Universal scaling between structural relaxation and caged dynamics in glass-forming systems: Free volume and time scales

Journal of Non-Crystalline Solids

Volumn 357, Issue 2, 2011, Pages 298-301

  Ottochian, A ^a   Leporini, D ^a  

^a UNIVERSITY OF PISA   (Italy)

Author keywords

Fast dynamics; Glass transition; Relaxation

Indexed keywords

CAGE DYNAMICS; DEBYE WALLER FACTOR; FAST DYNAMICS; GLASS-FORMING SYSTEMS; NEUTRON SCATTERING EXPERIMENTS; O-TERPHENYL; POSITRON ANNIHILATION LIFETIME SPECTROSCOPY; RELAXATION; SLOW RELAXATIONS; TIME-SCALES; UNIVERSAL SCALING;

DYNAMICS; GLASS; GLASS FORMING MACHINES; GLYCEROL; POSITRON ANNIHILATION SPECTROSCOPY; POSITRONS; RELAXATION PROCESSES;

GLASS TRANSITION;

EID: 78751566655     PISSN: 00223093     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jnoncrysol.2010.05.094     Document Type: Conference Paper

References (55)

1. C. Angell Relaxation in liquids, polymers and plastic crystals - strong/fragile patterns and problems J. Non-Cryst. Solids 131-133 1991 13 31
2. C.A. Angell Formation of glasses from liquids and biopolymers Science 267 1995 1924 1935
3. P.G. Debenedetti, and F.H. Stillinger Supercooled liquids and the glass transition Nature 410 2001 259 267
4. J.C. Dyre The glass transition and elastic models of glass-forming liquids Rev. Mod. Phys. 78 2006 953 972
5. L. Larini, A. Ottochian, C. De Michele, and D. Leporini Universal scaling between structural relaxation and vibrational dynamics in glass-forming liquids and polymers Nat. Phys. 4 2008 42 45
6. A. Ottochian, C. De Michele, and D. Leporini Universal divergenceless scaling between structural relaxation and caged dynamics in glass-forming systems J. Chem. Phys. 131 2009 224517
7. T. Kanaya, T. Tsukushi, K. Kaji, J. Bartos, and J. Kristiak Phys. Rev. E 60 1999 1906
8. K.L. Ngai, L.-R. Bao, A.F. Yee, and C.L. Soles Correlation of positron annihilation and other dynamic properties in small molecule glass-forming substances Phys. Rev. Lett. 87 21 2001 215901
9. E. Duval, A. Mermet, N. Surovtsev, J. Jal, and A. Dianoux Phil. Mag. B 77 1997 457
10. E. Duval, A. Mermet, N. Surovtsev, and A. Dianoux J. Non-Cryst. Solids 235-237 1998 203
11. R.W. Hall, and P.G. Wolynes The aperiodic crystal picture and free energy barriers in glasses J. Chem. Phys. 86 1987 2943 2948
12. K.L. Ngai Why the fast relaxation in the picosecond to nanosecond time range can sense the glass transition Phil. Mag. 84 2004 1341 1353
13. F.W. Starr, S. Sastry, J.F. Douglas, and S.C. Glotzer What do we learn from the local geometry of glass-forming liquids? Phys. Rev. Lett. 89 12 2002 125501
14. A. Widmer-Cooper, H. Perry, P. Harrowell, and D.R. Reichman Irreversible reorganization in a supercooled liquid originates from localized soft modes Nat. Phys. 4 2008 711 715
15. D.J. Ashton, and J.P. Garrahan Relationship between vibrations and dynamical heterogeneity in a model glass former: Extended soft modes but local relaxation Eur. Phys. J. E 30 2009 303 307
16. D. Prevosto, S. Capaccioli, M. Lucchesi, D. Leporini, and P. Rolla J. Phys. Condens. Matter 16 2004 6597 6608
17. A. Barbieri, G. Gorini, and D. Leporini Phys. Rev. E 69 2004 061509
18. A. Barbieri, E. Campani, S. Capaccioli, and D. Leporini J. Chem. Phys. 120 2004 437 453
19. A. Barbieri, D. Prevosto, M. Lucchesi, and D. Leporini J. Phys. Condens. Matter 16 2004 6609 6618
20. L. Alessi, L. Andreozzi, M. Faetti, and D. Leporini J. Chem. Phys. 114 2001 3631 3639
21. C. De Michele, and D. Leporini Phys. Rev. E 63 2001 036701
22. J. Bartoš, O. Šauša, J. Krištiak, T. Blochowicz, and E. Rössler J. Phys. Condens. Matter 13 2001 11473 11484
23. R.H. Doremus Viscosity of silica J. Appl. Phys. 92 12 2002 7619 7629
24. A. Wischnewski, Ph.D. thesis, Heinrich-Heine Universität, Düsseldorf (1998).
25. A. Sipp, Y. Bottinga, and P. Richet New high viscosity data for 3d network liquids and new correlations between old parameters J. Non-Cryst. Solids 288 1-3 2001 166 174
26. S. Caponi, M. Zanatta, A. Fontana, L.E. Bove, L. Orsingher, F. Natali, C. Petrillo, and F. Sacchetti Ergodicity breaking in strong and network-forming glassy systems Phys. Rev. B 79 17 2009 172201
27. K.M. Bernatz, I. Echeverría, S.L. Simon, and D.J. Plazek Viscoelastic properties of boron dioxide J. Non-Cryst. Solids 289 2001 9 16
28. 3 Phys. Rev. B 58 1998 9087 9097
29. D. Sidebottom, R. Bergman, L. Börjesson, and L.M. Torell Two-step relaxation decay in a strong glass former Phys. Rev. Lett. 71 1993 2260 2263
30. 27.5 bulk metallic glass forming alloy Acta Mater. 46 1998 4725 4732 (Pubitemid 128435605)
31. A. Meyer, H. Franz, B. Sepiol, J. Wuttke, and W. Petry Fast relaxation in a metastable metallic melt Europhys. Lett. 36 1996 379 384
32. H.Z. Cummins, J. Hernandez, W.M. Du, and G. Li Comment on anomalies in the scaling of the dielectric α-relaxation Phys. Rev. Lett. 73 1994 2935-2935
33. J. Wuttke, W. Petry, G. Coddens, and F. Fujara Fast dynamics of glass-forming glycerol Phys. Rev. E 52 4 1995 4026 4034
34. C.M. Roland, M.J. Schroeder, J.J. Fontanella, and K.L. Ngai Evolution of the dynamics in 1, 4-polyisoprene from a nearly constant loss to a Johari-Goldstein β-relaxation to the α-relaxation Macromolecules 37 2004 2630 2635
35. B. Frick, and L.J. Fetters Methyl group dynamics in glassy polyisoprene: a neutron backscattering investigation Macromolecules 27 1994 974 980
36. D.J. Plazek, and J.H. Magill Physical properties of aromatic hydrocarbons. iv. an analysis of the temperature dependence of the viscosity and the compliance of 1, 3, 5 tri-α-naphthylbenzene J. Chem. Phys. 49 1968 3678 3682
37. K.L. Ngai Dynamic and thermodynamic properties of glass-forming substances J. Non-Cryst. Solids 275 1-2 2000 7 51
38. H. Franz, W. Petry, and A.Q.R. Baron Quasielastic scattering: slow dynamics of glasses Hyperfine Interact. 123-124 1999 865 879
39. N. Menon, S.R. Nagel, and D.C. Venerus Dynamic viscosity of a simple glass-forming liquid Phys. Rev. Lett. 73 7 1994 963 966
40. A. Tölle Neutron scattering studies of the model glass former ortho-terphenyl Rep. Prog. Phys. 64 11 2001 1473 1532
41. U. Buchenau, and R. Zorn A relation between fast and slow motions in glassy and liquid selenium Europhys. Lett. 18 1992 523 529
42. D.L. Sidebottom, and C.M. Sorensen Dynamic light scattering study of nonexponential relaxation in supercooled 2ca(no[sub 3])[sub 2] [center-dot] 3kno[sub 3] J. Chem. Phys. 91 11 1989 7153 7158
43. E. Kartini, M.F. Collins, B. Collier, F. Mezei, and E.C. Svensson Inelastic-neutron-scattering studies on glassy and liquid ca0.4k0.6(no3)1.4 Phys. Rev. B 54 9 1996 6292 6300
44. K. Ngai, and C. Roland Fast dynamics in glass-formers: relation of fragility and kohlrausch exponent Mat. Res. Soc. Symp. Proc 455 1997 81 90
45. R. Zorn Microscopic dynamics of glass-forming polymers J. Phys. Condens. Matter 15 2003 R1025 R1046
46. B. Frick, and D. Richter The microscopic basis of the glass transition in polymers from neutron scattering studies Science 267 1995 1939 1945
47. B. Frick, D. Richter, W. Petry, and U. Buchenau Study of the glass transition order parameter in amorphous polybutadiene by incoherent neutron scattering Z. Phys. B 70 1988 73 79
48. C.M. Roland, K.L. Ngai, P.G. Santangelo, X. Qiu, M.D. Ediger, and D.J. Plazek Temperature dependence of segmental and terminal relaxation in atactic polypropylene melts Macromolecules 34 18 2001 6159 6160
49. T. Kanaya, K. Kaji, J. Bartos, and M. Klimova Onset of the fast process in amorphous polypropylene as detected by quasielastic neutron-scattering and electron spin resonance techniques Macromolecules 30 1997 1107 1110
50. R.H. Colby Dynamic scaling approach to glass formation Phys. Rev. E 61 2000 1783 1792
51. C.L. Soles, J.F. Douglas, W.-I. Wu, and R.M. Dimeo Incoherent neutron scattering as a probe of the dynamics in molecularly thin polymer films Macromolecules 36 2 2003 373 379
52. N.G. McCrum, B.E. Read, and G. Williams Anelastic and Dielectric Effects in Polymeric Solid 1991 Dover Publications New York
53. U.W. Gedde Polymer Physics 1995 Chapman and Hall London, London
54. R. Casalini, and K.L. Ngai Structural dependence of fast relaxation in glass-forming substances and correlation with the stretch exponent of the slow structural α-relaxation J. Non-Cryst. Solids 293-295 2001 318 326
55. R. Busselez, R. Lefort, M. Guendouz, B. Frick, O. Merdrignac-Conanec, and D. Morineau Molecular dynamics of glycerol and glycerol-trehalose bioprotectant solutions nanoconfined in porous silicon J. Chem. Phys. 130 21 2009 214502