A method for kinetic study of methanol oxidation at Pt electrodes by electrochemical in situ infrared spectroscopy

Journal of Electroanalytical Chemistry

Volumn 650, Issue 2, 2011, Pages 233-240

  Liao, Ling Wen ^a   Liu, Shao Xiong ^a   Tao, Qian ^a   Geng, Bin ^a   Zhang, Pu ^a   Wang, Cheng Ming ^a   Chen, Yan Xia ^a   Ye, Shen ^b  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

^b HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Attenuated total reflection configuration; Flow cell; Infrared spectroscopy; Kinetic study; Methanol oxidation; Platinum electrode

Indexed keywords

CARBON MONOXIDE; ELECTROMAGNETIC WAVE REFLECTION; FREE RADICALS; INFRARED IMAGING; INFRARED SPECTROSCOPY; KINETIC THEORY; METHANOL; OXIDATION; PLATINUM; RATE CONSTANTS; REACTION KINETICS;

ATTENUATED TOTAL REFLECTIONS; FLOW CELLS; KINETIC STUDY; METHANOL OXIDATION; PLATINUM ELECTRODE;

ELECTROCHEMICAL ELECTRODES;

EID: 78650015257     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2010.09.012     Document Type: Article

References (42)

1. M.W. Breiter Electrochim. Acta 8 1962 973 983
2. V.S. Bagotzky, and Y.B. Vassilyev Electrochim. Acta 12 1967 1323 1343
3. K. Shimazu, and H. Kita Denki Kagaku 53 1985 652 662
4. R. Inada, K. Shimazu, and H. Kita J. Electroanal. Chem. 277 1990 315 326
5. T.D. Jarvi, and E.M. Stuve J. Lipkowski, P.N. Ross, Electrocatalysis 1998 John Wiley and Sons Ltd. NewYork (Chapter 3)
6. W.F. Lin, M.S. Zei, M. Eiswirth, G. Ertl, T. Iwasita, and W. Vielstich J. Phys. Chem. B 103 1999 6968 6977
7. A. Hamnett A. Wieckowski, Interfacial Electrochemistry: Theory, Experiment, and Applications 1999 Marcel Dekker Inc. New York (Chapter 47)
8. D. Kardash, J. Huang, and C. Korzeniewski Langmuir 16 1999 2019 2023
9. C.L. Green, and A. Kucernak J. Phys. Chem. B 106 2002 11446 11456
10. N.M. Markovic, and P.N. Ross Surf. Sci. Rep. 45 2002 117 229
11. W. Viestich Electrochemistry second ed. 2007 John Wiley and Sons Ltd. New York
12. A.A. El-Shafei, R. Hoyer, L.A. Kibler, and D.M. Kolb J. Electrochem. Soc. 151 2004 F141 F145
13. Y.X. Chen, A. Miki, S. Ye, H. Sakai, and M. Osawa J. Am. Chem. Soc. 125 2003 3680 3681
14. Z. Jusys, J. Kaiser, and R.J. Behm Langmuir 19 2003 6759 6769
15. T.H.M. Housmans, A.H. Wonders, and M.T.M. Koper J. Phys. Chem. B 110 2006 10021 10031
16. J.S. Spendelow, P.K. Babu, and A. Wieckowski Curr. Opin. Solid State Mater. Sci. 9 2005 37 48
17. H. Wang, and H. Baltruschat J. Phys. Chem. C 111 2007 7038 7048
18. P. Ferrin, A.U. Nilekar, J. Greeley, M. Mavrikakis, and J. Rossmeisl Surf. Sci. 602 2008 3424 3431
19. P. Ferrin, and M. Mavrikakis J. Am. Chem. Soc. 131 2009 14381 14389
20. J. Greeley, and M. Mavrikakis J. Am. Chem. Soc. 124 2002 7193 7201
21. D. Cao, G.Q. Lu, A. Wieckowski, S.A. Wasileski, and M. Neurock J. Phys. Chem. B 109 2005 11622 11633
22. H. Wang, T. Loffler, and H. Baltruschat J. Appl. Electrochem. 31 2001 759 765
23. Y.X. Chen, M. Heinen, Z. Jusys, and R.B. Behm Angew. Chem. Int. Ed. 45 2006 981 985
24. L.W.H. Leung, A. Wieckowski, and M.J. Weaver J. Phys. Chem. 92 1988 6985 6990
25. K. Kunimatsu Ber. Bunsen Phys. Chem. 94 1990 1025 1029
26. M. Heinen, Y.X. Chen, Z. Jusys, and R.J. Behm Electrochim. Acta 52 2007 5634 5643
27. Y.X. Chen, M. Heinen, Z. Jusys, and R.J. Behm Langmuir 22 2006 10399 10408
28. Y.X. Chen, M. Heinen, Z. Jusys, and R.J. Behm ChemPhysChem 8 2007 380 385
29. A. Miki, S. Ye, and M. Osawa Chem. Commun. 2002 1500 1501
30. B.E. Conway, and H. Angerstein-Kozlowska Acc. Chem. Res. 14 1981 49 56
31. F.C. Nart, and W. Vielstich W. Vielstich, A. Lamm, H.A. Gasteiger, Handbook of Fuel Cells - Fundamentals, Technology and Applications: Electrocatalysis 2003 John Wiley and Sons Ltd. England (Chapter 21)
32. T.H.M. Housmans, and M.T.M. Koper J. Phys. Chem. B 107 2003 8557 8567
33. Z. Jusys, and R.J. Behm J. Phys. Chem. B 105 2001 10874 10883
34. Q.S. Chen, J. Solla Gullón, S.G. Sun, and J.M. Feliu Electrochim. Acta. 55 2010 7982 7994
35. A. Cuesta, A. Couto, A. Rincon, M.C. Perez, A. Lopez-Cudero, and C. Gutierrez J. Electroanal. Chem. 586 2006 184 195
36. R. Gomez, J.M. Feliu, A. Aldaz, and M.J. Weaver Surf. Sci. 410 1998 48 61
37. Y.X. Chen, M. Heinen, Z. Jusys, and R.J. Behm J. Phys. Chem. C 111 2007 435 438
38. S.C. Chang, and M.J. Weaver J. Chem. Phys. 92 1990 4582 4594
39. ad remained on the surface.
40. N.P. Lebedeva, M.T.M. Koper, J.M. Feliu, and R.A. van Santen J. Electroanal. Chem. 524-525 2002 242 251
41. dec(t)-time curve. To overcome this drawback, polynomial simulation has been firstly used to fit the coverage-time curve (Fig. 3b), before carrying out the differentiation procedure.
42. K. Franaszczuk, E. Herrero, P. Zelenay, A. Wieckowski, J. Wang, and R.I. Masel J. Phys. Chem. 96 1992 8509 8516