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Volumn 132, Issue 46, 2010, Pages 16467-16478

First hyperpolarizability dispersion of the octupolar molecule crystal violet: Multiple resonances and vibrational and solvation effects

Author keywords

[No Author keywords available]

Indexed keywords

BAND SHAPES; COMMONLY USED; CONJUGATED SYSTEMS; CRYSTAL VIOLET; DISPERSION CURVES; DISPERSION MODELS; ENERGY STATE; ENVIRONMENTAL EFFECTS; FIRST HYPERPOLARIZABILITIES; FORBIDDEN TRANSITIONS; FUNDAMENTAL WAVELENGTH; HYPER RAYLEIGH SCATTERING; IN-DEPTH UNDERSTANDING; INHOMOGENEOUS BROADENING; LINEAR ABSORPTION SPECTRA; MOLECULAR EXCITATIONS; MULTIPLE RESONANCES; NLO MATERIALS; NONLINEAR OPTICAL; NONLINEAR SPECTRUM; OCTUPOLAR MOLECULES; QUANTUM CHEMICAL CALCULATIONS; RELATIVE INTENSITY; SECOND-HARMONIC; SOLVATION EFFECT; STANDING PROBLEMS; TUNABLE WAVELENGTH; TWO-DIMENSIONAL CHROMOPHORES;

EID: 78649962062     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105600t     Document Type: Article
Times cited : (63)

References (84)
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    • Design and Characterization of Organic and Organometallic Molecules for Second Order Nonlinear Optics
    • Nalwa, H. S., Ed. Academic Press: San Diego, CA
    • Goovaerts, E., Wenseleers, W., Garcia, M. H., and Cross, G. H. Design and Characterization of Organic and Organometallic Molecules for Second Order Nonlinear Optics. In Nonlinear Optical Materials; Nalwa, H. S., Ed.; Academic Press: San Diego, CA, 2001; Vol. 9, pp 127 - 191.
    • (2001) Nonlinear Optical Materials , vol.9 , pp. 127-191
    • Goovaerts, E.1    Wenseleers, W.2    Garcia, M.H.3    Cross, G.H.4
  • 30
    • 78649934756 scopus 로고    scopus 로고
    • Available measurements in literature are moreover obtained with various setups in different circumstances, some of which (20, 23) are known to be erroneous due to 2PA-induced fluorescence and unreliable referencing (30)
    • Available measurements in literature are moreover obtained with various setups in different circumstances, some of which (20, 23) are known to be erroneous due to 2PA-induced fluorescence and unreliable referencing (30)
  • 61
    • 78649922851 scopus 로고    scopus 로고
    • Note that the term "essential state model" as used in the present work (and in refs 12 and 28) should not be confused with the model of Joffre, (8) which includes only g and 1E′ (the minimum to obtain a nonzero β). In contrast, the present definition of "essential state model" (g, 1E′, and 2A′) includes 2A′ as well, because it follows automatically from symmetry.
    • Note that the term "essential state model" as used in the present work (and in refs 12 and 28) should not be confused with the model of Joffre, (8) which includes only g and 1E′ (the minimum to obtain a nonzero β). In contrast, the present definition of "essential state model" (g, 1E′, and 2A′) includes 2A′ as well, because it follows automatically from symmetry.
  • 72
    • 84927811610 scopus 로고
    • Geschwind, S., Ed. Plenum: New York
    • Ham, F. S. In Electron Spin Resonance; Geschwind, S., Ed.; Plenum: New York, 1972; pp 1 - 119.
    • (1972) Electron Spin Resonance , pp. 1-119
    • Ham, F.S.1
  • 73
    • 78649912873 scopus 로고    scopus 로고
    • A Gaussian line shape is used here instead of a Lorentzian, to effectively account for the additional broadening caused by the presence of many coupled vibrational modes with different frequencies rather than the single normal coordinate per molecular arm (a single vibrational frequency) explicitly included in this model.
    • A Gaussian line shape is used here instead of a Lorentzian, to effectively account for the additional broadening caused by the presence of many coupled vibrational modes with different frequencies rather than the single normal coordinate per molecular arm (a single vibrational frequency) explicitly included in this model.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.