Mechanism of electron-induced hydrogen desorption from hydroxylated rutile TiO2 (110)

Journal of Physical Chemistry C

Volumn 114, Issue 49, 2010, Pages 21510-21515

  Acharya, D P ^a   Ciobanu, C V ^b   Camillone, N ^a   Sutter, P ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b Department of Metallurgical and Materials Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DESORPTION MECHANISM; H-ATOM TRANSFER; HYDROGEN DESORPTION; INELASTIC ELECTRON TUNNELING; LOWER ENERGIES; OXIDE SURFACE; REDEPOSITION; RUTILE TIO; SCANNING TUNNELING MICROSCOPY (STM); SELECTIVE REMOVAL; SURFACE HYDROXYL; SURFACE SPECIES; TIO; VIBRATIONAL HEATING;

ATOMS; DESORPTION; ELECTRON TUNNELING; HYDROGEN; OXIDE MINERALS;

SCANNING TUNNELING MICROSCOPY;

EID: 78650296392     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp107262b     Document Type: Article

References (26)

1. 2(110) Nat. Mater. 2006, 5, 189
2. Ollia, D. F.; Al-Ekabi, H. Photocatalytic Purification and Treatment of Water and Air; Elsevier: Amsterdam, 1993.
3. Schiavello, M. Photocatalysis and Environment: Kluwer Academic Publishers: Dordrecht, 1988.
4. Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode Nature 1972, 238, 37
5. Halmann, M.; Steinberg, M., Greenhouse Gas Carbon Dioxide Mitigation Science and Technology; CRC Press: Boca Raton, 1999.
6. Wendt, S.; Sprunger, P. T.; Lira, E.; Madsen, G. K. H.; Li, Z.; Hansen, J. O.; Matthiesen, J.; Blekinge-Rasmussen, A.; Laegsgaard, E.; Hammer, B.; Besenbacher, F. The Role of Interstitial Sites in the Ti3d Defect State in the Band Gap of Titania Science 2008, 320, 1755
7. 2(110) Phys. Rev. Lett. 1996, 77, 1322
8. 2(110) Phys. Rev. Lett. 2010, 104 036806
9. 2(110) Phys. Rev. Lett. 2001, 87, 266104
10. 2 Surfaces: Principles, Mechanisms, and Selected Results Chem. Rev. 1995, 95, 735
11. 2(110) Phys. Rev. Lett. 2001, 87, 266103
12. 2(110)-(1 × 1): A Direct View at the Atomic Scale Prog. Surf. Sci. 2010, doi:10.1016/j.progsurf.2010.03.001
13. 2(110)-(1 × 1) Characterized by Scanning Tunneling Microscopy and Electron Stimulated Desorption Phys. Rev. Lett. 2000, 84, 2156
14. Shen, T.-C.; Wang, C.; Abeln, G. C.; Tucker, J. R.; Lyding, J. W.; Avouris, P.; Walkup, R. E. Atomic-Scale Desorption through Electronic and Vibrational Excitation Mechanisms Science 1995, 268, 1590
15. Mayne, A. J.; Rose, F.; Dujardin, G. Inelastic Interactions of Tunnel Electrons with Surfaces Faraday Discuss. 2000, 117, 241
16. Yin, X. L.; Calatayud, M.; Qiu, H.; Wang, Y.; Birkner, A.; Minot, C.; Woll, C. Diffusion versus Desorption: Complex Behavior of H Atoms on an Oxide Surface ChemPhysChem 2008, 9, 253
17. Soukiassian, L.; Mayne, A. J.; Carbone, M.; Dujardin, G. Atomic-Scale Desorption of H Atoms from the Si(100)-2 × 1:H Surface: Inelastic Electron Interactions Phys. Rev. B 2003, 68 035303
18. Lyo, I. W.; Avouris, P. Field-Induced Nanometer-Scale to Atomic-Scale Manipulation of Silicon Surfaces with the STM Science 1991, 253, 173
19. Persson, B. N. J.; Avouris, P. The Effects of the Electric Field in the STM on Excitation Localization-Implications for Local Bond Breaking Chem. Phys. Lett. 1995, 242, 483
20. Lauhon, L. J.; Ho, W. Direct Observation of the Quantum Tunneling of Single Hydrogen Atoms with a Scanning Tunneling Microscope Phys. Rev. Lett. 2000, 85, 4566
21. Stipe, B. C.; Rezaei, M. A.; Ho, W.; Gao, S.; Persson, M.; Lundqvist, B. I. Single-Molecule Dissociation by Tunneling Electrons Phys. Rev. Lett. 1997, 78, 4410
22. Girard, C.; Joachim, C.; Chavy, C.; Sautet, P. The Electric Field under a STM Tip Apex: Implications for Adsorbate Manipulation Surf. Sci. 1993, 282, 400
23. Mesa, G.; Dobado-Fuentes, E.; Saenz, J. J. Image Charge Method for Electrostatic Calculations in Field-Emission Diodes J. Appl. Phys. 1996, 79, 39
24. 2(110) Surface Science 2005, 308, 1154
25. 2(110): The Extent of Molecular versus Dissociative Adsorption Surf. Sci. 1996, 355, 151
26. Nojima, A.; Yamashita, K. A Theoretical Study of Hydrogen Adsorption and Diffusion on a W(110) Surface Surf. Sci. 2007, 601, 3003