Watching solvent friction impede ultrafast barrier crossings: A direct test of Kramers theory

Journal of Chemical Physics

Volumn 133, Issue 17, 2010, Pages

  Anna, Jessica M ^a   Kubarych, Kevin J ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BARRIER CROSSING; CARBON-CHAIN LENGTH; CHEMICAL EXCHANGE; CONDENSED PHASE REACTIONS; ELECTRONIC EXCITATION; ELECTRONIC GROUND STATE; EXPERIMENTAL DATA; GROUND ELECTRONIC STATE; INTERCONVERSIONS; KRAMERS THEORY; LINEAR ALKANES; MARKOVIAN; METAL CARBONYL; PICOSECONDS; REACTION BARRIERS; SOLVENT VISCOSITY; STABLE ISOMERS; SYSTEMATIC INVESTIGATIONS; TIME DOMAIN; TIME-SCALES; TRANSITION STATE; ULTRA-FAST;

CARBONYLATION; COBALT COMPOUNDS; EXCITED STATES; FRICTION; ISOMERS; PARAFFINS; PROBES; QUANTUM CHEMISTRY; RATE CONSTANTS; REACTION KINETICS; TRIBOLOGY;

ORGANIC SOLVENTS;

EID: 78650651240     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3492724     Document Type: Article

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