Facile synthesis of 1-Methyl-1 H -benzo[ b ]azepines from 1-methylquinolinium iodides and diazo(trimethylsilyl)methylmagnesium bromide

Synthesis

Volumn , Issue 24, 2010, Pages 4221-4227

  Morita, Mikio ^a   Hari, Yoshiyuki ^b   Aoyama, Toyohiko ^a  

^a NAGOYA CITY UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

(trimethylsilyl)diazomethane; 1 H benzo b azepines; diazo(trimethylsilyl)methylmagnesium bromide; quinolinium salts; ring expansion

Indexed keywords

AZEPINES; DIAZOMETHANES; QUINOLINIUM SALTS; RING EXPANSION; TRIMETHYLSILYL;

CHLORINE COMPOUNDS; EXPANSION; FUNCTIONAL GROUPS; SALTS; SYNTHESIS (CHEMICAL);

BROMINE COMPOUNDS;

1 METHYL 1H BENZO[B]AZEPINE; 1 METHYL 1H BENZO[B]AZEPINE DERIVATIVE; 1 METHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; 1 METHYLQUINOLINIUM IODIDE; 1,7 DIMETHYL 1H BENZO[B]AZEPINE; 1,7 DIMETHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; 1,8 DIMETHYL 1H BENZO[B]AZEPINE; 1,8 DIMETHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1 METHYL 1,2 DIHYDROQUINOLINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1,4 DIMETHYL 1,2 DIHYDROQUINOLINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1,6 DIMETHYL 1,2 DIHYDROQUINOLINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1,7 DIMETHYL 1,2 DIHYDROQUINOLINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 6 METHOXY 1 METHYL 1,2 DIHYDROQUINOLINE; 2 [DIAZO(TRIMETHYLSILYL)METHYL] 8 METHOXY 1 METHYL 1,2 DIHYDROQUINOLINE; 4 [DIAZO(TRIMETHYLSILYL)METHYL] 1 METHYL 1,4 DIHYDROQUINOLINE; 5 CHLORO 1 METHYLQUINOLINIUM IODIDE; 5 CHLORO 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1 METHYL 1,2 DIHYDROQUINOLINE; 6 CHLORO 1 METHYL 1H BENZO[B]AZEPINE; 6 CHLORO 1 METHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; 6 CHLORO 2 [DIAZO(TRIMETHYLSILYL)METHYL] 1 METHYL 1,2 DIHYDROQUINOLINE; 7 CHLORO 1 METHYL 1H BENZO[B]AZEPINE; 7 METHOXY 1 METHYL 1H BENZO[B]AZEPINE; 7 METHOXY 1 METHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; 9 METHOXY 1 METHYL 3 (TRIMETHYLSILYL) 1H BENZO[B]AZEPINE; AZEPINE DERIVATIVE; DIAZO(TRIMETHYLSILYL)METHYLMAGNESIUM BROMIDE; DIHYDROQUINOLINE DERIVATIVE; ETHYL 1 METHYL IH BENZO[B]AZEPINE 3 CARBOXYLATE; ETHYL DIAZO(1 METHYL 1,2 DIHYDROQUINOLIN 2 YL)ACETATE; UNCLASSIFIED DRUG;

ADDUCTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 78650168769     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258306     Document Type: Article

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