Non-centrosymmetric tetrameric assemblies of tetramethylammonium halides with uranyl salophen complexes in the solid state

Inorganic Chemistry

Volumn 49, Issue 24, 2010, Pages 11473-11484

  Cametti, Massimo ^a   Ilander, Laura ^a   Valkonen, Arto ^a   Nieger, Martin ^b   Nissinen, Maija ^a   Nauha, Elisa ^a   Rissanen, Kari ^a  

^a UNIVERSITY OF JYVÄSKYLÄ   (Finland)

^b UNIVERSITY OF HELSINKI   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 78650320672     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic101547r     Document Type: Article

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55. 2 have been reported (see ref 8b). The dimeric assemblies which they feature are centrosymmetric; hence, they do not crystallize in polar space groups. We speculate that the stepwise formation of a tetrameric species (monomer-, dimer-, trimer-, tetramer) intrinsically involves non centrosymmetric species (trimer), while this not the case for dimeric species like the alkali metal complexes.
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