)

1. Intergovermental Panel on Climate Change, Climate Change 2007: Synthesis Report, Cambridge University Press, Cambridge, 2007.
2. Ishida M., Zheng D., Akehata T. Evaluation of a chemical-looping-combustion power-generating system by graphic exergy analysis. Energy 1987, 12:147-154.
3. 2. Fuel 2001, 80:1953-1962.
4. 2 separation using chemical looping with a Cu-based oxygen carrier. Fuel 2010.
5. J.S. Dennis, C.R. Müller, S.A. Scott, In situ gasification and CO2 separation using chemical looping with a Cu-based oxygen carrier: performance with bituminous coal, Fuel, 2010, doi:10.1016/j.fuel.2010.01.037.
6. A. Messerschmidt, Process of Producing Hydrogen, U.S. Patent 971,206, 1910.
7. H. Lane, Process for the Production of Hydrogen, U.S. Patent 1,078,686, 1913.
8. Gupta P., Velazquez-Vargas L.G., Fan L.S. Syngas redox (SGR) process to produce hydrogen from coal derived syngas. Energy and Fuels 2007, 21:2900-2908.
9. Bohn C.D., Müller C.R., Cleeton J.P.E., Hayhurst A.N., Davidson J.F., Scott S.A., Dennis J.S. Production of very pure hydrogen with simultaneous capture of carbon dioxide using the redox reactions of iron oxides in packed beds. Industrial and Engineering Chemistry Research 2008, 47:7623-7630.
10. Bohn C.D., Cleeton J.P.E., Müller C.R., Davidson J.F., Hayhurst A.N., Scott S.A., Dennis J.S. The kinetics of the reduction of iron oxide by carbon monoxide mixed with carbon dioxide. AIChE Journal 2010, 56:1016-1029.
11. Barin I., Knacke O.O. Thermodynamical Properties of Inorganic Substances 1973, Springer-Verlag, Berlin.
12. Focht G.D., Ranade P.V., Harrison D.P. High temperature desulfurization using zinc ferrite: reduction and sulfidation kinetics. Chemical Engineering Science 1988, 43:3005-3013.
13. Lew S., Jothimurugesan K., Flytzani-Stephanopoulos M. High temperature hydrogen sulfide removal from fuel gas by regenerable zinc oxide-titanium dioxide sorbents. Industrial and Engineering Chemistry Research 1989, 28:535-541.
14. 2S and zinc oxide-titanium oxide sorbents: single pellet kinetic studies. Industrial and Engineering Chemistry Research 1990, 30:1160-1167.
15. White J.D., Groves F.R., Harrison D.P. Elemental sufur production during the regeneration of iron oxide high-temperature desulfurization sorbent. Catalysis Today 1998, 40:47-57.
16. T. Grindley, G. Steinfeld, G., Development and Testing of Regenerable Hot-Coal-Gas Desulfurization Sorbents, DOE/MC/16545-1125, 1981.
17. Sa L.A., Focht G.D., Ranade P.V., Harrison D.P.D.P. High-temperature desulfurization using zinc ferrite: solid structural property changes. Chemical Engineering Science 1989, 44:215-224.
18. 2S adsorbents at high temperatures. Industrial and Engineering Chemistry Process Design and Development 1985, 24:1165-1168.
19. Tamhankar S.S., Hasatani M., Wen C.Y. Kinetic studies on the reactions involved in the hot gas desulfurization using a regenerable iron oxide sorbent - I. Chemical Engineering Science 1981, 36:1181-1191.
20. Tseng S.C., Tamhankar S.S., Wen C.Y. Kinetic studies on the reactions involved in the hot gas desulfurization using a regenerable iron oxide sorbent - II. Chemical Engineering Science 1981, 36:1287-1294.
21. Mattisson T., Johansson M., Lyngfeld A. The use of NiO as an oxygen carrier in chemical-looping combustion. Fuel 2006, 85:736-747.
22. Jerndal E., Mattisson T., Lyngfeld A. Thermal analysis of chemical looping combustion. Chemical Engineering Research and Design 2006, 84:795-806.
23. A.M. Kierzkowska, C.D. Bohn, S.A. Scott, J.P.E. Cleeton, J.S. Dennis, C.R. Müller, Development of iron oxide carriers for chemical looping combustion using sol-gel, Industrial and Engineering Chemistry Research, 2010, doi:10.1021/ie.100046f.
24. Abad A., Mattisson T., Lyngfelt A., Johansson M. The use of iron oxide as oxygen carrier in a chemical looping reactor. Fuel 2007, 86:1021-1035.