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Volumn 13, Issue 2, 2011, Pages 212-215

Photochemical heterolysis of 3,5-Bis(dimethylamino)benzyl alcohols and esters: Generation of a benzyl cation with a low-energy triplet state

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EID: 78651503884     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol102606m     Document Type: Article
Times cited : (24)

References (27)
  • 16
    • 0033950581 scopus 로고    scopus 로고
    • Several important excited state reactions appear to involve adiabatic formation of triplet benzylic cations. For example
    • Several important excited state reactions appear to involve adiabatic formation of triplet benzylic cations. For example. Rajesh, C. S.; Givens, R. S.; Wirz, J. J. Am. Chem. Soc. 2000, 122, 611-618
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 611-618
    • Rajesh, C.S.1    Givens, R.S.2    Wirz, J.3
  • 24
    • 78651471454 scopus 로고    scopus 로고
    • Those studies focused on the 3,5-dimethoxy derivatives, and according to our DFT calculations the resulting benzylic cation would still have a singlet ground state
    • Those studies focused on the 3,5-dimethoxy derivatives, and according to our DFT calculations the resulting benzylic cation would still have a singlet ground state.
  • 27
    • 0037151611 scopus 로고    scopus 로고
    • The one example where 3 is generated photochemically is complicated by competition between heterolysis to form the targeted cation and fragmentation within the diazeniumdiolate leaving group itself
    • The one example where 3 is generated photochemically is complicated by competition between heterolysis to form the targeted cation and fragmentation within the diazeniumdiolate leaving group itself. Ruane, P. H.; Bushan, K. M.; Pavlos, C. M.; D'Sa, R. A.; Toscano, J. P. J. Am. Chem. Soc. 2002, 124, 9806-9811
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9806-9811
    • Ruane, P.H.1    Bushan, K.M.2    Pavlos, C.M.3    D'Sa, R.A.4    Toscano, J.P.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.