Reverse-phase ternary phase diagram, tie lines, and plait point for commercial biodiesel-glycerol-methanol

Industrial and Engineering Chemistry Research

Volumn 50, Issue 2, 2011, Pages 1012-1016

  Csernica, Stephen N ^a   Hsu, James T ^a  

^a Lehigh University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EQUILIBRIUM BEHAVIOR; EXPERIMENTAL DATA; LIQUID-LIQUIDS; SEPARATION PROCESS; SOLUBILITY PARAMETERS; TERNARY PHASE DIAGRAMS; TIE LINE; TWO LIQUID PHASIS;

BIODIESEL; LIQUIDS; METHANOL; PHASE DIAGRAMS; PHASE EQUILIBRIA; TERNARY ALLOYS; TERNARY SYSTEMS;

GLYCEROL;

EID: 78651393354     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101262u     Document Type: Conference Paper

References (15)

1. Schonborn, A.; Ladommatos, N.; Williams, J.; Allan, R.; Rogerson, J. The Influence of Molecular Structure of Fatty Acid Monoalkyl Esters on Diesel Combustion Combust. Flame 2009, 156, 1396
2. Zhou, H.; Lu, H.; Liang, B. Solubility of Multicomponent Systems in the Biodiesel Production by Transesterification of Jatropha curcas L. Oil with Methanol J. Chem. Eng. Data 2006, 51, 1130
3. Andreatta, A. E.; Casas, L. M.; Hegel, P.; Bottini, S. B.; Brignole, E. A. Phase Equilibria in Ternary Mixtures of Methyl Oleate, Glycerol, and Methanol Ind. Eng. Chem. Res. 2008, 47, 5157
4. Franca, B. B.; Pinto, F. M.; Pessoa, F. L. P.; Uller, A. M. C. Liquid-Liquid Equilibria for Castor Oil Biodiesel + Glycerol + Alcohol J. Chem. Eng. Data 2009, 54, 2359
5. Negi, D. S.; Sobotka, F.; Kimmel, T.; Wozny, G.; Schomacker, R. Liquid-Liquid Phase Equilibrium in Glycerol-Methanol-Methyl Oleate and Glycerol-Monoolein-Methyl Oleate Ternary Systems Ind. Eng. Chem. Res. 2005, 45, 3693
6. Cerce, T.; Peter, S.; Weidner, E. Biodiesel-Transesterification of Biological Oils with Liquid Catalysts: Thermodynamic Properties of Oil-Methanol-Amine Mixtures Ind. Eng. Chem. Res. 2005, 44, 9535
7. Oliveira, M. B.; Teles, A. R. R.; Queimada, A. J.; Coutinho, J. A. P. Phase Equilibria of Glycerol Containing Systems and Their Description with the Cubic-Plus-Association (CPA) Equation of State Fluid Phase Equilib. 2009, 280, 22
8. Chiu, C. W.; Goff, M. J.; Suppes, G. J. Distribution of Methanol and Catalysts Between Biodiesel and Glycerin Phases AIChE J. 2005, 51, 1274
9. Komers, K.; Tichy, J.; Skopal, F. Ternary Phase Diagram Biodiesel Fuel-Methanol-Glycerol J. Prakt. Chem. 1995, 337, 328
10. Seader, J. D.; Henley, E. J. Separation Process Principles, 2nd ed.; John Wiley and Sons: New York, 2006.
11. Othmer, D. F.; Tobias, P. E. Tie Line Correlation Ind. Eng. Chem. 1942, 34, 693
12. Heric, E. L. Tie Line Correlation and Plait Point Determination J. Chem. Educ. 1960, 37, 44
13. King, C. J. Separation Processes, 2nd ed.; McGraw-Hill Book Co.: New York, 1980.
14. Snyder, L. R.; Kirkland, J. J. Introduction to Modern Liquid Chromatography, 2nd ed.; John Wiley and Sons: New York, 1979.
15. Yaws, C. L. Chemical Properties Handbook; McGraw-Hill: New York, 1999.