Phase equilibria of mixtures containing organic sulfur species (OSS) and water/hydrocarbons: VLE measurements and modeling using the cubic-plus- association equation of state

Industrial and Engineering Chemistry Research

Volumn 49, Issue 24, 2010, Pages 12718-12725

  Awan, Javeed A ^a   Tsivintzelis, Ioannis ^a   Breil, Martin P ^a,c   Coquelet, Christophe ^b   Richon, Dominique ^b   Kontogeorgis, Georgios M ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^b PSL RESEARCH UNIVERSITY   (France)

^c NOVO NORDISK A S   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS MIXTURES; BINARY INTERACTION PARAMETER; BINARY SYSTEMS; CROSS-ASSOCIATION; CUBIC PLUS ASSOCIATIONS; DIMETHYL SULFIDE; EQUATION OF STATE; ETHYL MERCAPTANS; HENRY'S CONSTANTS; LIQUID PHASE; METHYL MERCAPTANS; MOLE FRACTION; ORGANIC SULFUR; PRESSURE RANGES; PURE WATER; SULFUR EMISSIONS; SYSTEM PRESSURE; THREE TEMPERATURE; VAPOR-LIQUID EQUILIBRIUM; VLE DATA; WATER SYSTEM;

ASSOCIATION REACTIONS; BINARY MIXTURES; DIAMONDS; EQUATIONS OF STATE; HYDROCARBONS; LIQUIDS; SULFUR; TERNARY SYSTEMS; WATER VAPOR; WATERWORKS;

PHASE EQUILIBRIA;

EID: 78650167776     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101470b     Document Type: Article

References (25)

1. Awan, A. J.; Thomsen, K.; Coquelet, C.; Fosbøl, L. P.; Richon, D. Vapor-Liquid Equilibrium Measurements and Modeling of the Propyl Mercaptan + Methane + Water System J. Chem. Eng. Data 2010, 55, 842-846
2. Iliuta, M. C.; Larachi, F. Solubility of total reduced sulfurs (Hydrogen sulfide, Methylmercaptan, Dimethyl sulfide, and Dimethyldisulfide) in liquids J. Chem. Eng. Data 2007, 52, 2-19
3. Awan, A. J.; Coquelet, C.; Richon, D. Effect of acid gases on the solubility of n-propyl mercaptan in 50 wt% methyldiethanolamine aqueous solution J. Chem. Eng. Res. Des. 2008, 86, 600-605
4. Michelsen, M. L.; Hendriks, E. M. Physical properties from association models Fluid Phase Equilib. 2001, 180, 165-174
5. Kontogeorgis, G. M.; Michelsen, M. L.; Folas, G. K.; Derawi, S.; Solms, N. V.; Stenby, E. H. Ten Years with the CPA (Cubic-Plus-Association) Equation of State. Part-I, 2006, Pure Compounds and Self-Associating Systems Ind. Eng. Chem. Res. 2006, 45, 4855-4868
6. Kontogeorgis, G. M.; Voutsas, E. C.; Yakoumis, I. V.; Tassios, D. P. An Equation of State for Associating Fluids. Ind. Eng. Chem. Res. 1996, 35, 4310-4318
7. Huang, S. H.; Radosz, M. Equation of State for Small, Large, Polydisperse and Associating Molecules Ind. Eng. Chem. Res. 1990, 29, 2284-2294
8. Folas, G. K.; Kontogeorgis, G. M.; Michelsen, M. L.; Stenby, E. H. Application of the cubic-plus-association equation of state to mixtures with polar chemicals and high pressures Ind. Eng. Chem. Res. 2006, 45, 1516-1526
9. Iliuta, M. C.; Larachi, F. Gas-liquid partition coefficients and Henry's law constants of DMS in aqueous solutions of Fe(II) chelate complexes using the static headspace method J. Chem. Eng. Data 2005, 50, 1700-1705
10. Williams, I. H.; Murray, F. E. Studies on the gas chromatographic analysis of Kraft mill sulphides. Part I. Collection and analysis of gaseous samples Pulp Paper Mag. Can. 1966, 347-352
11. Vitenberg, A. G.; Ioffe, B. V.; St. Dimitrova, Z.; Butaeva, I. L. Determination of gas-liquid partition coefficients by means of gas chromatographic analysis J. Chromatogr. 1975, 112, 319-327
12. Murakami, H.; Okada, T.; Nitta, T.; Katayama, T. Gas solubilities of rancid substances in water Kagaku Kogaku Ronbunshu 1987, 13, 43-50
13. DIPPR 801, Thermophysical Property Database, version 1.1; Brigham Young University: Provo, UT, 2001.
14. Kontogeorgis, G. M.; Yakoumis, I. V.; Meijer, H.; Hendriks, E.; Moorwood, T. Multicomponent phase equilibrium calculations for water-methanol-alkane mixtures Fluid Phase Equilib. 1999, 201, 158-160
15. Bondi, A. Physical properties of molecular crystals, liquids and glasses; Wiley: New York, 1968.
16. Abrams, D. S.; Prausnitz, J. M. Statistical thermodynamics of liquid mixtures: a new expression for the excess Gibbs energy of partly or completely miscible systems AIChE J. 1975, 21, 116-128
17. Denyer, R. L.; Fidler, F. A.; Lowry, R. A. Azeotrope Formation between Thiols and Hydrocarbons Ind. Eng. Chem. 1949, 2727-2737
18. Giles, F. N.; Wilson, L. H.; Wilding, V. W. Phase Equilibrium Measurements on Twelve Binary Mixtures J. Chem. Eng. Data 1996, 41, 1223-1238
19. Giles, F. N.; Wilson, G. M. Phase Equilibria on Seven Binary Mixtures J. Chem. Eng. Data 2000, 45, 146-153
20. Guilbot, P.; Fischer, K.; Valtz, A.; Theveneau, P.; aba-Ahmed, A.; Richon, D. Measurement of VLE (TP x or TP xy data) for hydrogen sulfide + (dimethylsulfide or ethylmethylsulfide or carbon disulfide) and methane solubilities in (dimethylsulfide or ethylmethylsulfide or methylmercaptan or ethylmercaptan Fluid Phase Equilib. 2007, 260, 49-59
21. Gillespie, P. C.; Wilson, G. M. Sulfur Compounds and Water V-L-E and Mutual Solubility MESH-H2O; ETSH-H2O; CS2-H2O; and COS-H2O. GPA Research Report RR-78; Gas Processors Association: Tulsa, OK, 1984.
22. Coquelet, C.; Richon, D. Measurement of Henry's law constants and infinite dilution activity coefficients of propyl mercaptan, butyl mercaptan, and dimethyl sulfide in methyldiethanolamine (1) + water (2) with w1 = 0.50 using a gas stripping technique J. Chem. Eng. Data 2005, 50, 2053-2057
23. Hine, J.; Weimar, R. D., Jr. Carbon Basicity J. Am. Chem. Soc. 1965, 87, 3387-3396
24. Tsivintzelis, I.; Kontogeorgis, G. M.; Michelsen, M. L.; Stenby, E. H. Modeling Phase Equilibria for Acid Gas Mixtures Using the CPA Equation of State. I. Mixtures with H2S. AIChE J. 2010, 56, 2956 - 2982.
25. Kontogeorgis, G. M.; Folas, G. K.; Muro-Suňe', N.; Roca, L. F.; Michelsen, M. L. Solvation phenomena in association theories with applications to oil and gas and chemical industries Oil Gas Sci. Technol. Rev. IFP 2008, 63, 305-319