Quantitative study of hydration of C3S and C2S by thermal analysis : Evolution and composition of C-S-H gels formed

Journal of Thermal Analysis and Calorimetry

Volumn 102, Issue 3, 2010, Pages 965-973

  Goñi, Sara ^a,b   Puertas, Francisca ^a,b   Hernández, María Soledad ^a,b   Palacios, Marta ^a,b   Guerrero, Ana ^a,b   Dolado, Jorge S ^b   Zanga, Bruno ^c   Baroni, Fulvio ^c  

^a INSTITUTO DE CIENCIAS DE LA CONSTRUCCIÓN EDUARDO TORROJA   (Spain)

^b TECNALIA RESEARCH AND INNOVATION   (Spain)

^c CTG Italcementi Group   (Italy)

Author keywords

C 2S; C S H gel; C3S; Chemical composition; Thermal analysis

Indexed keywords

C 2S; C-S-H GEL; C3S; CHEMICAL COMPOSITION; THERMAL ANALYSIS;

CALCIUM; COMPUTATIONAL MECHANICS; GELS; GEOMETRY; HYDRATES; HYDRATION; PORTLAND CEMENT; SCANNING ELECTRON MICROSCOPY; SILICATES; THERMOANALYSIS; WATER CONTENT;

CALCIUM SILICATE;

EID: 78650736213     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-010-0816-7     Document Type: Article

References (37)

1. Taylor HFW. Cement chemistry. London: Academic Press; 2nd ed. Telford Publishing, 1997.
2. HFW Taylor AB Turner 1987 Reactions of tricalcium silicate paste with organic liquids Cem Concr Res 17 613 623 1:CAS:528:DyaL2sXks1ektro%3D 10.1016/0008-8846(87)90134-7 (Pubitemid 17622593)
3. K Fujii W Kondo 1974 Kinetics of the hydration of tricalcium silicate J Am Ceram Soc 57 11 492 497 1:CAS:528:DyaE2MXit1arsw%3D%3D 10.1111/j.1151-2916. 1974.tb11400.x
4. M Daimon S Ueda R Kondo 1971 Morphological study on hydration of tricalcium silicate Cem Concr Res 1 391 401 10.1016/0008-8846(71)90032-9
5. JGM de Jong HN Stein JM Stevels 1967 Hydration of tricalcium silicate J Appl Chem 17 246 250 10.1002/jctb.5010170902
6. Bishnoi S, Scrivener KL. Studying nucleation and growth kinetics of alite hydration using μic. Cem Concr Res. 2009. doi: 10.1016/j.cemconres.2009.07. 004.
7. S Bishnoi KL Scrivener 2009 μic: a new platform for modelling the hydration of cements Cem Concr Res 39 266 274 1:CAS:528:DC%2BD1MXjsVekt78%3D 10.1016/j.cemconres.2008.12.002
8. Bishnoi S. Vector modelling of hydrating cement microstructure and kinetics. Thèse no 4093. École Polytechnique Fédé rale de Lausanne; 2008.
9. Costoya Fernandez MM. Effect of particle size on the hydration kinetics and microstructural development of tricalcium silicate. Thèse n° 4102. École Polytechnique Fédérale de Lausanne; 2008.
10. S Goñi A Guerrero 2010 Study of alkaline hydrothermal activation of belite cements by thermal analysis J Therm Anal Calorim 99 2 471 477 10.1007/s10973-009-0140-2
11. HFW Taylor 1986 Proposed structure for calcium silicate hydrate gel J Am Ceram Soc 69 6 464 467 1:CAS:528:DyaL28XksVOru7g%3D 10.1111/j.1151-2916.1986. tb07446.x
12. Powers TC, Brownyard TL. Studies of the physical properties of hardened Portland cement paste. Skokie, IL: Portland Cement Association R&D Bull. 22. Reprinted from J Am Concr Inst. 1946;18(2):101-32 and 1948;8(5):549-602.
13. Powers TC. Physical properties of cement paste. Proceedings of the Fourth International Symposium on Chemistry of Cement, Washington, USA; 1960. p. 577-613.
14. RF Feldman PJ Sereda 1968 A model for hydrated Portland cement paste as deduced from sorption length change and mechanical properties Mater Struct 1 6 509 520 1:CAS:528:DyaF1MXptVCktw%3D%3D
15. RF Feldman PJ Sereda 1970 A new model for hydrated Portland cement and its practical implications Eng J Can 53 8/9 53 59
16. IG Richardson 2004 Tobermorite/jennite- and tobermorite/calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate, β-dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaolin, or silica fume Cem Concr Res 34 1733 1777 1:CAS:528:DC%2BD2cXntVGisrY%3D 10.1016/j.cemconres. 2004.05.034
17. HM Jennings 2000 A model for the microstructure of calcium silicate hydrate in cement paste Cem Concr Res 30 101 116 1:CAS:528:DC%2BD3cXhtl2rur4%3D 10.1016/S0008-8846(99)00209-4 (Pubitemid 30563998)
18. PD Tennis HM Jennings 2000 A model for two types of C-S-H in the microstructure of Portland cement pastes Cem Concr Res 30 855 863 1:CAS:528:DC%2BD3cXlvVWntb8%3D 10.1016/S0008-8846(00)00257-X
19. G Constantinides F-J Ulm 2004 The effect of two types of C-S-H on the elasticity of cement based materials: results from nanoindentation and micromechanical modelling Cem Concr Res 34 67 80 1:CAS:528:DC%2BD3sXpsFeltr4%3D 10.1016/S0008-8846(03)00230-8
20. JJ Thomas HM Jennings 2006 A colloidal interpretation of chemical aging of the C-S-H gel and its effects on the properties of cement paste Cem Concr Res 36 30 38 1:CAS:528:DC%2BD2MXht12isbbN 10.1016/j.cemconres.2004.10.022 (Pubitemid 41773612)
21. AJ Allen JJ Thomas HM Jennings 2007 Composition and density of nanoscale calcium-silicate-hydrate in cement Nat Mater 6 311 316 1:CAS:528: DC%2BD2sXjs1ersr8%3D 10.1038/nmat1871 (Pubitemid 46516823)
22. G Constantinides F-J Ulm 2007 The nanogranular nature of C-S-H J Mech Phys Solids 55 64 90 1:CAS:528:DC%2BD28Xht1Oltr3O 10.1016/j.jmps.2006.06.003 (Pubitemid 44827117)
23. HM Jennings 2008 Refinements to colloid model of C-S-H in cement: CM-II Cem Concr Res 38 275 289 1:CAS:528:DC%2BD1cXhtVGmtbs%3D 10.1016/j.cemconres. 2007.10.006
24. JS Dolado M Griebel J Hamaekers 2007 A molecular dynamic study of cementitious calcium silicate hydrate (C-S-H) gels J Am Ceram Soc 90 12 3938 3942 1:CAS:528:DC%2BD2sXhsVGmurfJ
25. H Manzano JS Dolado M Griebel J Hamaekers 2008 A molecular dynamics study of the aluminosilicate chains structure in Al-rich calcium silicate hydrated (C-S-H) gels Phys Status Solidi A 205 6 1324 1329 1:CAS:528:DC%2BD1cXot1ejtrs%3D 10.1002/pssa.200778175
26. Vandamme M, Ulm F-J, Fonollosa P. Nanogranular packing of C-S-H at substochiometric conditions. Cem Concr Res. http://dx.doi.org/10.1016/j. cemconres.2009.09.017.
27. Pellenq RJM, Kushim A, Shahsavari R, Van Vliet KJ, Buehler MJ, Yip S, Ulm F-J. A realistic molecular model of cement hydrates. www.pnas.org-cgi-doi-10. 1073-pnas.0902180106.
28. COmputationally Driven design of Innovative CEment-based materials (CODICE) project-contract NMP3-SL-2008-214030. www.codice-project.eu.
29. L Cherem da Cunha JP Gonzalves PM Büchler J Dweck 2008 Effect of metakaolin pozzolanic activity in the early stages of cement type ii paste and mortar hydration J Therm Anal Calorim 92 115 119 1:CAS:528:DC%2BD1cXlslChtrk%3D 10.1007/s10973-007-8749-5
30. Pacewska B, Wiliñska I, Bukowska M. Calorimetric investigations of the influence of waste aluminosilicate on the hydration of different cements. J Therm Anal Calorim. 2009. doi: 10.1007/s10973-008-9668-9.
31. Vessalas K, Thomas PS, Ray AS, Guerbois J-P, Joyce P, Haggman J. Pozzolanic reactivity of the supplementary cementitious material pitchstone fines by thermogravimetric analysis. J Therm Anal Calorim. 2009. doi: 10.1007/s10973-008-9708-5.
32. A Fernández-Jiménez F Puertas A Arteaga 1998 Determination of kinetic equations of alkaline activation of blast furnace slag by means of calorimetric data J Therm Anal Calorim 52 945 955 10.1023/A:1010172204297
33. EE Pressler S Brunauer DL Kantro 1956 Investigation of the Franke method of determining free calcium hydroxide and free calcium oxide Anal Chem 28 5 896 902 1:CAS:528:DyaG28XkvVWhsQ%3D%3D 10.1021/ac60113a036
34. 29Si NMR chemical shifts and mean Si-O bond lengths for calcium silicates Chem Phys Lett 172 3-4 279 283 1:CAS:528:DyaK3cXls1Chsrk%3D 10.1016/0009-2614(90)85403-Y
35. 29Si NMR spectroscopy of cements and concretes. In: Colombet P, Grimmer A, editors. Application of NMR spectroscopy to cement science. Amsterdam: Gordon & Breach; 1994. p. 55-76.
36. García-Lodeiro I. Compatibilidad de geles cementantes C-S-H y N-A-S-H. Estudios en muestras reales y en polvos sintéticos. Tesis Doctoral. Universidad Autónoma de Madrid; 2008.
37. IG Richardson 1999 The nature of C-S-H in hardened cements Cem Concr Res 29 1131 1147 1:CAS:528:DyaK1MXmtVymsrY%3D 10.1016/S0008-8846(99)00168-4