Solvent-free nanocomposite proton-conducting membranes composed of cesium salt of phosphotungstic acid doped PVDF-CTFE/PEO blend

Ionics

Volumn 16, Issue 8, 2010, Pages 681-687

  Amirinejad, M ^a   Madaeni, S S ^a   Navarra, M A ^b   Rafiee, E ^a   Scrosati, B ^b  

^a RAZI UNIVERSITY   (Iran)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

Membrane; Nanocomposite; Phosphotungstic acid; Polyethylene oxide; Proton conductors; Solvent free

Indexed keywords

BLEND RATIOS; CESIUM SALTS; DRY CONDITION; DRY STATE; DSC STUDIES; DYNAMIC EQUILIBRIA; NANOCOMPOSITE MEMBRANES; PHOSPHOTUNGSTIC ACID; POLYVINYLIDENE FLUORIDES; PRESENCE OF WATER; PROTON CONDUCTORS; PROTON HOPPING; PROTON MOTION; PROTON-CONDUCTING MEMBRANES; SEGMENTAL MOTION; SOLVENT FREE; SOLVENT-FREE PROCEDURES; THERMAL STABILITY;

ACIDS; CESIUM; ETHYLENE; FILLED POLYMERS; HYDRATES; HYDRATION; NANOCOMPOSITES; POLYETHYLENE GLYCOLS; POLYETHYLENE OXIDES; POLYETHYLENES; PROTONS; SOLVENTS; THERMODYNAMIC STABILITY; THERMOPLASTICS;

MEMBRANES;

EID: 78649703440     PISSN: 09477047     EISSN: 18620760     Source Type: Journal    
DOI: 10.1007/s11581-010-0449-7     Document Type: Article

References (40)

1. Scrosati B (ed) (1993) Applications of electroactive polymers. Chapman and Hall, London.
2. Jeona J-D, Chob B-W, Kwak S-Y (2005) Solvent-free polymer electrolytes based on thermally annealed porous P(VdF-HFP)/P(EO-EC) membranes. J Power Sources 143: 219-226.
3. 2 nanoparticles on mechanical properties and ionic conductivity of solvent-free polymer electrolytes based on porous P(VdF-HFP)/P(EO-EC) membranes. J Power Sources 162: 1304-1311.
4. Katsaros G, Stergiopoulos T, Arabatzis IM, Papadokostaki KG, Falaras P (2002) A solvent-free composite polymer/inorganic oxide electrolyte for high efficiency solid-state dye-sensitized solar cells. J Photochem Photobiol, A Chem 149: 191-198.
5. Ratner MA, Shriver DF (1988) Ion transport in solvent-free polymers. Chem Rev 88: 109-124.
6. 2 nanoparticles. Solid State Ion 179: 543-549.
7. 4 polymer batteries. J Power Sources 124: 246-253.
8. Appetecchi GB, Croce F, Hassoun J, Scrosati B, Salomon M, Cassel F (2003) Hot-pressed, dry, composite, PEO-based electrolyte membranes, I. Ionic conductivity characterization. J Power Sources 114: 105-112.
9. Chen-Yang YW, Wang YL, Chen YT, Li YK, Chen HC, Chiu HY (2008) Influence of silica aerogel on the properties of polyethylene oxide-based nanocomposite polymer electrolytes for lithium battery. J Power Sources 182: 340-348.
10. Fan J, Raghavan SR, X-Y Yu, Khan SA, Fedkiw PS, Hou J, Baker GL (1998) Composite polymer electrolytes using surface-modified fumed silicas: conductivity and rheology. J Power Sources 111: 117-123.
11. 2 in poly(ethylene oxide)-based polymer electrolytes. J Power Sources 109: 507-514.
12. 3 nano-composite solid polymer electrolyte. Electrochimica Acta 50: 5602-5605.
13. Dai Y, Greenbaum S, Golodnitsky D, Ardel G, Strauss E, Peled E, Rosenberg Y (1998) Lithium-7 NMR studies of concentrated LiI/PEO-based solid electrolytes. Solid State Ion 106: 25-32.
14. Croce F, Appetecchi GB, Persi L, Scrosati B (1998) Nanocomposite polymer electrolytes for lithium batteries. Nature 394: 456-458.
15. Kozhevnikov IV (1998) Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem Rev 98: 171-198.
16. Mioč UB, Todorović MR, Davidović M, Colomban Ph, Holclajtner-Antunović I (2005) Heteropoly compounds-from proton conductors to biomedical agents. Solid State Ion 176: 3005-3017.
17. Katsoulis DE (1998) A survey of applications of polyoxometalates. Chem Rev 98: 359-387.
18. Okuhara T, Nishimura T, Watanabe H, Misono M (1992) Insoluble heteropoly compounds as highly active catalysts for liquid-phase reactions. J Mol Catal 74: 247-256.
19. 40, for hydrolysis of esters in water. Appl Catal, A: Gen 155: L9-L13.
20. 40 on their partially substituted Cs or K salts. Appl Catal, A: Gen 255: 265-277.
21. www. matweb. com.
22. Hassoun J, Croce F, Tizzani C, Scrosati B (2007) Acid-gel-immobilized, nanoporous composite, protonic membranes as low cost system for direct methanol fuel cells. Electrochem Commun 9: 2045-2050.
23. Croce F, Hassoun J, Tizzani C, Scrosati B (2006) Nanoporous composite, low cost, protonic membranes for direct methanol fuel cells. Electrochem Commun 8: 1125-1131.
24. Rafiee E, Zolfagharifar Z, Joshaghani M, Eavani S (2009) Facile condensation of indole with benzaldehyde over Keggin-type heteropoly compounds: an initial effort toward catalyst design. Appl Catal, A: Gen 365: 287-291.
25. Privalko VP, Lobodina AP (1974) Glass transition in the lower homologues of polyethyleneoxide. Eur Polym J 10: 1033-1038.
26. Kobayashi M, Tashiro K, Tadokoro H (1975) Molecular vibrations of three crystal forms of poly(vinylidene fluoride). Macromolecules 8: 158-171.
27. Reddy MJ, Chu PP (2002) Ion pair formation and its effect in PEO: Mg solid polymer electrolyte system. J Power Sources 109: 340-346.
28. 6 solid polymer electrolyte with enhanced ion conduction in 'wet' form. J Power Sources 123: 222-229.
29. Wu F, Feng T, Bai Y, Wu C, Ye L, Feng Z (2009) Preparation and characterization of solid polymer electrolytes based on PHEMO and PVDF-HFP. Solid State Ion 180: 677-680.
30. 2 nanocomposite polymer electrolytes. Electrochim Acta 52: 3181-3189.
31. Rodriguez F (1996) Principles of polymer systems, 4th edn. Taylor & Francis Publishers, New York.
32. Dohany JE, Humphrey JS (1989) In: Mark HF et al (eds) Encyclopedia of polymer science and engineering, vol. 17. Wiley, New York.
33. Ramani V, Kunz HR, Fenton JM (2004) Investigation of Nafion/HPA composite membranes for high temperature/low relative humidity PEMFC operation. J Membr Sci 232: 31-44.
34. Kreuer KD (1996) Proton conductivity: materials and applications. Chem Mater 8: 610-641.
35. Druger SD, Nitzam A, Ratner MA (1983) Dynamic bond percolation theory: a microscopic model for diffusion in dynamically disordered systems. I. Definition and one-dimensional case. J Chem Phys 79: 3133-3142.
36. Druger SD, Ratner MA, Nitzan A (1983) Polymeric solid electrolytes: dynamic bond percolation and free volume models for diffusion. Solid State Ion 9-10: 1115-1120.
37. Ukshe EA, Leonova LS, Korosteleva AI (1989) Proton conduction in heteropoly compounds. Solid State Ion 36: 219-223.
38. Rajendran S, Sivakumar P (2008) An investigation of PVDF/PVC-based blend electrolytes with EC/PC as plasticizers in lithium battery applications. Physica B 403: 509-516.
39. Stephan AM (2006) Review on gel polymer electrolytes for lithium batteries. Eur Polym J 42: 21-42.
40. Vickraman P, Ramamurthy S (2006) A study on the blending effect of PVDF in the ionic transport mechanism of plasticized PVC-LiBF4 polymer electrolyte. Mater Lett 60: 3431-3436.