Investigating acrylic acid polymerization by using a droplet-based millifluidics approach

Macromolecular Symposia

Volumn 296, Issue 1, 2010, Pages 203-209

  Lorber, Nicolas ^a   Pavageau, Bertrand ^a   Mignard, Emmanuel ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

Author keywords

acrylic acid free radical polymerization; droplets as microreactors; inline monitoring; millifluidics; Raman spectroscopy

Indexed keywords

ACRYLIC ACIDS; AQUEOUS DROPLETS; BASIC CONCEPTS; DROPLETS AS MICROREACTORS; HIGH MOLECULAR WEIGHT; HIGH TEMPERATURE; HIGH THROUGHPUT SCREENING TOOLS; INLINE MONITORING; KINETIC DATA; MICROREACTOR MODELS; MILLIFLUIDICS; NEW APPROACHES; OFF-LINE ANALYSIS; POLYMERIZATION KINETICS; POLYMERIZATION RATES; POLYMERIZATION REACTION; PROOF OF CONCEPT; SODIUM PERSULFATE; VARIOUS PH;

ACRYLICS; ACTIVATION ENERGY; ATOM TRANSFER RADICAL POLYMERIZATION; CARBOXYLIC ACIDS; CHEMICAL REACTORS; DROP FORMATION; FREE RADICALS; ORGANIC ACIDS; POLYDISPERSITY; POLYMERS; RAMAN SCATTERING; RAMAN SPECTROSCOPY; REACTION KINETICS; SIZE EXCLUSION CHROMATOGRAPHY; SODIUM;

FREE RADICAL POLYMERIZATION;

EID: 78649858846     PISSN: 10221360     EISSN: 15213900     Source Type: Journal    
DOI: 10.1002/masy.201051030     Document Type: Conference Paper

References (19)

1. A. Huebner, S. Sharma, M. Srisa-Art, F. Hollfelder, J. B. Edel, A. J. DeMello, Lab Chip 2008, 8, 1244.
2. H. Song, D. L. Chen, R. F. Ismagilov, Angew. Chem. Int. Ed. 2006, 45, 7336.
3. J. L. Steinbacher, D. T. McQuade, J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 6505.
4. F. Sarrazin, MS Thesis, Institut National Polytechnique de Toulouse, France, 2006.
5. H. Song, R. F. Ismagilov, J. Am. Chem. Soc. 2003, 125, 14613.
6. R. Hoogenboom, M. W. M. Fijten, C. H. Abeln, U. S. Schubert, Macromol. Rapid. Commun. 2004, 25, 237.
7. M. J. Madou, Fundamentals of Microfabrication: The Science of Miniaturization, second edition, Taylor & Francis, Inc., 2002.
8. WO 2008043860 (2008), Rhodia operation, invs.:, B. Pavageau, G. Christobal, R. Rabih, C.-T. Vuong.
9. WO 2008043922 (2008), Rhodia operation and University of Bordeaux 1, invs.:, P. Panizza, G. Christobal, B. Pavageau, A. Colin.
10. FR 2907030 (2008), Rhodia Recherches et Technologies and Université de Bordeaux 1, invs.:, P. Panizza, E. Wilfried, B. Pavageau, S. Galinat.
11. W. Engl, M. Tachibana, P. Panizza, R. Backov, Int. J. Multiphase Flow 2007, 33, 897.
12. M. Tachibana, W. Engl, P. Panizza, H. Deleuze, S. Lecommandoux, H. Ushiki, R. Backov, Chem. Eng. Process. 2008, 47, 1323.
13. P. Panizza, W. Engl, C. Hany, R. Backov, Colloids Surf. A, 2008, 312, 24.
14. W. Engl, M. Tachibana, A. Colin, P. Panizza, Chem. Eng. Sci. 2008, 63, 1692.
15. H. Çatalgil-Giz, A. Giz, A. M. Alb, W. F. Reed, J. Appl. Polym. Sci. 2004, 91, 1352.
16. R. A. Scott, N. A. Peppas, AIChE J. 1997, 43, 135.
17. S. P. Manickam, K. Venkatarao, N. R. Subbaratnam, Eur. Polym. J. 1979, 15, 483.
18. S. S. Cutié, P. B. Smith, D. E. Henton, T. L. Staples, C. Powell, J. Polym. Sci., Part B: Polym. Phys. 1997, 35, 2029.
19. N. Lorber, B. Pavageau, E. Mignard, Macromolecules 2010, 43, 5524.