Size control of catalytic reaction space by intercalation of alkylcarboxylate anions into Ni-Zn mixed basic salt interlayer: Application for knoevenagel reaction in water

Chemistry Letters

Volumn 39, Issue 3, 2010, Pages 304-305

  Hara, Takayoshi ^a   Kurihara, Jun ^a   Ichikuni, Nobuyuki ^a   Shimazu, Shogo ^a  

^a CHIBA UNIVERSITY   (Japan)

Author keywords

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Indexed keywords

EID: 79251525245     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2010.304     Document Type: Article

References (22)

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18. From the XRD results, the layered structure of NiZn was maintained in each case; however, the clearance space of the interlayer was changed after intercalation. See Supporting Information, which is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem- lett/index.html.
19. 2, which are the precursors of NiZn and the partly components of brucite layer of NiZn did not show remarkable catalytic activity under this reaction conditions.
20. -/NiZn can be a bilayer arrangement with a tilting angle of ca. 40 degree.
21. It can be speculated that the butyrate anion is exchanged in apparent to enolate anion.
22. -/NiZn catalyst was maintained its original one. See Supporting Information.