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Several important excited state reactions appear to involve adiabatic formation of triplet benzylic cations. For example
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Those studies focused on the 3,5-dimethoxy derivatives, and according to our DFT calculations the resulting benzylic cation would still have a singlet ground state
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Those studies focused on the 3,5-dimethoxy derivatives, and according to our DFT calculations the resulting benzylic cation would still have a singlet ground state.
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The one example where 3 is generated photochemically is complicated by competition between heterolysis to form the targeted cation and fragmentation within the diazeniumdiolate leaving group itself
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The one example where 3 is generated photochemically is complicated by competition between heterolysis to form the targeted cation and fragmentation within the diazeniumdiolate leaving group itself. Ruane, P. H.; Bushan, K. M.; Pavlos, C. M.; D'Sa, R. A.; Toscano, J. P. J. Am. Chem. Soc. 2002, 124, 9806-9811
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