Rotational and constitutional dynamics of caged supramolecules

Proceedings of the National Academy of Sciences of the United States of America

Volumn 107, Issue 50, 2010, Pages 21332-21336

  Kühne, Dirk ^a   Klappenberger, Florian ^a   Krenner, Wolfgang ^a   Klyatskaya, Svetlana ^b   Ruben, Mario ^b,c   Barth, Johannes V ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^c UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

Nanochemistry; Supramolecular dynamics; Surface architecture

Indexed keywords

ARTICLE; CHIRALITY; COVALENT BOND; MOLECULAR DYNAMICS; NANOFABRICATION; NONHUMAN; PRIORITY JOURNAL; ROTATION; SCANNING TUNNELING MICROSCOPY; SUPRAMOLECULAR CHEMISTRY; SURFACE PROPERTY; TEMPERATURE DEPENDENCE;

METALS; MICROSCOPY, SCANNING TUNNELING; MOLECULAR STRUCTURE; NANOTECHNOLOGY; STEREOISOMERISM; SURFACE PROPERTIES;

EID: 78650735659     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1008991107     Document Type: Article

References (37)

1. Rebek J, Jr (2009) Molecular behavior in small spaces. Acc Chem Res 42:1660-1668.
2. Kitagawa H, Kobori Y, Yamanaka M, Yoza K, Kobayashi K (2009) Encapsulatedguest rotation in a self-assembled heterocapsule directed toward a supramolecular gyroscope. Proc Natl Acad Sci USA 106:10444-10448.
3. Rosi NL, et al. (2003) Hydrogen storage in microporous metal-organic frameworks. Science 300:1127-1129.
4. Horike S, Shimomura S, Kitagawa S (2009) Soft porous crystals. Nat Chem 1:695-704.
5. Akutagawa T, et al. (2009) Ferroelectricity and polarity control in solid-state flip-flop supramolecular rotators. Nat Mater 8:342-347.
6. Gimzewski JK, et al. (1998) Rotation of a single molecule within a supramolecular bearing. Science 281:531-533.
7. Lin N, Dmitriev A, Weckesser J, Barth JV, Kern K (2002) Real-time single-molecule imaging of the formation and dynamics of coordination compounds. Angew Chem, Int Ed 41:4779-4883.
8. Kühnle A, Linderoth TR, Hammer B, Besenbacher F (2002) Chiral recognition in dimerization of adsorbed cysteine observed by scanning tunnelingmicroscopy. Nature 415:891-893.
9. Schull G, et al. (2006) Single-molecule dynamics in a self-assembled 2D molecular sieve. Nano Lett 6:1360-.
10. Wintjes N, et al. (2007) A supramolecular multiposition rotary device. Angew Chem, Int Ed 46:4089-4092.
11. Tomba G, et al. (2007) Structure and energetics of diphenylalanine self-assembling on Cu(110). J Phys Chem A 111:12740-12748.
12. Grill L, et al. (2007) Rolling a single molecular wheel at the atomic scale. Nat Nanotechnol 2:95-98.
13. Lehn JM (2002) Toward complex matter: Supramolecular chemistry and selforganization. Proc Natl Acad Sci USA 99:4763-4768.
14. Rowan SJ, Cantrill SJ, Cousins GRL, Sanders JKM, Stoddart JF (2002) Dynamic covalent chemistry. Angew Chem, Int Ed 41:898-952.
15. Garcia-Garibay MA (2005) Crystalline molecular machines: Encoding supramolecular dynamics into molecular structure. Proc Natl Acad Sci USA 102:10771-10776.
16. Lehn JM (2007) From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry. Chem Soc Rev 36:151-160.
17. Kottas GS, Clarke LI, Horinek D, Michl J (2005) Artificial molecular motors. Chem Rev 105:1281-1376.
18. Browne WR, Feringa BL (2006) Making molecular machines work. Nat Nanotechnol 1:25-35.
19. Balzani V, Credi A, Venturi M (2008) Molecular machines working on surfaces and at interfaces. ChemPhysChem 9:202-220.
20. Barth JV (2007) Molecular architectonic on metal surfaces. Annu Rev Phys Chem 58:375-407.
21. Lin N, Stepanow S, Ruben M, Barth JV (2009) Surface-confined supramolecular coordination chemistry. Top Curr Chem 287:1-44.
22. Theobald JA, Oxtoby NS, Phillips MA, Champness NR, Beton PH (2003) Controlling molecular deposition and layer structure with supramolecular surface assemblies. Nature 424:1029-1031.
23. Stepanow S, et al. (2004) Steering molecular organization and host-guest interactions using tailor-made two-dimensional nanoporous coordination systems. Nat Mater 3:229-233. (Pubitemid 27058688)
24. Schlickum U, et al. (2007) Metal-organic honeycomb nanomeshes with tunable cavity size. Nano Lett 7:3813-3817.
25. Madueno R, Räisänen MT, Silien C, Buck M (2008) Functionalizing hydrogen-bonded surface networks with self-assembled monolayers. Nature 454:618-621.
26. Kühne D, et al. (2009) High-quality 2D metal-organic coordination network providing giant cavities within mesoscale domains. J Am Chem Soc 131:3881-3883.
27. Schlickum U, et al. (2008) Chiral kagomé lattice from simple ditopic molecular bricks. J Am Chem Soc 130:11778-11782.
28. Kühne D, et al. (2009) Self-assembly of nanoporous chiral networks with varying symmetry from sexiphenyl-dicarbonitrile on Ag(111). J Phys Chem C 113:17851-17859.
29. Maksymovych P, Sorescu DC, Dougherty DB, Yates JT, Jr (2005) Surface bonding and dynamical behavior of the CH3SH molecule on Au(111). J Phys Chem B 109:22463-22468.
30. Gao L, et al. (2008) Constructing an array of anchored single-molecule rotors on gold surfaces. Phys Rev Lett 101:197209-1-4.
31. Baber AE, Tierney HL, Sykes ECH (2008) A quantitative single-molecule study of thioether molecular rotors. ACS Nano 2:2385-2391.
32. Barth JV (2000) Transport of adsorbates at metal surfaces: From thermal migration to hot precursors. Surf Sci Rep 40:75-149.
33. Spillmann H, et al. (2006) A two-dimensional porphyrin-based porous network featuring communicating cavities for the templated complexation of fullerenes. Adv Mater 18:275-279.
34. Pennec Y, et al. (2007) Self-assembled molecular superlattices for tunable confinement of electrons on metal surfaces. Nat Nanotechnol 2:99-103.
35. Schiffrin A, et al. (2008) Self-aligning atomic strings in surface-supported biomolecular gratings. Phys Rev B 78:035424-1-7.
36. Klappenberger F, et al. (2009) Dichotomous array of chiral quantum corrals by a self-assembled nanoporous kagomé network. Nano Lett 9:3509-3514.
37. Clair S, et al. (2004) STM study of terephthalic acid self-assembly on Au(111): Hydrogen- bonded sheets on an inhomogenous substrate. J Phys Chem B 108:19392-19397.