Triblock copolymer-templated synthesis of porous TiO2 and its photocatalytic activity

Journal of Nanoparticle Research

Volumn 12, Issue 8, 2010, Pages 2895-2906

  Suwanchawalit, Cheewita ^a,b   Wongnawa, Sumpun ^a  

^a PRINCE OF SONGKLA UNIVERSITY   (Thailand)

^b SILPAKORN UNIVERSITY   (Thailand)

Author keywords

Catalyst; Dye decolorization; Environmental remediation; Indigo carmine; Non ionic surfactant; Sol gel process; Titanium dioxide

Indexed keywords

ADSORPTION DESORPTION; ANATASE PHASE; DEGUSSA P25; DIFFUSE REFLECTANCE; DYE DECOLORIZATION; EFFECT OF PH; ENVIRONMENTAL REMEDIATION; FOURIER TRANSFORMED INFRARED SPECTROSCOPY; INDIGO CARMINE; INORGANIC PRECURSOR; NONIONIC; PHOTO-CATALYTIC; PHOTOCATALYTIC ACTIVITIES; POROUS TIO; RECYCLABILITY; SCANNING AND TRANSMISSION ELECTRON MICROSCOPY; SURFACE AREA; SURFACTANT TEMPLATE; TEMPLATE MATERIAL; TEMPLATED SYNTHESIS; TIO; TITANIA; TRIBLOCK COPOLYMERS; ULTRAVIOLET IRRADIATIONS; X-RAY DIFFRACTION SPECTROSCOPY;

ADSORPTION; BLOCK COPOLYMERS; CATALYSTS; COPOLYMERIZATION; DESORPTION; DICHLOROMETHANE; DIFFRACTION; GELS; INFRARED SPECTROSCOPY; NANOSTRUCTURED MATERIALS; OXIDES; PH EFFECTS; POLLUTION; PORE SIZE; SOL-GELS; SOLS; SURFACE ACTIVE AGENTS; TITANIUM; TITANIUM DIOXIDE; TRANSMISSION ELECTRON MICROSCOPY; ULTRAVIOLET SPECTROSCOPY; ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY DIFFRACTION;

SOL-GEL PROCESS;

COPOLYMER; CRYSTALLIN; DICHLOROMETHANE; INDIGO CARMINE; TITANIUM DIOXIDE;

ADSORPTION; ARTICLE; DESORPTION; DIFFUSE REFLECTANCE SPECTROSCOPY; FOURIER TRANSFORM MASS SPECTROMETRY; INFRARED SPECTROSCOPY; PARTICLE SIZE; PH; PHOTOCATALYSIS; PHOTODEGRADATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY; ULTRAVIOLET SPECTROSCOPY; X RAY DIFFRACTION;

EID: 78649909396     PISSN: 13880764     EISSN: 1572896X     Source Type: Journal    
DOI: 10.1007/s11051-010-9880-y     Document Type: Article

References (43)

1. T Alapi P Sipos I Ilisz G Wittmann Z Ambrus I Kirisi K Mogyorosi A Dombi 2006 Synthesis and characterization of titania photocatalysts: the influence of pretreatment on the activity Appl Catal A Gen 303 1 8 1:CAS:528: DC%2BD28XivVamtLo%3D 10.1016/j.apcata.2006.01.026
2. DM Antonelli 1999 Synthesis of phosphorus-free mesoporous titania via templating with amine surfactants Micropor Mesopor Mater 30 315 319 1:CAS:528:DyaK1MXkvFCjtrw%3D 10.1016/S1387-1811(99)00042-6
3. 2 by a modified sol-gel method J Angew Chem Int Ed Engl 34 2014 2017 1:CAS:528:DyaK2MXosFOqs7Y%3D 10.1002/anie.199520141
4. J Bandara JA Mielczarski J Kiwi 1999 2. Photosensitized degradation of azo dyes on Fe, Ti, and Al oxides: mechanism of charge transfer during the degradation Langmuir 15 7680 7687 1:CAS:528:DyaK1MXlvV2hsrc%3D 10.1021/la990030j (Pubitemid 30503894)
5. 2 with enhanced thermal stability Micropor Mesopor Mater 122 247 254 1:CAS:528:DC%2BD1MXkslygsbk%3D 10.1016/j.micromeso.2009.03.007
6. 2 in the presence of nonionic surfactants Ind Eng Chem Res 43 2485 2492 1:CAS:528: DC%2BD2cXjtVersbw%3D 10.1021/ie030646a
7. 2 photocatalysts J Catal 188 48 57 1:CAS:528:DyaK1MXntVCntrk%3D 10.1006/jcat.1999.2596 (Pubitemid 33125145)
8. O Carp CL Huisman A Reller 2004 Photoinduced reactivity of titanium dioxide Prog Solid State Chem 32 33 177 1:CAS:528:DC%2BD2cXhtVaitr7N 10.1016/j.progsolidstchem.2004.08.001
9. 2 J Photochem Photobiol A Chem 148 295 301 1:CAS:528: DC%2BD38Xktlejsro%3D 10.1016/S1010-6030(02)00056-4
10. N Daneshvar D Salari AR Khataee 2003 Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters J Photochem Photobiol A Chem 157 111 116 1:CAS:528:DC%2BD3sXivVGjsLs%3D 10.1016/S1010-6030(03)00015-7 (Pubitemid 36437547)
11. MA Fox MT Dulay 1993 Heterogeneous photocatalysis Chem Rev 93 341 357 1:CAS:528:DyaK3sXmvFOnsw%3D%3D 10.1021/cr00017a016
12. 2 Environ Sci Technol 30 647 653 1:CAS:528:DyaK28XhtFWnsQ%3D%3D 10.1021/es950391v (Pubitemid 26042373)
13. M Gopal WJM Chan LC De Jonghe 1997 Room temperature synthesis of crystalline metal oxides J Mater Sci 32 6001 6008 1:CAS:528:DyaK2sXnslGns7c%3D 10.1023/A:1018671212890
14. CAK Gouvea F Wypych SG Moraes N Duran N Nagata P Peralta-Zamora 2000 Semiconductor-assisted photocatalytic degradation of reactive dyes in aqueous solution Chemosphere 40 433 440 1:CAS:528:DC%2BD3cXkt1Orug%3D%3D 10.1016/S0045-6535(99)00313-6 10665410 (Pubitemid 30016627)
15. A Houas H Lachheb M Ksibi E Elaloui C Guillard JM Herrmann 2001 Photocatalytic degradation pathway of methylene blue in water Appl Catal B Environ 31 145 157 1:CAS:528:DC%2BD3MXislOlt74%3D 10.1016/S0926-3373(00)00276-9 (Pubitemid 32430417)
16. 2 powders prepared by sol-gel method: characterization and photocatalytic study Mater Chem Phys 110 166 175 1:CAS:528:DC%2BD1cXks1Gisbw%3D 10.1016/j.matchemphys.2008.01.037 (Pubitemid 351503663)
17. M Kanna S Wongnawa S Buddee K Dilokkhunakul P Pinpithak 2010 Amorphous titanium dioxide: a recyclable dye remover for water treatment J Sol Gel Sci Technol 53 162 170 1:CAS:528:DC%2BC3cXhsFers70%3D 10.1007/s10971-009-2072-5
18. 2 with high crystallinity, thermal stability, large surface area, and enhanced photocatalytic activity Appl Catal A Gen 323 110 118 1:CAS:528:DC%2BD2sXjvFaqtbo%3D 10.1016/j.apcata.2007.02.010 (Pubitemid 46528191)
19. P Kluson P Kacer T Cajthaml M Kalaji 2001 Preparation of titania mesoporous materials using a surfactant-mediated sol-gel method J Mater Chem 11 644 651 1:CAS:528:DC%2BD3MXnt1Sqtw%3D%3D 10.1039/b004760k (Pubitemid 32193491)
20. 2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations Appl Catal B Environ 49 1 14 1:CAS:528:DC%2BD2cXisl2ksL4%3D 10.1016/j.apcatb.2003.11.010 (Pubitemid 38448836)
21. O Legrini E Oliveros AM Braun 1993 Photochemical processes for water treatment Chem Rev 93 671 698 1:CAS:528:DyaK3sXhsFektLc%3D 10.1021/cr00018a003
22. JS Lettow TM Lancaster CJ Glinka JY Ying 2005 Small-angle neutron scattering and theoretical investigation of poly(ethylene oxide)-poly(propylene oxide)- poly(ethylene oxide) stabilized oil-in-water microemulsions Langmuir 21 5738 5746 1:CAS:528:DC%2BD2MXksVOqu7o%3D 10.1021/la046918b 15952817 (Pubitemid 40925816)
23. MI Litter 1999 Heterogeneous photocatalysis: transition metal ions in photocatalytic systems Appl Catal B Environ 23 89 114 1:CAS:528: DyaK1MXmsFahs7k%3D 10.1016/S0926-3373(99)00069-7 1999mvlp.book.....L (Pubitemid 29492493)
24. B Ohtani Y Ogawa S Nishimoto 1997 Photocatalytic activity of amorphous-anatase mixture of titanium(IV) oxide particles suspended in aqueous solutions J Phys Chem B 101 3746 3752 1:CAS:528:DyaK2sXislyru7k%3D 10.1021/jp962702+
25. 2 suspensions Environ Sci Technol 35 971 976 1:CAS:528:DC%2BD3MXmsVeruw%3D%3D 10.1021/es000162v 11351544 (Pubitemid 32896097)
26. C Randorn S Wongnawa P Boonsin 2004 Bleaching of methylene blue by hydrated titanium dioxide ScienceAsia 30 149 156 10.2306/scienceasia1513-1874. 2004.30.149
27. VF Stone RJ Davis 1998 Synthesis, characterization, and photocatalytic activity of titania and niobia mesoporous molecular sieves Chem Mater 10 1468 1474 1:CAS:528:DyaK1cXis12rur4%3D 10.1021/cm980050r
28. YI Su HZ Liu 2003 Temperature-dependent solubilization of PEO-PPO-PEO block copolymers and their application for extraction trace organics from aqueous solutions Korean J Chem Eng 20 343 346 1:CAS:528:DC%2BD3sXjvVeru78%3D 10.1007/BF02697250
29. Wang OJ, Moss SC, Shalz ML, Glaeser AM, Zandbergen HW, Zschack P (1992) In: Jena P, Khanna SN, Rao BK (eds) Physics and chemistry of finite systems: from clusters to crystals, vol 2. Kluwer Academic Publishers, Boston, 1992, p 1287
30. 2 derived from hydrolysis condensation with TX-100 as template Mater Sci Eng B 128 229 233 1:CAS:528:DC%2BD28XhvVWntLw%3D 10.1016/j.mseb.2005.12.004 (Pubitemid 43289211)
31. Y Wang H Yang D Zhao 2006 "Host-Guest" chemistry in the synthesis of ordered nonsiliceous mesoporous materials Acc Chem Res 39 423 432 10.1021/ar050129j
32. 2 with high photocatalytic activities J Photochem Photobiol A Chem 173 7 12 1:CAS:528:DC%2BD2MXkvFWnu7g%3D 10.1016/j.jphotochem.2004.12.024 (Pubitemid 40801125)
33. M Yan F Chen J Zhang M Anpo 2005 Preparation of controllable crystalline titania and study on the photocatalytic properties J Phys Chem B 109 8673 8678 1:CAS:528:DC%2BD2MXivV2mtrw%3D 10.1021/jp046087i 16852027 (Pubitemid 40750898)
34. J Yang J Zhang L Zhu S Chen Y Zhang Y Tang Y Zhu Y Li 2006 Synthesis of nano titania particles embedded in mesoporous SBA-15: characterization and photocatalytic activity J Hazard Mater B 137 952 958 1:CAS:528: DC%2BD28XpsFyqu7k%3D 10.1016/j.jhazmat.2006.03.017 (Pubitemid 44363125)
35. 2 particles by modified sol-gel method using ionic liquids Micropor Mesopor Mater 84 211 217 1:CAS:528:DC%2BD2MXpsF2nsbo%3D 10.1016/j.micromeso.2005.05.029 (Pubitemid 41764828)
36. C Yu Y Yu L Miao D Zhao 2001 Highly ordered mesoporous silica structures templated by poly(butylene oxide) segment di- and tri-block copolymers Micropor Mesopor Mater 44 45 65 72 10.1016/S1387-1811(01)00169-X (Pubitemid 32657111)
37. 2-based photocatalysts J Phys Chem B 102 10871 10878 1:CAS:528:DyaK1cXnslOhs7g%3D 10.1021/jp982948+
38. J Zhang M Minagawa M Matsuoka H Yamashita M Anpo 2000 Photocatalytic decomposition of NO on Ti-HMS mesoporous zeolite catalysts Catal Lett 66 241 243 1:CAS:528:DC%2BD3cXkvFCks78%3D 10.1023/A:1019084631137
39. 2 powder J Eur Ceram Soc 20 2153 2158 1:CAS:528:DC%2BD3cXls1Ckt7w%3D 10.1016/S0955-2219(00)00085-6
40. 2 Mater Lett 54 375 381 1:CAS:528:DC%2BD38XjsFOjtr8%3D 10.1016/S0167-577X(01)00597-3 (Pubitemid 34532393)
41. L Zhao Y Yu L Song M Ruan X Hu A Larbot 2004 Preparation of mesoporous titania film using nonionic triblock copolymer as surfactant template Appl Catal A Gen 263 171 177 1:CAS:528:DC%2BD2cXjvVWktr0%3D 10.1016/j.apcata.2003.12.022
42. JY Zheng JB Pang KY Qiu Y Wei 2001 Synthesis and characterization of mesoporous titania and silica-titania materials by urea templated sol-gel reactions Micropor Mesopor Mater 49 189 195 1:CAS:528:DC%2BD3MXotFynurw%3D 10.1016/S1387-1811(01)00417-6
43. 4 as a precursor Appl Surf Sci 158 32 37 1:CAS:528: DC%2BD3cXjvVSntrs%3D 10.1016/S0169-4332(99)00587-5 2000ApSS..158...32Z