Critical behavior of pure confined fluids from an extension of the van der Waals equation of state

Journal of Supercritical Fluids

Volumn 55, Issue 2, 2010, Pages 455-461

  Travalloni, Leonardo ^a   Castier, Marcelo ^a,b   Tavares, Frederico W ^a   Sandler, Stanley I ^c  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

^b UNITED ARAB EMIRATES UNIVERSITY   (United Arab Emirates)

^c University of Delaware   (United States)

Author keywords

Adsorption; Confined fluid; Critical point; State equation

Indexed keywords

CONFINED FLUIDS; CRITICAL BEHAVIOR; CRITICAL POINT; CRITICAL POINTS; CYLINDRICAL PORES; FLUID MOLECULES; MECHANICALLY STABLE; MOLECULE-MOLECULE INTERACTIONS; PORE WALL; POROUS SOLIDS; PURE FLUIDS; SQUARE-WELL POTENTIALS; STATE EQUATIONS; VAN DER WAALS EQUATION OF STATE;

ADSORPTION; FLUIDS; MOLECULES; PHASE TRANSITIONS; PORE SIZE; VAN DER WAALS FORCES;

EQUATIONS OF STATE;

EID: 78649778024     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2010.09.008     Document Type: Article

References (31)

1. 2 in aerogel Physical Review Letters 70 1993 954 957
2. M. Thommes, G.H. Findenegg, and M. Schoen Critical depletion of a pure fluid in controlled-pore glass: experimental results and grand canonical ensemble Monte Carlo simulation Langmuir 11 1995 2137 2142
3. Y. Hiejima, and M. Yao Phase behaviour of water confined in Vycor glass at high temperatures and pressures Journal of Physics: Condensed Matter 16 2004 7903 7908
4. V.G. Arakcheev, A.A. Valeev, V.B. Morozov, and A.N. Olenin CARS diagnostics of molecular media under nanoporous confinement Laser Physics 18 2008 1451 1458
5. M. Thommes, and G.H. Findenegg Pore condensation and critical-point shift of a fluid in controlled-pore glass Langmuir 10 1994 4270 4277
6. K. Morishige, and M. Shikimi Adsorption hysteresis and pore critical temperature in a single cylindrical pore Journal of Chemical Physics 108 1998 7821 7824
7. A. Vishnyakov, E.M. Piotrovskaya, E.N. Brodskaya, E.V. Votyakov, and Y.K. Tovbin Critical properties of Lennard-Jones fluids in narrow slit-shaped pores Langmuir 17 2001 4451 4458
8. H.L. Vortler Simulation of fluid phase equilibria in square-well fluids: from three to two dimensions Collection of Czechoslovak Chemical Communications 73 2008 518 532
9. S. Jana, J.K. Singh, and S.K. Kwak Vapor-liquid critical and interfacial properties of square-well fluids in slit pores Journal of Chemical Physics 130 2009 214707 (1-8)
10. S.K. Singh, A. Sinha, G. Deo, and J.K. Singh Vapor-liquid phase coexistence, critical properties, and surface tension of confined alkanes Journal of Physical Chemistry C 113 2009 7170 7180
11. M. Alvarez, D. Levesque, and J.J. Weis Monte Carlo approach to the gas-liquid transition in porous materials Physical Review E 60 1999 5495 5504
12. C. Spöler, and S.H.L. Klapp Phase behavior of Stockmayer fluids confined to a nonpolar porous material Journal of Chemical Physics 118 2003 3628 3638
13. J. Jiang, and S.I. Sandler Adsorption and phase transitions on nanoporous carbonaceous materials: insights from molecular simulations Fluid Phase Equilibria 228-229 2005 189 195
14. V. De Grandis, P. Gallo, and M. Rovere The phase diagram of confined fluids Journal of Molecular Liquids 134 2007 90 93
15. X. Zhang, and W. Wang Square-well fluids in confined space with discretely attractive wall-fluid potentials: critical point shift Physical Review E 74 2006 062601 (1-4)
16. J.K. Singh, and S.K. Kwak Surface tension and vapor-liquid phase coexistence of confined square-well fluid Journal of Chemical Physics 126 2007 024702 (1-8)
17. T.W. Rosch, and J.R. Errington Phase behavior of model confined fluids: influence of substrate-fluid interaction strength Journal of Physical Chemistry B 112 2008 14911 14919
18. M. Schoen, and D.J. Diestler Analytical treatment of a simple fluid adsorbed in a slit-pore Journal of Chemical Physics 109 1998 5596 5606
19. A. Giaya, and R.W. Thompson Water confined in cylindrical micropores Journal of Chemical Physics 117 2002 3464 3475
20. G.J. Zarragoicoechea, and V.A. Kuz van der Waals equation of state for a fluid in a nanopore Physical Review E 65 2002 021110 (1-4)
21. A.G. Meyra, G.J. Zarragoicoechea, and V.A. Kuz Thermodynamic equations for a confined fluid at nanometric scale Fluid Phase Equilibria 230 2005 9 14
22. E.G. Derouane On the physical state of molecules in microporous solids Microporous and Mesoporous Materials 104 2007 46 51
23. L. Travalloni, M. Castier, F.W. Tavares, and S.I. Sandler Thermodynamic modeling of confined fluids using an extension of the generalized van der Waals theory Chemical Engineering Science 65 2010 3088 3099
24. S.I. Sandler The generalized van der Waals partition function. I. Basic theory Fluid Phase Equilibria 19 1985 233 257
25. K.-H. Lee, M. Lombardo, and S.I. Sandler The generalized van der Waals partition function. II. Application to the square-well fluid Fluid Phase Equilibria 21 1985 177 196
26. G.E. Mueller Numerically packing spheres in cylinders Powder Technology 159 2005 105 110
27. T.M. Truskett, P.G. Debenedetti, and S. Torquato Thermodynamic implications of confinement for a waterlike fluid Journal of Chemical Physics 114 2001 2401 2418
28. G. Franzese, G. Malescio, A. Skibinsky, S.V. Buldyrev, and H.E. Stanley Generic mechanism for generating a liquid-liquid phase transition Nature 409 2001 692 695
29. J.W. Tester, and M. Modell Thermodynamics and its Applications 1996 Prentice Hall New Jersey
30. B.E. Poling, J.M. Prausnitz, and J.P. O'Connell The Properties of Gases and Liquids 2000 McGraw-Hill New York
31. T.L. Hill An Introduction to Statistical Thermodynamics 1960 Addison-Wesley Massachusetts