Effect of higher alcohols on the performances of a 1%Rh/MgAl 2O4/Al2O3 catalyst for hydrogen production by crude bioethanol steam reforming

International Journal of Hydrogen Energy

Volumn 36, Issue 1, 2011, Pages 311-318

  Le Valant, Anthony ^a   Garron, Anthony ^a   Bion, Nicolas ^a   Duprez, Daniel ^a   Epron, Florence ^a  

^a UNIVERSITÉ DE POITIERS   (France)

Author keywords

Bioethanol; Crude bioethanol; Ethanol steam reforming; Hydrogen production; Rhodium catalyst

Indexed keywords

BUTAN-1-OL; CARBON ATOMS; CATALYTIC PERFORMANCE; COKE DEPOSITION; CRUDE BIOETHANOL; DIRECT IMPACT; ETHANOL CONVERSION; ETHANOL STEAM REFORMING; HIGHER ALCOHOLS; HYDROGEN YIELDS; ISO-PROPANOLS; PROPAN-1-OL; RHODIUM CATALYST;

BIOETHANOL; CATALYST DEACTIVATION; ETHANOL; HYDROGEN PRODUCTION; METHANOL; OLEFINS; RHODIUM; STEAM; STEAM ENGINEERING;

STEAM REFORMING;

EID: 79251608335     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.09.039     Document Type: Article

References (47)

1. H. Muroyama, R. Nakase, T. Matsui, and K. Eguchi Ethanol steam reforming over Ni-based spinel oxide Int J Hydrogen Energy 32 2007 3238 3247
2. W. Cai, F. Wang, A. van Veen, C. Descorme, Y. Schuurman, and W. Shen Int J Hydrogen Energy 35 2010 1152 1159
3. M. Ni, D.Y.C. Leung, and M.K.H. Leung Int J Hydrogen Energy 32 2007 3238 3247
4. S. Freni, G. Maggio, and S. Cavallaro Ethanol steam reforming in a molten carbonate fuel cell: a thermodynamic approach J Power Sources 62 1996 67 73
5. T. Ioannides Thermodynamic analysis of ethanol processors for fuel cell applications J Power Sources 92 2001 17 25
6. M. Benito, J.L. Sanz, R. Isabel, R. Padilla, R. Arjona, and L. Daza Bio-ethanol steam reforming: insights on the mechanism for hydrogen production J Power Sources 151 2005 11 17
7. P.D. Vaidya, and A.E. Rodrigues Insight into steam reforming of ethanol to produce hydrogen for fuel cells Chem Eng J 117 2006 39 49
8. A.N. Fatsikostas, and X.E. Verykios Reaction network of steam reforming of ethanol over Ni-based catalysts J Catal 225 2004 439 452
9. F. Auprêtre, C. Descorme, and D. Duprez Bio-ethanol catalytic steam reforming over supported metal catalysts Catal Commun 3 2002 263 267
10. F. Auprêtre, C. Descorme, and D. Duprez Hydrogen production for fuel cells from the catalytic ethanol steam reforming Top Catal 30 2004 487 491
11. S. Cavallaro, and S. Freni Ethanol steam reforming in a molten carbonate fuel cell. A preliminary kinetic investigation Int J Hydrogen Energy 21 1996 465 469
12. 3 catalysts Energy Fuels 14 2000 1195 1199
13. S. Freni Rh based catalysts for indirect internal reforming ethanol applications in molten carbonate fuel cells J Power Sources 94 2001 14 19
14. J.P. Breen, R. Burch, and H.M. Coleman Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications Appl Catal B 39 2002 65 74
15. 2 catalysts Catal Commun 3 2002 565 571
16. D.K. Liguras, D.I. Kondarides, and X.E. Verykios Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts Appl Catal B 43 2003 345 354
17. 2 production for MCFC Appl Catal A 249 2003 119 128
18. 3 catalyst J Power Sources 123 2003 10 16
19. 2 production from ethanol Stud Surf Sci Catal 145 2003 303 306
20. 2 Appl Catal A 269 2004 13 25
21. 2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts Catal Commun 5 2004 611 615
22. E.C. Wanat, K. Venkataraman, and L.D. Schmidt Steam reforming and water-gas shift of ethanol on Rh and Rh-Ce catalysts in a catalytic wall reactor Appl Catal A 276 2004 155 162
23. 2 C R Chim 7 2004 617 622
24. E. Kikuchi, K. Ito, T. Ino, and Y. Morita Reaction of normal-heptane on rhodium catalysts in presence of steam J Catal 46 1977 382 387
25. D. Duprez, P. Pereira, A. Miloudi, and R. Maurel Steam dealkylation of aromatic-hydrocarbons.2. Role of the support and kinetic pathway of oxygenated species in toluene steam dealkylation over group-viii metal-catalysts J Catal 75 1982 151 163
26. 4 catalyst.1. Support and kinetics Appl Catal 47 1989 75 84
27. D. Duprez Selective steam reforming of aromatic-compounds on metal-catalysts Appl Catal A 82 1992 111 157
28. 2-supported noble metal catalysts at low temperature Fuel Proc Technol 86 2004 319 326
29. G. Kolb, R. Zapf, V. Hessel, and H. Löwe Propane steam reforming in micro-channels - results from catalyst screening and optimisation Appl Catal A 277 2004 155 166
30. 3 spinel oxide-supported Rh catalysts J Catal 233 2005 464 477
31. F. Auprêtre, C. Descorme, and D. Duprez Catalytic steam reforming: use for on-board hydrogen production from hydrocarbons or alcohols Ann Chim Sci Mat 26 2001 93 106
32. J.C. Vargas, S. Libs, A.C. Roger, and A. Kienneman Study of Ce-Zr-Co fluorite-type oxide as catalysts for hydrogen production by steam reforming of bioethanol Catal Today 107-108 2005 417 425
33. 3 catalysts for reforming of crude ethanol for hydrogen production Appl Catal A 287 2005 159 175
34. E. Akpan, A. Akande, A. Aboudheir, H. Ibrahim, and R.O. Idem Experimental, kinetic and 2-D reactor modeling for simulation of the production of hydrogen by the catalytic reforming of concentrated crude ethanol (CRCCE) over a Ni-based commercial catalyst in a packed-bed tubular reactor Chem Eng Sci 62 2007 3112 3126
35. 4 catalyst impact of impurities: heavy alcohol, aldehyde, ester, acid and amine Catal Today 138 2008 169 174
36. J. Rass-Hansen, R. Johanson, M. Moller, and C.H. Christensen Int J Hydrogen Energy 33 2008 4547 4554
37. 2 production. A comparison with hydrocarbon reforming J.J. Spivey, K.M. Dooley, Catalysis vol. 22 2010 1 55
38. x catalysts J Catal 190 2000 261 275
39. 3 and its possible mechanism J Mol Catal A 277 2007 137 144
40. G. Avgouropoulos, J. Papavasiliou, and T. Ioannides Hydrogen production from methanol over combustion-synthesized noble metal/ceria catalysts Chem Eng J 154 2009 274 280
41. N. Takezawa, and N. Iwasa Steam reforming and dehydrogenation of methanol: difference in the catalytic functions of copper and group VIII metals Catal Today 36 1997 45 56
42. H. Pines, and J. Manassen The mechanism of dehydration of alcohols over alumina catalysts Adv Catal 16 1966 49
43. H. Knözinger, and R. Köhne Dehydration of alcohols over alumina.1. Reaction scheme J Catal 5 1966 264 270
44. P.A. Clayborne, T.C. Nelson, and T.C. DeVore Temperature programmed desorption-FTIR investigation of C-1-C-5 primary alcohols adsorbed on gamma-alumina Appl Catal A 257 2004 225 233
45. 2: a study of activity, selectivity, and stability Appl Catal A 366 2009 353 362
46. A. Le Valant, F. Can, N. Bion, D. Duprez, and F. Epron Hydrogen production from raw bioethanol steam reforming: optimization of catalyst composition with improved stability against various impurities Int J Hydrogen Energy 35 2010 5015 5020
47. 3 for hydrogen production by raw ethanol steam reforming: influence of the addition of nickel on the catalyst performances and stability Appl Catal B 97 2010 72 81