Quantification of dissolved organic carbon at very low levels in natural ice samples by a uv-induced oxidation method

Environmental Science and Technology

Volumn 45, Issue 2, 2011, Pages 673-678

  Preunkert, S ^a   Legrand, M ^a   Stricker, P ^b   Bulat, S ^c   Alekhina, I ^c   Petit, J R ^a   Hoffmann, H ^b   May, B ^b   Jourdain, B ^a  

^a CNRS   (France)

^b UNIVERSITY OF HEIDELBERG   (Germany)

^c PETERSBURG NUCLEAR PHYSICS INSTITUTE   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ANTARCTICA; ANTHROPOGENIC EMISSIONS; CHEMICAL COMPOSITIONS; CHEMICAL IMPURITIES; DISSOLVED ORGANIC CARBON; ICE CORE; ICE SAMPLES; INORGANIC SPECIES; LOW LEVEL; MIDLATITUDES; ORGANIC CONTENT; ORGANIC SPECIES; ORGANICS; POLAR ICE; POLAR ICE SHEETS; PRE-INDUSTRIAL; SOLID PRECIPITATION; UV OXIDATION; WORKING CONDITIONS;

ATMOSPHERIC AEROSOLS; DISSOLUTION; GLACIERS; ORGANIC CARBON; OXIDATION; STREAM FLOW;

ICE;

CARBON DIOXIDE; ICE; ORGANIC CARBON;

ALPINE ENVIRONMENT; ANTHROPOGENIC SOURCE; ATMOSPHERIC CHEMISTRY; ATMOSPHERIC POLLUTION; CHEMICAL COMPOSITION; DISSOLVED ORGANIC CARBON; ICE CORE; ICE SHEET; INFRARED RADIATION; OXIDATION; QUANTITATIVE ANALYSIS; SULFUR DIOXIDE; ULTRAVIOLET RADIATION;

ARTICLE; ATMOSPHERE; ICE CORE RECORD; OXIDATION; ULTRAVIOLET RADIATION; WASTE MANAGEMENT;

ANTARCTIC REGIONS; ARCTIC REGIONS; CARBON; ENVIRONMENTAL MONITORING; ENVIRONMENTAL POLLUTANTS; ENVIRONMENTAL POLLUTION; GLOBAL WARMING; ICE; OXIDATION-REDUCTION; PHOTOCHEMICAL PROCESSES; SPECTROPHOTOMETRY, INFRARED; ULTRAVIOLET RAYS;

ANTARCTICA;

EID: 78651385545     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es1023256     Document Type: Article

References (28)

1. Legrand, M.; Mayewski, P. Glaciochemistry of polar ice cores: A review Rev. Geophys. 1997, 35, 219-243
2. Putaud, J.-P.; Raes, F.; Van Dingenen, R.; Brueggemann, E.; Facchini, M. C.; Decesari, S.; Fuzzi, S.; Gehrig, R.; Hueglin, C.; Laj, P.; Lorbeer, G.; Maenhaut, W.; Mihalopoulos, N.; Mueller, K.; Querol, X.; Rodriguez, S.; Wiedensohler, A. A European aerosol phenomenology-2: chemical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe Atmos. Environ. 2004, 38, 2579-2595 (Pubitemid 38490275)
3. Legrand, M.; Puxbaum, H. Summary of the CARBOSOL project: Present and Retrospective State of Organic versus Inorganic Aerosol over Europe J. Geophys. Res. 2007, 112, D23S01. DOI: 10.1029/2006JD008271
4. Legrand, M.; Feniet-Saigne, C.; Saltzman, E. S.; Germain, C.; Barkov, N. I.; Petrov, V. N. An ice core record of oceanic emissions of dimethylsulfide during the last climatic cycle Nature 1991, 350, 144-146
5. Wolff, E. W.; Fischer, H.; Fundel, F.; Ruth, U.; Twarloh, B.; Littot, G. C.; Mulvaney, R.; Röthlisberger, R.; De Angelis, M.; Boutron, C. F.; Hansson, M.; Jonsell, U.; Hutterli, M. A.; Lambert, F.; Kaufmann, P.; Stauffer, B.; Stocker, T. F.; Steffensen, J. P.; Bigler, M.; Siggaard-Andersen, M. L.; Udisti, R.; Becagli, S.; Castellano, E.; Severi, M.; Wagenbach, D.; Barbante, C.; Gabrielli, P.; Gaspari, V. Southern ocean sea-ice extent productivity and iron flux over the past eight glacial cycles Nature 2006, 440, 491-496
6. Staffelbach, T.; Neftel, A.; Stauffer, B.; Jacob, D. A record of the atmospheric methane sink from formaldehyde in polar ice cores Nature 1991, 349, 603-605
7. 2) and formaldehyde (HCHO) preservation in snow to changing environmental conditions: Implications for ice core records J. Geophys. Res. 2003, 108. DOI: 10.1029/2002JD002528
8. Legrand, M.; De Angelis, M. Origins and variations of light carboxylic acids in polar precipitation J. Geophys. Res. 1995, 100, 1445-1462
9. Legrand, M.; Preunkert, S.; Schock, M.; Cerqueira, M.; Kasper-Giebl, A.; Afonso, J.; Pio, C.; Gelencsér, A.; Dombrowski-Etchevers, I. Major 20th century changes of carbonaceous aerosol components (EC, WinOC, DOC, HULIS, carboxylic acids, and cellulose) derived from Alpine ice cores J. Geophys. Res. 2007, 112, D23S11. DOI: 10.1029/2006JD008080
10. Kawamura, K.; Suzuki, I.; Fujii, Y.; Watanabe, O. Ice core record of fatty acids over the past 450 years in Greenland Geophys. Res. Lett. 1996, 23 (19) 2665-2668
11. Grannas, A.; Hockaday, C.; Hatcher, P.; Thompson, L.; Mosley-Thompson, E. New revelations on the nature of organic matter in ice cores J. Geophys. Res. 2006, 111, D04304. DOI: 10.1029/2005JD006251
12. Golimowski, J.; Golimowska, K. UV-photooxidation as pretreatment step in inorganic analysis of environmental samples Anal. Chem. Acta 1996, 325, 111-123
13. Federer, U.; Kaufmann, P. R.; Hutterli, M.; Schüpbach, S.; Stocker, T. F. Continuous flow analysis of total organic carbon in polar ice cores Environ. Sci. Technol. 2008, 42, 8039-8043
14. Wallace, B.; Purcell, M. Minimizing your instrument background for total organic carbon analysis. Application note June 2003, (Tekmar).
15. Stevens, R. How to gain reliable, fast, precise, and accurate TOC results from purified water, water for injection, ultra-high purity water, and clean in place. Application note January 2004, (Tekmar).
16. Booth, R.; Furlong, J.; Wallace, B. Selection of a TOC analyzer: Analytical considerations. Application note Fall 1998, (Tekmar).
17. Wallace, B. European Pharmacopoeia Method 2.2.44: Total Organic Carbon (TOC) analysis for pharmaceutical water using the Phoenix 8000 UV-persulfate TOC analyzer. Application note June 2003, (Tekmar).
18. Saigne, C.; Kirchner, S.; Legrand, M. Ion-chromatographic measurements of ammonium, fluoride, acetate, formate, and methanesulphonate ions at very low levels in Antarctic ice Anal. Chim. Acta 1987, 203, 11-21
19. Legrand, M.; De Angelis, M.; Delmas, R. Ion chromatographic determination of common ions at ultratrace levels in Antarctic snow and ice Anal. Chim. Acta 1984, 156, 181-192
20. Legrand, M.; De Angelis, M.; Maupetit, F. In the field investigation of major and minor ions along Summit (Central Greenland) ice cores using ion chromatography J. Chromatogr. 1993, 640, 251-258
21. Fischer, H.; Wagenbach, D.; Kipfstuhl, J. Sulfate and nitrate firn concentrations on the Greenland ice sheet J. Geophys. Res. 1998, 103, 21927-21934
22. Kaufmann, P.; Federer, U.; Hutterli, M.; Bigler, M.; Schüpbach, S.; Ruth, U.; Stocker, T. F. A new continuous flow analysis (CFA) system for high-resolution field measurements on ice cores Environ. Sci. Technol. 2008, 42, 8044-8050
23. Parrenin, F.; Barnola, J.-M.; Beer, J.; Blunier, T.; Castellano, E.; Chappellaz, J.; Dreyfus, G.; Fischer, H.; Fujita, J. J. S.; Kawamura, K.; Lemieux-Dudon, B.; Loulergue, L.; Masson-Delmotte, V.; Narcisi, B.; Petit, J.-R.; Raisbeck, G.; Raynaud, D.; Ruth, U.; Schwander, J.; Severi, M.; Spahni, R.; Steffensen, J. P.; Svensson, A.; Udisti, R.; Waelbroeck, C.; Wolff, E. The EDC3 chronology for the EPICA Dome C ice core Clim. Past 2007, 3, 485-497 (Pubitemid 47293599)
24. Delmas, R. J.; Kirchner, S.; Palais, J.; Petit, J.-R. 1000 years of explosive volcanism recorded at the South Pole Tellus 1992, 44 B, 335-350
25. Ciais, P.; Jouzel, J.; Petit, J. R.; White, J. W. C. Holocene temperature variations inferred from six Antarctic ice cores Ann. Glaciol. 1994, 20, 427-436
26. Clausen, H. B.; Hammer, C. U.; Hvidberg, C. D.; Dahl-Jensen, D.; Kipfstuhl, J.; Legrand, M. A comparison of the volcanic records over the past 4000 years from the Greenland Ice Core Project and Dye 3 Greenland ice cores J. Geophys. Res. 1997, 102, 26707-26723
27. Preunkert, S.; Wagenbach, D.; Legrand, M.; Vincent, C. Col du Doìme (Mt Blanc Massif, French Alps) suitability for ice core studies in relation with past atmospheric chemistry over Europe Tellus 2000, 59, 993-1012
28. Gelencsér, A.; May, B.; Simpson, D.; Sánchez-Ochoa, A.; Kasper-Giebl, A.; Puxbaum, H.; Caseiro, A.; Pio, C.; Legrand, M. Source apportionment of PM2.5 organic aerosol over Europe: Primary/secondary, natural/anthropogenic, and fossil/biogenic origin J. Geophys. Res. 2007, 112, D23S04. DOI: 10.1029/2006JD008094