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Following the argument of Ref., one easily proves that the conventional 90 ° Cu-O-Cu superexchange is twice as large as the 180 ° superexchange (two and one Cu-O-Cu bridges, respectively)
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x2 - y2 orbitals, NO orbitals lying ∼1eV above the Fermi level. The respective WF fit evidences that the hopping between Cu and NO orbitals is negligible and does not exceed 0.8 meV, justifying the one-orbital model.
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x 2 - y 2 orbitals, NO orbitals lying ∼ 1 eV above the Fermi level. The respective WF fit evidences that the hopping between Cu and NO orbitals is negligible and does not exceed 0.8 meV, justifying the one-orbital model
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4 plaquette
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4 plaquette
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44
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78649694874
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The magnetic susceptibility of the uniform chain with the staggered anisotropy should depend on the direction of the applied field. Unfortunately, Ref. reports ESR measurements for two directions of the applied field only and does not allow to perform an extensive comparison with models involving the staggered anisotropy
-
The magnetic susceptibility of the uniform chain with the staggered anisotropy should depend on the direction of the applied field. Unfortunately, Ref. reports ESR measurements for two directions of the applied field only and does not allow to perform an extensive comparison with models involving the staggered anisotropy.
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45
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47
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78649691690
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N /J=0.21. Thus, the effect is rather strong but it does not influence any of our conclusions
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N / J = 0.21. Thus, the effect is rather strong but it does not influence any of our conclusions
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