Reductive openings of benzylidene acetals revisited: A mechanistic scheme for regio- and stereoselectivity

Journal of Organic Chemistry

Volumn 75, Issue 23, 2010, Pages 8003-8011

  Johnsson, Richard ^a   Ohlin, Markus ^a   Ellervik, Ulf ^a  

^a LUND UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

BENZYLIDENE ACETALS; COMPLEX FORMATIONS; CYCLIC ACETALS; ELECTRON-DEFICIENT; ELECTROPHILIC SPECIES; HYDROXYL GROUPS; ION PAIRS; ISOTOPE EFFECT; ISOTOPIC STUDY; LEWIS ACID; MECHANISTIC PATHWAYS; MECHANISTIC SCHEME; MODEL COMPOUND; NON-POLAR SOLVENTS; NUCLEOPHILIC OXYGEN; OXOCARBENIUM; REDUCTIVE OPENING; REGIO-SELECTIVE;

BORON COMPOUNDS; IONS; ISOTOPES; ORGANIC SOLVENTS; OXYGEN; REDUCING AGENTS; STEREOSELECTIVITY; TOLUENE;

REGIOSELECTIVITY;

4,6 O BENZYLIDENE ACETAL; ACETAL; BENZYLIDENE DERIVATIVE; BORANE DERIVATIVE; HYDROXYL GROUP; ISOTOPE; LEWIS ACID; OXYGEN; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CONTROLLED STUDY; ELECTRON; MOLECULAR INTERACTION; NUCLEOPHILICITY; REDUCTION KINETICS; STEREOCHEMISTRY;

EID: 78650303107     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101184d     Document Type: Article

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